arXiv subjects

David E. Harker

Publications and source records attributed to David E. Harker.

17 recordsLinked to original sources

arXiv2026

A JWST Study of Stardust. II. Polycyclic Aromatic Hydrocarbons in Comet 81P/Wild 2 and Implications for Primitive Solar System Carbon

We report observations of comet 81P/Wild 2, target of the Stardust sample return mission, on UT 2023 March 20 and 24 at a heliocentric distance ($r_H$) of 1.85 au using the NIRSpec and MIRI integral field unit spectrographs on board the James Webb Space Telescope (JWST). This study is the first compositional comparison between JWST remote-sensing spectroscopy of a solar system object against terrestrial analysis of its returned samples. Recent work determined contributions of molecular emission from coma volatiles and thermal emission from the nucleus and coma dust grains to these spectra. Subtracting the molecular and thermal emission models produces a residual spectrum with a clear resonance near 3.37 $μ$m and multiple others spanning the $6 - 12$ $μ$m region. Analysis of these residuals provides strong evidence for the presence of polycyclic aromatic hydrocarbons (PAHs) in the coma of 81P/Wild 2. The resulting PAH populations reflect material incorporated into the nucleus of 81P/Wild 2 that was inherited from the diffuse interstellar medium, the interstellar medium, and the protoplanetary disk. The PAHs sensed by JWST are compared to those detected in laboratory analyses of the Stardust mission returned samples.

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arXiv2026

JWST Spatial-Spectral Mapping of Green Comet C/2022 E3 (ZTF)

We report a survey of molecular emission from cometary volatiles using the James Webb Space Telescope (JWST) toward Oort cloud comet C/2022 E3 (ZTF) carried out on UT 2023 February 28 and March 1 at a heliocentric distance (rH) of 1.33 au. These measurements of H2O, HCN, CH3OH, C2H6, CH4, CO, CO2, 13CO2, and OCS sampled post-perihelion molecular chemistry in C/2022 E3. A suite of near to mid-infrared OH (prompt emission) transitions were also detected. This work presents nucleus-centered spectra for all detected species, spatial-spectral maps of column density and rotational temperature as a function of distance from the nucleus for all except C2H6, HCN, and OH, and maps of co-measured continuum. The spatial distributions of both quantities were anisotropic for all mapped molecules; however, H2O showed distributions distinct from the remaining species. Coma-averaged values of the ortho-to-para ratio (OPR) for H2O and the 12CO2/13CO2 ratio derived from these maps were consistent with the statistical equilibrium value of 3 and the terrestrial value of 89, respectively. The modeled mass fraction of the sub-micron dust grains is dominated by amorphous carbon (56%) followed by amorphous Mg:Fe pyroxene (28%), crystalline olivine (10%), and amorphous Mg:Fe olivine (5%) with a crystalline mass fraction of 0.2385(0.0008). We compare the volatile and dust composition of C/2022 E3 (ZTF) against comets measured to date, including those surveyed by JWST.

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arXiv2026

A JWST Study of Stardust. I. Infrared Spectroscopy of Comet 81P/Wild 2 and Overall Composition

We report observations of comet 81P/Wild 2, target of the Stardust sample return mission, on UT 2023 March 20 and 24 at a heliocentric distance ($r_H$) of 1.85 au using the NIRSpec and MIRI integral field unit spectrographs on board the James Webb Space Telescope (JWST). This study is the first compositional comparison between JWST remote-sensing spectroscopy of a solar system object against terrestrial analysis of its returned samples. We securely detected molecular emission from H$_2$O, CH$_4$, C$_2$H$_6$, CH$_3$OH, CO, CO$_2$, $^{13}$CO$_2$, OCS, HCN, and CN and find molecular abundances consistent within $2σ$ with those reported during previous perihelion passages. The water ortho-to-para ratio was $2.76\pm0.05$, and the $^{12}$CO$_2$/$^{13}$CO$_2$ ratio was $85\pm4$. Thermal emission from the nucleus and dust was detected and modeled, providing an effective nucleus radius of $1.77\pm0.04$ km and a dust composition (relative mass fraction of the submicron grains) of $\sim36\%$ amorphous carbon, $\sim25\%$ amorphous Mg:Fe olivine, $\sim23\%$ Mg-rich crystalline olivine, and $\sim15\%$ amorphous Mg:Fe pyroxene. The crystalline mass fraction of the sub-micron grains in the coma was $0.362\pm0.003$. Comparison of the JWST-derived thermal model against the fine-grained materials in Stardust returned samples demonstrates complementarity between the missions, with each most sensitive to a different population of the coma dust grains.

