arXiv subjects

David Moore

Publications and source records attributed to David Moore.

13 recordsLinked to original sources

arXiv2025

Offset geometry for extended field-of-view in multi-contrast and multi-scale X-ray microtomography of lung cancer lobectomy specimens

X-ray microtomography is a powerful non-destructive technique allowing 3D virtual histology of resected human tissue. The achievable imaging field-of-view, is however limited by the fixed number of detector elements, enforcing the requirement to sacrifice spatial resolution in order to image larger samples. In applications such as soft-tissue imaging, phase-contrast methods are often employed to enhance image contrast. Some of these methods, especially those suited to laboratory sources, rely on optical elements, the dimensions of which can impose a further limitation on the field-of-view. We describe an efficient method to double the maximum field-of-view of a cone-beam X-ray microtomography system, without sacrificing on spatial resolution, and including multi-contrast capabilities. We demonstrate an experimental realisation of the method, achieving exemplary reconstructions of a resected human lung sample, with a cubic voxel of 10.5 $\mu$m linear dimensions, across a horizontal field-of-view of 4.3 cm. The same concepts are applied to free-space propagation imaging of a 2.7 mm segment of the same sample, achieving a cubic voxel of 450 nm linear dimensions. We show that the methodology can be applied at a range of different length-scales and geometries, and that it is directly compatible with complementary implementations of X-ray phase-contrast imaging.

physics.med-ph↗

arXiv2025

A combined statistical mechanical and ab initio approach to understanding H2O/CO2 co-adsorption in mmen-Mg2(dobpdc)

We study the effects of H2O on CO2 adsorption in an amine-appended variant of the metal-organic framework Mg2(dobpdc), which is known to exhibit chaining behavior that presents in a step-shaped adsorption isotherm. We first show how the presence of different levels of local H2O affects this chaining behavior and the energetics of CO2 adsorption, based on a series of ab initio calculations, giving insight into the atomic-scale environment. In particular, we predict a novel adsorbed configuration, in which H2O and CO2 intertwine to make a braided chain down the MOF pore. We then show how an existing lattice model can be adapted to incorporate the effect of water, and predict the CO2 isotherms for the various water levels, observing a sharp shift the uptake at low partial pressures. The manifestation of this braided chain in the lattice model points to the potential emergence of a shift from cooperative capture to that of a phase transition. In addition to the physical insights, this work may serve as a launching off point for further work on this and related materials.

cond-mat.mtrl-sci↗

arXiv2024

Low-energy pathways lead to self-healing defects in CsPbBr$_3$

Self-regulation of free charge carriers in perovskites via Schottky defect formation has been posited as the origin of the well-known defect tolerance of metal halide perovskite materials that are promising candidates for photovoltaic applications, like solar cells. Understanding the mechanisms of self-regulation, here for a representative of more commercially viable all-inorganic perovskites, promises to lead to the fabrication of better-performing solar cell materials with higher efficiencies. We investigated different mechanisms and pathways of the diffusion and recombination of interstitials and vacancies (Schottky pairs) in CsPbBr$_3$. We use Nudged Elastic Band calculations and ab initio-derived pseudopotentials within Quantum ESPRESSO to determine energies of formation, migration, and activation for these defects. Our calculations uncover defect pathways capable of producing an activation energy at or below the value of 0.53~eV observed for the slow, temperature-dependent recovery of light-induced conductivity in CsPbBr$_3$. Our work reveals the existence of a low-energy diffusion pathway involving a concerted "domino effect" interstitial mechanism, with the net result that interstitials can diffuse more readily over long distances than expected. Importantly, this observation suggests that defect self-healing can be promoted if the "domino effect" strategy can be engaged.

cond-mat.mtrl-sci↗

arXiv2023

Quantum Information Science and Technology for Nuclear Physics. Input into U.S. Long-Range Planning, 2023

In preparation for the 2023 NSAC Long Range Plan (LRP), members of the Nuclear Science community gathered to discuss the current state of, and plans for further leveraging opportunities in, QIST in NP research at the Quantum Information Science for U.S. Nuclear Physics Long Range Planning workshop, held in Santa Fe, New Mexico on January 31 - February 1, 2023. The workshop included 45 in-person participants and 53 remote attendees. The outcome of the workshop identified strategic plans and requirements for the next 5-10 years to advance quantum sensing and quantum simulations within NP, and to develop a diverse quantum-ready workforce. The plans include resolutions endorsed by the participants to address the compelling scientific opportunities at the intersections of NP and QIST. These endorsements are aligned with similar affirmations by the LRP Computational Nuclear Physics and AI/ML Workshop, the Nuclear Structure, Reactions, and Astrophysics LRP Town Hall, and the Fundamental Symmetries, Neutrons, and Neutrinos LRP Town Hall communities.

