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Dominic Samra

Publications and source records attributed to Dominic Samra.

15 recordsLinked to original sources
arXiv2026

Wet Removal and Cloud Enhancement: The Microphysics of Cloud-Haze Interactions on Sub-Neptunes

Aerosols are a near-ubiquitous feature of sub-Neptune atmospheres, yet their microphysical nature remains poorly understood. Both condensate clouds and photochemical hazes have been proposed to explain observations, but have largely been studied in isolation. Here we present a new bin-scheme microphysical model, adapted from CARMA, that couples cloud and haze formation through heterogeneous nucleation - the dominant mode of cloud formation in the Solar System - in which haze particles act as cloud condensation nuclei (CCN). Applying this model to KCl clouds on GJ 1214 b-like warm sub-Neptunes, we find that the microphysical contact angle $\theta$ between cloud and haze particles governs distinct regimes of aerosol behavior: at moderate contact angles ($25^\circ \lesssim \theta \lesssim 70^\circ$), hazes are efficiently removed from the upper atmosphere through "wet removal" as they seed gravitationally-settling clouds; at small contact angles ($\theta \lesssim 25^\circ$), heterogeneous nucleation instead produces an enhanced population of mixed cloud-haze particles at high altitudes, dramatically increasing aerosol optical depth ("cloud enhancement"). These structural changes produce differences of up to four scale heights in transmission spectra, with strong effects at optical and near-infrared wavelengths relevant to JWST NIRISS/SOSS, while wavelengths beyond about 3 microns remain comparatively unaffected. We map these effects across orders of magnitude in metallicity, haze production rate, and vertical mixing strength, establishing their generality across sub-Neptune parameter space. Because heterogeneous nucleation is a universal phase-change process, this framework extends naturally to other exoplanet atmospheres and potentially any astrophysical environments where condensation onto foreign substrates may occur, including protoplanetary disks and stellar outflows.

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arXiv2026

Phase-dependent chemistry of WASP-43 b revealed with a suite of one-, two-, and three-dimensional models

Our goal is to investigate the chemistry of the hot Jupiter WASP-43 b in detail using theoretical models, considering the constraints of the James Webb Space Telescope MIRI phase curve. With a suite of pseudo-two-dimensional and three-dimensional photochemical models, we simulate the composition of WASP-43 b in various configurations, and compare them with atmospheric retrieval models. We confirm that disequilibrium chemistry in our theoretical models reduces the methane concentration on the planet night side for wind jet speeds > 500 m/s. Varying the metallicity in the models induces large changes in the CO$_2$ and SO$_2$ concentrations, with SO$_2$ producing mid-infrared absorption features in synthetic emission spectra of the night side at atmospheric metallicities > 10x solar. Our models provide evidence for pole-to-equator circulation enhancing the CH$_4$, NH$_3$, and HCN abundances, which is nonetheless insufficient for detectable spectral features. Finally, we show that H$_2$O, CO, and CO$_2$ are robustly modeled, but species affected by photochemistry are more sensitive to model-specific assumptions and pathways. We conclude that horizontal quenching is the prime mechanism that explains the non-detection of methane in the MIRI phase-curve of WASP-43 b. This mechanism requires only moderate wind speeds and is operative at various thermal structures and atmospheric metallicities. Furthermore, coupled carbon-sulfur chemistry leads to an additional decrease in methane compared to previous models in the literature that did not contain sulfur chemistry. We do not favor a high metallicity as it would have led to observable SO$_2$ features in the MIRI spectra. Our study shows that phase-dependent photochemistry models are essential tools in the interpretation of hot-Jupiter phase curves, but benchmarking is needed to improve the accuracy of photochemical models in the future.