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arXiv2025

A JWST Study of the Remarkable Oort Cloud Comet C/2017 K2 (PanSTARRS)

Comets, during their journeys into the inner solar system, deliver volatile gases, organics, and particulates into their comae that provide crucial information for assessing the physico-chemical conditions in the outer disk from which they formed. Here we present observational and modeling results of a JWST NIRSpec and MIRI MRS integral-field-unit (IFU) spatial-spectral study of the inner coma of the Oort Cloud comet C/2017 K2 (PanSTARRS) at a heliocentric distance of 2.35 au. We find the comet is hyperactive (water ice active fraction greater than or equal to 86%), with a nucleus radius of $<$4.2 km, exhibiting strong emission from H$_{2}$O, $^{12}$CO, $^{13}$CO, and CO$_{2}$ as well as CN, H$_2$CO, CH$_3$OH, CH$_4$, C$_2$H$_6$, HCN, NH$_2$, and OH prompt emission. The water ortho-to-para ratio is greater than or equal to 2.75. The modeled dust composition (relative mass fraction of the sub-micron grains) in the coma is dominated by amorphous carbon ($\simeq 25$%), amorphous Mg:Fe olivine ($\simeq 19$%), amorphous Mg:Fe pyroxene ($\simeq 16$%), and Mg-rich crystalline olivine ($\simeq 39$%) and the crystalline mass fraction of the sub-micron grains in the coma is, $f_{cryst} \simeq 0.384 \pm 0.065$. Analysis of residuals in 3 to 8 $μ$m region of the spectral energy distribution strongly suggests the presence of polycyclic aromatic hydrocarbon (PAHs) species in the coma.

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arXiv2023

Dust Properties of Comets Observed by Spitzer

As comets journey into the inner solar system, they deliver particulates and volatile gases into their comae that reveal the most primitive materials in the solar system. Cometary dust particles provide crucial information for assessing the physico-chemical conditions in the outer disk from which they formed. Compared to the volatiles and soluble organics, the refractory dust particles are more robust and may be traceable to other small bodies. Using data from the Spitzer Heritage Archive, we present thermal dust models of 57 observations of 33 comets observed spectroscopically with the NASA Spitzer Space Telescope. This comet spectral survey offers the opportunity to study comets with data from the same instrument, reduced by the same methods, and fitted by the same thermal model using the same optical constants. The submicron dust tends to be dominated by amorphous carbon, and the submicron silicate mass tends to be dominated by amorphous silicate materials. We discuss the implications of these findings as they relate to Mg-rich crystalline silicates, which are high-temperature condensates, as well as to potential ion irradiation of amorphous Mg:Fe silicates prior to their incorporation into comets. These results impact our understandings of the protoplanetary disk conditions of planetesimal formation. Lastly, we cannot definitively conclude that a distinct difference exists in the dust composition between Oort cloud and Jupiter-family comet dynamical population as a whole.

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arXiv2020

The Coma Dust of Comet C2013 US10 (Catalina) A Window into Carbon in the Solar System

Comet C/2013 US10 (Catalina) was an dynamically new Oort cloud comet whose apparition presented a favorable geometry for observations near close Earth approach (~0.93au) at heliocentric distances ~2au when insolation and sublimation of volatiles drive maximum activity. Here we present mid-infrared spectrophotometric observations at two temporal epochs from NASA's Stratospheric Observatory for Infrared Astronomy and the NASA Infrared Telescope Facility. The grain composition is dominated by dark dust grains (modeled as amorphous carbon) with a silicate-to-carbon ratio ~0.9, little of crystalline stoichiometry (no distinct 11.2um feature attributed to Mg-rich crystalline olivine), the submicron grain size distribution peaking at ~0.6um. The 10um silicate feature was weak, ~12.8% above the local continuum, and the bolometric grain albedo was low (~14%). Comet Catalina is a carbon-rich object. This material, which is well-represented by the optical constants of amorphous carbon is similar to the material that darkens and reddens the surface of comet 67P/Churyumov-Gerasimenko. We argue this material is endemic the nuclei of comets, synthesizing results from the study of Stardust samples, interplanetary dust particle investigations and micrometeoritic analyses. The atomic carbon-to-silicate ratio of comet Catalina and other comets joins a growing body of evidence suggesting the existence of a C/Si gradient in the primitive solar system.

