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Core pinning by intragranular nanoprecipitates in polycrystalline MgCNi_3

L. D. Cooley·X. Song·J. Jiang·D. C. Larbalestier·T. He·K. A. Regan·R. J. Cava
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Abstract

The nanostructure and magnetic properties of polycrystalline MgCNi_3 were studied by x-ray diffraction, electron microscopy, and vibrating sample magnetometry. While the bulk flux-pinning force curve F_p(H) indicates the expected grain-boundary pinning mechanism just below T_c = 7.2 K, a systematic change to pinning by a nanometer-scale distribution of core pinning sites is indicated by a shift of F_p(H) with decreasing temperature. The lack of scaling of F_p(H) suggests the presence of 10 to 20% of nonsuperconducting regions inside the grains, which are smaller than the diameter of fluxon cores 2xi at high temperature and become effective with decreasing temperature when xi(T) approaches the nanostructural scale. Transmission electron microscopy revealed cubic and graphite nanoprecipitates with 2 to 5 nm size, consistent with the above hypothesis since xi(0) = 6 nm. High critical current densities, more than 10^6 A/cm^2 at 1 T and 4.2 K, were obtained for grain colonies separated by carbon. Dirty-limit behavior seen in previous studies may be tied to electron scattering by the precipitates, indicating the possibility that strong core pinning might be combined with a technologically useful upper critical field if versions of MgCNi_3 with higher T_c can be found.

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L. D. Cooley, X. Song, J. Jiang, D. C. Larbalestier, T. He, K. A. Regan, R. J. Cava. 2001-08-28. Core pinning by intragranular nanoprecipitates in polycrystalline MgCNi_3. https://doi.org/10.1103/physrevb.65.214518

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