nucl-ex↗

arXiv2022

Snowmass White Paper: Precision Studies of Spacetime Symmetries and Gravitational Physics

High-energy physics is primarily concerned with uncovering the laws and principles that govern nature at the fundamental level. Research in this field usually relies on probing the boundaries of established physics, an undertaking typically associated with extreme energy and distance scales. It is therefore unsurprising that particle physics has traditionally been dominated by large-scale experimental methods often involving high energies, such as colliders and storage rings, cosmological and astrophysical observations, large-volume detector systems, etc. However, high-sensitivity measurements in smaller experiments, often performed at lower energies, are presently experiencing a surge in importance for particle physics for at least two reasons. First, they exploit synergies to adjacent areas of physics with recent advances in experimental techniques and technology. Together with intensified phenomenological explorations, these advances have led to the realization that challenges associated with weak couplings or the expected suppression factors for new physics can be overcome with such methods while maintaining a large degree of experimental control. Second, many of these measurements broaden the range of particle-physics phenomena and observables relative to the above set of more conventional methodologies. Combining such measurements with the conventional efforts above therefore casts both a wider and tighter net for possible effects originating from physics beyond the Standard Model (BSM). This paper argues that this assessment points at a growing impact of such methods and measurements on high-energy physics, and therefore warrants direct support as particle-physics research. Leveraging the recent rapid progress and bright outlook associated with such studies for high-energy physics, could yield high returns, but requires substantial and sustained efforts by funding agencies.

hep-ex↗

arXiv2022

High throughput data-driven design of laser crystallized 2D MoS2 chemical sensors

High throughput characterization and processing techniques are becoming increasingly necessary to navigate multivariable, data-driven design challenges for sensors and electronic devices. For two-dimensional materials, device performance is highly dependent upon a vast array of material properties including number of layers, lattice strain, carrier concentration, defect density, and grain structure. In this work, laser-crystallization was used to locally pattern and transform hundreds of regions of amorphous MoS2 thin films into 2D 2H-MoS2. A high throughput Raman spectroscopy approach was subsequently used to assess the process-dependent structural and compositional variations for each illuminated region, yielding over 5500 distinct non-resonant, resonant, and polarized Raman spectra. The rapid generation of a comprehensive library of structural and compositional data elucidated important trends between structure-property-processing relationships involving laser-crystallized MoS2, including the relationships between grain size, grain orientation, and intrinsic strain. Moreover, extensive analysis of structure/property relationships allowed for intelligent design, and evaluation of major contributions to, device performance in MoS2 chemical sensors. In particular, it is found that sensor performance is strongly dependent on the orientation of the MoS2 grains relative to the crystal plane.

cond-mat.mtrl-sci↗

arXiv2021

Scalable synthesis of 2D van der Waals superlattices

Heterostructure materials form the basis of much of modern electronics, from transistors to lasers and light-emitting diodes. Recent years have seen a renewed focus on creating heterostructures through the vertical integration of two-dimensional materials, including graphene, hexagonal boron nitride, and transition metal dichalcogenides (TMDCs). However, fundamental challenges associated with materials processing have limited material quality and impeded scalability. We demonstrate a method to convert sub-nanometer metal films deposited on silicon and sapphire into TMDC heterostructures through vapor-phase processing. The resulting heterostructures and superlattices exhibit novel properties compared with stand-alone TMDCs, including reduced bandgap, enhanced light-matter coupling, and improved catalytic performance. This robust and scalable synthetic method provides new opportunities to generate a wide range of artificially stacked 2D superlattices with controlled morphology and composition.

cond-mat.mtrl-sci↗

arXiv2016

Vibrational Signatures in the THz Spectrum of 1,3-DNB: A First-Principles and Experimental Study

Understanding the fundamental processes of light-matter interaction is important for detection of explosives and other energetic materials, which are active in the infrared and terahertz (THz) region. We report a comprehensive study on electronic and vibrational lattice properties of structurally similar 1,3-dinitrobenzene (1,3- DNB) crystals through first-principles electronic structure calculations and THz spectroscopy measurements on polycrystalline samples. Starting from reported x-ray crystal structures, we use density-functional theory (DFT) with periodic boundary conditions to optimize the structures and perform linear response calculations of the vibrational properties at zero phonon momentum. The theoretically identified normal modes agree qualitatively with those obtained experimentally in a frequency range up to 2.5 THz and quantitatively at much higher frequencies. The latter frequencies are set by intra-molecular forces. Our results suggest that van der Waals dispersion forces need to be included to improve the agreement between theory and experiment in the THz region, which is dominated by intermolecular modes and sensitive to details in the DFT calculation. An improved comparison is needed to assess and distinguish between intra- and intermolecular vibrational modes characteristic of energetic materials.