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arXiv2016

Mid-infrared spectra of comet nuclei

Jovian Trojan D-type asteroids have mid-infrared emissivity features strikingly similar to comet comae, suggesting that they have the same compositions and that the surfaces of the Trojans are highly porous. However, a direct comparison between a comet and asteroid surface has not been possible due to the paucity of spectra of comet nuclei at mid-infrared wavelengths. We present 5-35 μm thermal emission spectra of comets 10P/Tempel 2, and 49P/Arend-Rigaux observed with the Infrared Spectrograph on the Spitzer Space Telescope. Our analysis suggests the spectra are dominated by the comet nucleus. We fit each spectrum with the near-Earth asteroid thermal model (NEATM) and find sizes in agreement with previous values. However, the NEATM beaming parameters of the nuclei, 0.74 to 0.83, are systematically lower than the Jupiter-family comet population mean of 1.03+/-0.11, derived from 16- and 22-μm photometry. When the spectra are normalized by the NEATM model, a weak 10-μm silicate plateau is evident, with a shape similar to those seen in mid-infrared spectra of D-type asteroids. We compare, in detail, these comet nucleus emission features to those seen in spectra of the Jovian Trojan D-types (624) Hektor, (911) Agamemnon, and (1172) Aneas, as well as those seen in the spectra of seven comet comae. The comet comae present silicate features with two distinct shapes, either trapezoidal, or more rounded. The surfaces of Tempel 2, Arend-Rigaux, and Hektor best agree with the comae that present trapezoidal features. An emissivity minimum at 15 μm, present in the spectra of Tempel 2, Arend-Rigaux, Hektor, and Agamemnon, is also described, the origin of which remains unidentified. The compositional similarity between D-type asteroids and comets is discussed, and our data supports the hypothesis that they have similar origins in the early Solar System.

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arXiv2015

Cometary Science with the James Webb Space Telescope

The James Webb Space Telescope (JWST), as the largest space-based astronomical observatory with near- and mid-infrared instrumentation, will elucidate many mysterious aspects of comets. We summarize four cometary science themes especially suited for this telescope and its instrumentation: the drivers of cometary activity, comet nucleus heterogeneity, water ice in comae and on surfaces, and activity in faint comets and main-belt asteroids. With JWST, we can expect the most distant detections of gas, especially CO2, in what we now consider to be only moderately bright comets. For nearby comets, coma dust properties can be studied with their driving gases, measured simultaneously with the same instrument or contemporaneously with another. Studies of water ice and gas in the distant Solar System will help us test our understanding of cometary interiors and coma evolution. The question of cometary activity in main-belt comets will be further explored with the possibility of a direct detection of coma gas. We explore the technical approaches to these science cases and provide simple tools for estimating comet dust and gas brightness. Finally, we consider the effects of the observatory's non-sidereal tracking limits, and provide a list of potential comet targets during the first 5 years of the mission.

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arXiv2015

SOFIA Infrared Spectrophotometry of Comet C/2012 K1 (Pan-STARRS)