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arXiv2026

CARMApy: An Open-Source Python Framework for Simulating Microphysical Clouds in Planetary Atmospheres

CARMApy is a new open-source python code that performs bin-scheme microphysical modeling of clouds in exoplanet atmospheres. It models key cloud properties such as particle size distributions and microphysical rates from first principles. The code is a wrapper of ExoCARMA, a well tested Fortran code with an almost half century long heritage. CARMApy includes the microphysical processes of homogeneous and heterogeneous nucleation, condensational growth, evaporation, coagulation, and vertical transport. CARMApy has 10 built-in default condensates and allows the user to specify additional condensates. In this work we describe CARMApy and the data products that it can generate, along with the history of its code heritage. We additionally compile a complete description of the theory and methods used in CARMA. Lastly we benchmark CARMApy and show that its results are consistent with previous versions of CARMA, while executing the code ~1.9 times faster single threaded ~3.8 times faster multithreaded.

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arXiv2026

Cloudy With a Chance of Meatballs

Speculative fiction has long served an inspiration for genuine scientific inquiry. One notable work that has almost acted in this manner is the the seminal comedic speculative fiction work Cloudy with a Chance of Meatballs. While exoplaneteers reference this work frequently, we have never engaged with the central prediction of this work... until now! We perform detailed microphysical modeling of meatball clouds, both bare and coated with marinara sauce, and find that while meatball condensation is possible in temperate atmospheres, the meatballs do not quite grow to the sizes predicted by Cloudy. We do find, however, that such meatball condensation, across a large enough planet, would be able to sustain humanity calorically.

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arXiv2025

Limb Asymmetries on WASP-39b: A Multi-GCM Comparison of Chemistry, Clouds, and Hazes

With JWST, observing separate spectra of the morning and evening limbs of hot Jupiters has finally become a reality. The first such observation was reported for WASP-39b, where the evening terminator was observed to have a larger transit radius by about 400 ppm and a stronger 4.3 $\mu$m CO$_2$ feature than the morning terminator. Multiple factors, including temperature differences, photo/thermochemistry, clouds and hazes, could cause such limb asymmetries. To interpret these new limb asymmetry observations, a detailed understanding of how the relevant processes affect morning and evening spectra grounded in forward models is needed. Focusing on WASP-39b, we compare simulations from five different general circulation models (GCMs), including one simulating disequilibrium thermochemistry and one with cloud radiative feedback, to the recent WASP-39b limb asymmetry observations. We also post-process the temperature structures of all simulations with a 2D photochemical model and one simulation with a cloud microphysics model. Although the temperatures predicted by the different models vary considerably, the models are remarkably consistent in their predicted morning--evening temperature differences. Several equilibrium-chemistry simulations predict strong methane features in the morning spectrum, not seen in the observations. When including disequilibrium processes, horizontal transport homogenizes methane, and these methane features disappear. However, even after including photochemistry and clouds, our models still cannot reproduce the observed ${\sim}2000$ ppm asymmetry in the CO$_2$ feature. A combination of factors, such as varying metallicity and unexplored parameters in cloud models, may explain the discrepancy, emphasizing the need for future models integrating cloud microphysics and feedback across a broader parameter space.

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arXiv2024

Under the magnifying glass: A combined 3D model applied to cloudy warm Saturn type exoplanets around M-dwarfs