cond-mat.mtrl-sci↗

arXiv2015

New Limits on Polarized Power Spectra at 126 and 164 MHz: Relevance to Epoch of Reionization Measurements

Polarized foreground emission is a potential contaminant of attempts to measure the fluctuation power spectrum of highly redshifted 21 cm HI emission from the epoch of reionization. Using the Donald C. Backer Precision Array for Probing the Epoch of Reionization (PAPER), we present limits on the observed power spectra of all four Stokes parameters in two frequency bands, centered at 126 MHz ($z=10.3$) and 164 MHz ($z=7.66$) for a three-month observing campaign of a 32-antenna deployment, for which unpolarized power spectrum results have been reported at $z=7.7$ (Parsons et al 2014) and $7.5 < z < 10.5$ (Jacobs et al 2014). The power spectra in this paper are processed in the same way as in those works, and show no definitive detection of polarized power. This non-detection appears to be largely due to the suppression of polarized power by ionospheric rotation measure fluctuations, which strongly affect Stokes Q and U. We are able to show that the net effect of polarized leakage is a negligible contribution at the levels of of the limits reported in Parsons et al 2014 and Jacobs et al 2014.

astro-ph.CO↗

arXiv2014

An RF-only ion-funnel for extraction from high-pressure gases

An RF ion-funnel technique has been developed to extract ions from a high-pressure (10 bar) noble-gas environment into vacuum ($10^{-6}$ mbar). Detailed simulations have been performed and a prototype has been developed for the purpose of extracting $^{136}$Ba ions from Xe gas with high efficiency. With this prototype, ions have been extracted for the first time from high-pressure xenon gas and argon gas. Systematic studies have been carried out and compared to the simulations. This demonstration of extraction of ions with mass comparable to that of the gas generating the high-pressure into vacuum has applications to Ba tagging from a Xe-gas time-projection chamber (TPC) for double beta decay as well as to the general problem of recovering trace amounts of an ionized element in a heavy (m$>40$ u) carrier gas.

physics.ins-det↗

arXiv2010

ARCONS: A highly multiplexed superconducting optical to near-IR camera

We report on the development of ARCONS, the ARray Camera for Optical to Near-IR Spectrophotometry. This photon counting integral field unit (IFU), being built at UCSB and Caltech with detectors fabricated at JPL, will use a unique, highly multiplexed low temperature detector technology known as Microwave Kinetic Inductance Detectors (MKIDs). These detectors, which operate at 100 mK, should provide photon counting with energy resolution of R = E/{\delta}E > 20 and time resolution of a microsecond, with a quantum efficiency of around 50%. We expect to field the instrument at the Palomar 200" telescope in the first quarter of 2011 with an array containing 1024 pixels in a 32x32 pixel form factor to yield a field of view of approximately 10x10 arcseconds. The bandwidth of the camera is limited by the rising sky count rate at longer wavelengths, but we anticipate a bandwidth of 0.35 to 1.35 {\mu}m will be achievable. A simple optical path and compact dewar utilizing a cryogen-free adiabatic demagnetization refridgerator (ADR) allows the camera to be deployed quickly at Naysmith or Coude foci at a variety of telescopes. A highly expandable software defined radio (SDR) readout that can scale up to much larger arrays has been developed.

astro-ph.IM↗

arXiv2001

Operational quantum logic: An overview

The term quantum logic has different connotations for different people, having been considered as everything from a metaphysical attack on classical reasoning to an exercise in abstract algebra. Our aim here is to give a uniform presentation of what we call operational quantum logic, highlighting both its concrete physical origins and its purely mathematical structure. To orient readers new to this subject, we shall recount some of the historical development of quantum logic, attempting to show how the physical and mathematical sides of the subject have influenced and enriched one another.

quant-ph↗

arXiv2000

Operational Galois adjunctions

We present a detailed synthetic overview of the utilisation of categorical techniques in the study of order structures together with their applications in operational quantum theory. First, after reviewing the notion of residuation and its implementation at the level of quantaloids we consider some standard universal constructions and the extension of adjunctions to weak morphisms. Second, we present the categorical formulation of closure operators and introduce a hierarchy of contextual enrichments of the quantaloid of complete join lattices. Third, we briefly survey physical state-property duality and the categorical analysis of derived notions such as causal assignment and the propagation of properties.

quant-ph↗