We present pre-perihelion infrared 8 to 31 micron spectrophotometric and imaging observations of comet C/2012 K1 (Pan-STARRS), a dynamically new Oort Cloud comet, conducted with NASA's Stratospheric Observatory for Infrared Astronomy (SOFIA) facility (+FORCAST) in 2014 June. As a "new" comet (first inner solar system passage), the coma grain population may be extremely pristine, unencumbered by a rime and insufficiently irradiated by the Sun to carbonize its surface organics. The comet exhibited a weak 10 micron silicate feature ~1.18 +/- 0.03 above the underlying best-fit 215.32 +/- 0.95 K continuum blackbody. Thermal modeling of the observed spectral energy distribution indicates that the coma grains are fractally solid with a porosity factor D = 3 and the peak in the grain size distribution, a_peak = 0.6 micron, large. The sub-micron coma grains are dominated by amorphous carbon, with a silicate-to-carbon ratio of 0.80 (+0.25) (- 0.20). The silicate crystalline mass fraction is 0.20 (+0.30) (-0.10), similar to with other dynamically new comets exhibiting weak 10 micron silicate features. The bolometric dust albedo of the coma dust is 0.14 +/- 0.01 at a phase angle of 34.76 degrees, and the average dust production rate, corrected to zero phase, at the epoch of our observations was Afrho ~ 5340~cm.

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arXiv2013

Absorption Efficiencies of Forsterite. I: DDA Explorations in Grain Shape and Size

We compute the absorption efficiency (Qabs) of forsterite using the discrete dipole approximation (DDA) in order to identify and describe what characteristics of crystal grain shape and size are important to the shape, peak location, and relative strength of spectral features in the 8-40 μm wavelength range. Using the DDSCAT code, we compute Qabs for non-spherical polyhedral grain shapes with a_eff = 0.1 μm. The shape characteristics identified are: 1) elongation/reduction along one of three crystallographic axes; 2) asymmetry, such that all three crystallographic axes are of different lengths; and 3) the presence of crystalline faces that are not parallel to a specific crystallographic axis, e.g., non-rectangular prisms and (di)pyramids. Elongation/reduction dominates the locations and shapes of spectral features near 10, 11, 16, 23.5, 27, and 33.5 μm, while asymmetry and tips are secondary shape effects. Increasing grain sizes (0.1-1.0 μm) shifts the 10, 11 μm features systematically towards longer wavelengths and relative to the 11 μm feature increases the strengths and slightly broadens the longer wavelength features. Seven spectral shape classes are established for crystallographic a-, b-, and c-axes and include columnar and platelet shapes plus non-elongated or equant grain shapes. The spectral shape classes and the effects of grain size have practical application in identifying or excluding columnar, platelet or equant forsterite grain shapes in astrophysical environs. Identification of the shape characteristics of forsterite from 8-40 μm spectra provides a potential means to probe the temperatures at which forsterite formed.

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arXiv2011

Infrared Spectroscopy of Comet 73P/Schwassmann-Wachmann 3 using the Spitzer Space Telescope

We have used the Spitzer Space Telescope Infrared Spectrograph (IRS) to observe the 5-37 micron thermal emission of comet 73P/Schwassmann-Wachmann 3 (SW3), components B and C. We obtained low spectral resolution (R ~ 100) data over the entire wavelength interval, along with images at 16 and 22 micron. These observations provided an unprecedented opportunity to study nearly pristine material from the surface and what was until recently the interior of an ecliptic comet - cometary surface having experienced only two prior perihelion passages, and including material that was totally fresh. The spectra were modeled using a variety of mineral types including both amorphous and crystalline components. We find that the degree of silicate crystallinity, ~ 35%, is somewhat lower than most other comets with strong emission features, while its abundance of amorphous carbon is higher. Both suggest that SW3 is among the most chemically primitive solar system objects yet studied in detail, and that it formed earlier or farther from the sun than the bulk of the comets studied so far. The similar dust compositions of the two fragments suggests that these are not mineralogically heterogeneous, but rather uniform throughout their volumes. Atomic abundances derived from the spectral models indicates a depletion of O compared to solar photospheric values, despite the inclusion of water ice and gas in the models. Atomic C may be solar or slightly sub-solar, but its abundance is complicated by the potential contribution of spectrally featureless mineral species to the portion of the spectra most sensitive to the derication of the C abundance. We find a relatively high bolometric albedo, ~ 0.13 for the dust, considering the large amount of dark carbonaceous material, but consistent with the presence of abundant small particles and strong emission features.