Warm Saturn type exoplanets orbiting M-dwarfs are particularly suitable for in-depth cloud characterisation through transmission spectroscopy due to their favourable stellar to planetary radius contrast. However, modelling cloud formation consistently within the 3D atmosphere remains computationally challenging. The aim is to explore the combined atmospheric and micro-physical cloud structure, and the kinetic gas-phase chemistry for the warm Saturn HATS0-6b orbiting an M-dwarf. A combined 3D cloudy atmosphere model is constructed by iteratively executing the 3D General Circulation Model (GCM) expeRT/MITgcm and a kinetic cloud formation model, each in its full complexity. Resulting cloud particle number densities, sizes, and compositions are used to derive the local cloud opacity which is then utilised in the next GCM iteration. The disequilibrium H/C/O/N gas-phase chemistry is calculated for each iteration to assess the resulting transmission spectrum in post-processing. The cloud opacity feedback causes a temperature inversion at the sub-stellar point and at the evening terminator at gas pressures higher than 0.01 bar. Furthermore, clouds cool the atmosphere between 0.01 bar and 10 bar, and narrow the equatorial wind jet. The transmission spectrum shows muted gas-phase absorption and a cloud particle silicate feature at approximately 10 micron. The combined atmosphere-cloud model retains the full physical complexity of each component and therefore enables a detailed physical interpretation with JWST NIRSpec and MIRI LRS observational accuracy. The model shows that warm Saturn type exoplanets around M-dwarfs are ideal candidates to search for limb asymmetries in clouds and chemistry, identify cloud particle composition by observing their spectral features, and identify the cloud-induced strong thermal inversion that arises on these planets specifically.

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arXiv2024

Why heterogeneous cloud particles matter: Iron-bearing species and cloud particle morphology affects exoplanet transmission spectra

The possibility of observing spectral features in exoplanet atmospheres with space missions like JWST and ARIEL necessitates the accurate modelling of cloud particle opacities. In exoplanet atmospheres, cloud particles can be made from multiple materials and be considerably chemically heterogeneous. Therefore, assumptions on the morphology of cloud particles are required to calculate their opacities. The aim of this work is to analyse how different approaches to calculate the opacities of heterogeneous cloud particles affect cloud particle optical properties. We calculate cloud particle optical properties using seven different mixing treatments: four effective medium theories (EMTs: Bruggeman, Landau-Lifshitz-Looyenga (LLL), Maxwell-Garnett, and Linear), core-shell, and two homogeneous cloud particle approximations. We study the mixing behaviour of 21 commonly considered cloud particle materials for exoplanets. To analyse the impact on observations, we study the transmission spectra of HATS-6b, WASP-39b, WASP-76b, and WASP-107b.Materials with large refractive indices, like iron-bearing species or carbon, can change the optical properties of cloud particles when they comprise less than 1\% of the total particle volume. The mixing treatment of heterogeneous cloud particles also has an observable effect on transmission spectroscopy. Assuming core-shell or homogeneous cloud particles results in less muting of molecular features and retains the cloud spectral features of the individual cloud particle materials. The predicted transit depth for core-shell and homogeneous cloud particle materials are similar for all planets used in this work. If EMTs are used, cloud spectral features are broader and cloud spectral features of the individual cloud particle materials are not retained. Using LLL leads to less molecular features in transmission spectra compared to Bruggeman.

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arXiv2024

Inhomogeneous terminators on the exoplanet WASP-39 b

Transmission spectroscopy has been a workhorse technique over the past two decades to constrain the physical and chemical properties of exoplanet atmospheres. One of its classical key assumptions is that the portion of the atmosphere it probes -- the terminator region -- is homogeneous. Several works in the past decade, however, have put this into question for highly irradiated, hot ($T_{eq}\gtrsim 1000$ K) gas giant exoplanets both empirically and via 3-dimensional modelling. While models predict clear differences between the evening (day-to-night) and morning (night-to-day) terminators, direct morning/evening transmission spectra in a wide wavelength range has not been reported for an exoplanet to date. Under the assumption of precise and accurate orbital parameters on WASP-39 b, here we report the detection of inhomogeneous terminators on the exoplanet WASP-39 b, which allows us to retrieve its morning and evening transmission spectra in the near-infrared ($2-5\ \mu$m) using JWST. We observe larger transit depths in the evening which are, on average, $405 \pm 88$ ppm larger than the morning ones, also having qualitatively larger features than the morning spectrum. The spectra are best explained by models in which the evening terminator is hotter than the morning terminator by $177^{+65}_{-57}$ K with both terminators having C/O ratios consistent with solar. General circulation models (GCMs) predict temperature differences broadly consistent with the above value and point towards a cloudy morning terminator and a clearer evening terminator.

