Search arXiv⌕ Search

arXiv · cond-mat/0409011

On a discussion about the determination of surface characteristics of microemulsion droplets from static and dynamic scattering experiments

Abstract

The interpretation of static and dynamic scattering experiments on droplet microemulsions is discussed. We review the arguments given in our previous papers that call into question the methods of current determination of basic phenomenological characteristics of the droplet surfactant monolayer, such as the bending and Gaussian rigidities. We give also responses to our criticism by T. Hellweg, B. Farago, M. Gradzielski, D. Langevin, and S. Safran (Colloids and Surfaces A 221 (2003) 257 and some other works by these authors). They agree with some of our objections; the rest of their response is shown to be flawed. We also show that in many points their way of discussion is improper and misleading. It is concluded that the values of the parameters of microemulsion droplets, as extracted in their experiments, are not reliable and should be reexamined.

Explore related subjects

Keep this discovery

Explore connections, maps & timelines

BibTeXRIS

V. Lisy. 2004-09-01. On a discussion about the determination of surface characteristics of microemulsion droplets from static and dynamic scattering experiments. https://arxiv.org/abs/cond-mat/0409011

Cite the original work for its findings. Save a collection to share your selection of sources.

KEEP EXPLORING

Related papers

Control of filament network rigidity by the condensation of crowding molecules

Understanding how liquid-liquid phase separation impacts the mechanics of filament networks is a fundamental physical problem at the heart of biological cellular processes and soft material design. While a few theoretical mechanisms have been proposed, a clear demonstration of the direct coupling of phase separation to the overall network stiffness is missing. We report experiments that reveal a universal mechanism by which the condensation of macromolecular crowders induces a rigidity transition in a model filament network. We reconstituted stiff sterically interacting helical filaments and polymeric crowders. Initially, the macromolecules were uniformly dissolved and the filaments formed bundles that assembled a rigid entangled network. Once the crowders condensed into droplets, the network structure lost its rigidity and its mechanical response weakened by an order-of-magnitude. The subsequent dissolution of the condensates was accompanied by the re-establishment of rigidity. Our results show that crowder phase separation modulates the mechanics of filament networks by tuning the osmotic pressure holding the network together. This principle may serve as a paradigm for devising dynamically tunable filamentous materials.

cond-mat.soft↗

Speed up of passive tracers in mixtures with active chemical reactions

Diffusivity of passive tracers in complex mixtures is widely relevant for industrial applications and for probing biological systems. Interactions with the surrounding medium typically generate a drag force that suppresses tracer diffusion, although self-propulsion can accelerate tracers via active fluctuations. Similar effects are not understood in mixtures with particle conversion and exchange, although these are particularly relevant in biological contexts, where actively driven reactions prevail. By studying a thermodynamically consistent model of chemical reactions in mixtures, we show that reactions provide an additional relaxation pathway that suppresses interaction-induced memory, reducing the drag on tracers and restoring their diffusivity toward the value expected in the absence of solutes. Moreover, active reactions generate nonequilibrium fluctuations that can push tracer diffusivity beyond this limit, an effect we confirm with particle-based simulations. Our results identify chemical activity as a distinct route to controlling mass transport and offer a framework for interpreting microrheology experiments in chemically active mixtures.

cond-mat.soft↗

Diffusion of charged rods across 3D varying section channels

We analyze the transport of rod-like particles by diffusion and drift in a three-dimensional channel with varying circular or elliptic cross section. Applying the Fick-Jacobs approximation to the transport equation of the particles' probability distribution, we derive an effective one-dimensional substitute model and the associated free energy profile. Our results show that the data for the mean first passage time of rods, once expressed as a function of the effective free energy barrier, collapse onto the same master curve as obtained for point or spherical particles. The observed universality provides a simple framework for predicting transport times of anisotropic particles in confined geometries without resolving the full multidimensional dynamics.

cond-mat.soft↗