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arXiv2011

Dust in Comet C/2007 N3 (Lulin)

We report optical imaging, optical and near-infrared polarimetry, and Spitzer mid-infrared spectroscopy of comet C/2007 N3 (Lulin). Polarimetric observations were obtained in R (0.676 micron) at phase angles from 0.44 degrees to 21 degrees with simultaneous observations in H (1.65 micron) at 4.0 degrees, exploring the negative branch in polarization. Comet C/2007 N3 (Lulin) shows typical negative polarization in the optical as well as a similar negative branch near-infrared wavelengths. The 10 micron silicate feature is only weakly in emission and according to our thermal models, is consistent with emission from a mixture of silicate and carbon material. We argue that large, low-porosity (akin to Ballistic Particle Cluster Aggregates) rather absorbing aggregate dust particles best explain both the polarimetric and the mid-infrared spectral energy distribution.

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arXiv2010

Mid-Infrared Spectrophotometric Observations of Fragments B and C of Comet 73P/Schwassmann-Wachmann 3

We present mid-infrared spectra and images from the GEMINI-N (+Michelle) observations of fragments SW3-[B] and SW3-[C] of the ecliptic (Jupiter Family) comet 73P/Schwassmann-Wachmann 3 pre-perihelion. We observed fragment B soon after an outburst event (between 2006 April 16 - 26 UT) and detected crystalline silicates. The mineralogy of both fragments was dominated by amorphous carbon and amorphous pyroxene. The grain size distribution (assuming a Hanner modified power-law) for fragment SW3-[B] has a peak grain radius of a_p ~ 0.5 micron, and for fragment SW3-[C], a_p ~ 0.3 micron; both values larger than the peak grain radius of the size distribution for the dust ejected from ecliptic comet 9P/Tempel 1 during the Deep Impact event (a_p = 0.2 micron. The silicate-to-carbon ratio and the silicate crystalline mass fraction for the submicron to micron-size portion of the grain size distribution on the nucleus of fragment SW3-[B] was 1.341 +0.250 -0.253 and 0.335 +0.089 -0.112, respectively, while on the nucleus of fragment SW3-[C] was 0.671 +0.076 -0.076 and 0.257 +0.039 -0.043, respectively. The similarity in mineralogy and grain properties between the two fragments implies that 73P/Schwassmann-Wachmann 3 is homogeneous in composition. The slight differences in grain size distribution and silicate-to-carbon ratio between the two fragments likely arises because SW3-[B] was actively fragmenting throughout its passage while the activity in SW3-[C] was primarily driven by jets. The lack of diverse mineralogy in the fragments SW3-[B] and SW3-[C] of 73P/Schwassmann-Wachmann 3 along with the relatively larger peak in the coma grain size distribution suggests the parent body of this comet may have formed in a region of the solar nebula with different environmental properties than the natal sites where comet C/1995 O1 (Hale-Bopp) and 9P/Tempel 1 nuclei aggregated.

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arXiv2009

Spitzer Observations of Comet 67P/Churyumov-Gerasimenko at 5.5-4.3 AU From the Sun

We report Spitzer Space Telescope observations of comet 67P/Churyumov-Gerasimenko at 5.5 and 4.3 AU from the Sun, post-aphelion. Comet 67P is the primary target of the European Space Agency's Rosetta mission. The Rosetta spacecraft will rendezvous with the nucleus at heliocentric distances similar to our observations. Rotationally resolved observations at 8 and 24 microns (at a heliocentric distance, rh, of 4.8 AU) that sample the size and color-temperature of the nucleus are combined with aphelion R-band light curves observed at the Very Large Telescope (VLT) and yield a mean effective radius of 2.04 +/- 0.11 km, and an R-band geometric albedo of 0.054 +/- 0.006. The amplitudes of the R-band and mid-infrared light curves agree, which suggests that the variability is dominated by the shape of the nucleus. We also detect the dust trail of the comet at 4.8 and 5.5 AU, constrain the grain sizes to be less than or similar to 6 mm, and estimate the impact hazard to Rosetta. We find no evidence for recently ejected dust in our images. If the activity of 67P is consistent from orbit to orbit, then we may expect the Rosetta spacecraft will return images of an inactive or weakly active nucleus as it rendezvous with the comet at rh = 4 AU in 2014.

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arXiv2006

A Spitzer Study of Comets 2P/Encke, 67P/Churyumov-Gerasimenko, and C/2001 HT50 (LINEAR-NEAT)

We present infrared images and spectra of comets 2P/Encke, 67P/Churyumov-Gerasimenko, and C/2001 HT50 (LINEAR-NEAT) as part of a larger program to observe comets inside of 5 AU from the sun with the Spitzer Space Telescope. The nucleus of comet 2P/Encke was observed at two vastly different phase angles (20 degrees and 63 degrees). Model fits to the spectral energy distributions of the nucleus suggest comet Encke's infrared beaming parameter derived from the near-Earth asteroid thermal model may have a phase angle dependence. The observed emission from comet Encke's dust coma is best-modeled using predominately amorphous carbon grains with a grain size distribution that peaks near 0.4 microns, and the silicate contribution by mass to the sub-micron dust coma is constrained to 31%. Comet 67P/Churyumov-Gerasimenko was observed with distinct coma emission in excess of a model nucleus at a heliocentric distance of 5.0 AU. The coma detection suggests that sublimation processes are still active or grains from recent activity remain near the nucleus. Comet C/2001 HT50 (LINEAR-NEAT) showed evidence for crystalline silicates in the spectrum obtained at 3.2 AU and we derive a silicate-to-carbon dust ratio of 0.6. The ratio is an order of magnitude lower than that derived for comets 9P/Tempel 1 during the Deep Impact encounter and C/1995 O1 (Hale-Bopp).

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arXiv2004

The Disk Atmospheres of Three Herbig Ae/Be Stars

We present infrared (IR) spectrophotometry ($R \simeq 180$) of three Herbig Ae/Be stars surrounded by possible protoplanetary disks: HD 150193, HD100546 and HD 179218. We construct a mid-IR spectral energy distributions (SED) for each object by using $7.6 - 13.2$ \micron HIFOGS spectra, 2.4 -- 45 \micron\ spectrophotometry from the {\it ISO} SWS, the 12, 25, 60, and 100 \micron\ photometric points from IRAS, and for HD 179218, photometric bolometric data points from the Mt. Lemmon Observing Facility. The SEDs are modeled by using an expanded version of the \citet{chigol97} two-layer, radiative and hydrostatic equilibrium, passive disk. This expanded version includes the emission from Mg-pure crystalline olivine (forsterite) grains in the disk surface layer. HD 150193 contains no crystals while HD 100546 and HD 179218 respectively show evidence of having crystalline silicates in the surface layers of their disks. We find that the inner region of HD100546 has a 37% higher crystalline-to-amorphous silicate ratio in its inner disk region ($\leq 5$ AU) compared to the outer disk region, while the inner disk region of HD 179218 has a 84% higher crystalline-to-amorphous silicate ratio in its inner disk region ($\leq 5$ AU) compared to the outer region. HD 150193 is best-fit by a small disk ($\sim 5$ AU in radius) while HD 100546 and HD 179218 are best fit by larger disks ($\sim 150$ AU in radius).

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arXiv2001

Annealing of Silicate Dust by Nebular Shocks at 10 AU

Silicate dust grains in the interstellar medium are known to be mostly amorphous, yet crystalline silicate grains have been observed in many long-period comets and in protoplanetary disks. Annealing of amorphous silicate grains into crystalline grains requires temperatures > 1000 K, but exposure of dust grains in comets to such high temperatures is incompatible with the generally low temperatures experienced by comets. This has led to the proposal of models in which dust grains were thermally processed near the protoSun, then underwent considerable radial transport until they reached the gas giant planet region where the long-period comets originated. We hypothesize instead that silicate dust grains were annealed in situ, by shock waves triggered by gravitational instabilities. We assume a shock speed of 5 km/s, a plausible value for shocks driven by gravitational instabilities. We calculate the peak temperatures of micron and submicron amorphous pyroxene grains of chondritic composition under conditions typical in protoplanetary disks at 5 - 10 AU. Our results also apply to chondritic amorphous olivine grains. We show that {\it in situ} thermal annealing of submicron and micron-sized silicate dust grains can occur, obviating the need for large-scale radial transport.

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