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arXiv2023

Modelling reflected polarised light from close-in giant exoplanet WASP-96b using PolHEx (Polarisation of Hot Exoplanets)

We present the Polarisation of Hot Exoplanets (PolHEx) code for modelling the total flux (F) and degree of linear polarisation (P) of light spectra reflected by close-in, tidally locked exoplanets. We use the output from a global climate model (GCM) combined with a kinetic cloud model of hot Jupiter WASP-96b as a base to investigate effects of atmospheric longitudinal-latitudinal inhomogeneities on these spectra. We model F and P-spectra as functions of wavelength and planet orbital phase for various model atmospheres. We find different materials and sizes of cloud particles to impact the reflected flux F, and particularly the linear polarisation state P. A range of materials are used to form inhomogeneous mixed-material cloud particles (Al2O3, Fe2O3, Fe2SiO4, FeO, Fe, Mg2SiO4, MgO, MgSiO3, SiO2, SiO, TiO2), with Fe2O3, Fe, and FeO the most strongly absorbing species. The cloud particles near the relatively cool morning terminator are expected to have smaller average sizes and a narrower size distribution than those near the warmer evening terminator, which leads to different reflected spectra at the respective orbital phases .We also find differences in the spectra of F and P as functions of orbital phase for irregularly or spherically shaped cloud particles. This work highlights the importance of including polarisation in models and future observations of the reflection spectra of exoplanets.

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arXiv2023

WASP-39b: exo-Saturn with patchy cloud composition, moderate metallicity, and underdepleted S/O

WASP-39b is one of the first extrasolar giant gas planets that has been observed within the JWST ERS program. Fundamental properties that may enable the link to exoplanet formation differ amongst retrieval methods, for example metallicity and mineral ratios. In this work, the formation of clouds in the atmosphere of WASP-39b is explored to investigate how inhomogeneous cloud properties (particle sizes, material composition, opacity) may be for this intermediately warm gaseous exoplanet. WASP-39b's atmosphere has a comparable day-night temperature median with sufficiently low temperatures that clouds may form globally. The presence of clouds on WASP-39b can explain observations without resorting to a high (> 100x solar) metallicity atmosphere for a reduced vertical mixing efficiency. The assessment of mineral ratios shows an under-depletion of S/O due to condensation compared to C/O, Mg/O, Si/O, Fe/O ratios. Vertical patchiness due to heterogeneous cloud composition challenges simple cloud models. An equal mixture of silicates and metal oxides is expected to characterise the cloud top. Further, optical properties of Fe and Mg silicates in the mid-infrared differ significantly which will impact the interpretation of JWST observations. We conclude that WASP-39b's atmosphere contains clouds and the underdepletion of S/O by atmospheric condensation processes suggest the use of sulphur gas species as a possible link to primordial element abundances. Over-simplified cloud models do not capture the complex nature of mixed-condensate clouds in exoplanet atmospheres. The clouds in the observable upper atmosphere of WASP-39b are a mixture of different silicates and metal oxides. The use of constant particles sizes and/or one-material cloud particles alone to interpret spectra may not be sufficient to capture the full complexity available through JWST observations.

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arXiv2022

Clouds form on the hot Saturn JWST ERO target WASP-96b

WASP-96b is a hot Saturn exoplanet, with an equilibrium temperature well within the regime of thermodynamically expected extensive cloud formation. Prior observations with Hubble/WFC3, Spitzer/IRAC, and VLT/FORS2 have been combined into a single spectra for which retrievals suggest a cold but cloud-free atmosphere. Recently, the planet was observed with the James Webb Space Telescope (JWST) as part of the Early Release Observations (ERO). 1D profiles are extracted from the 3D GCM expeRT/MITgcm results and used as input for a kinetic, non-equilibrium model to study the formation of mineral cloud particles of mixed composition. The ARCiS retrieval framework is applied to the pre-JWST WASP-96b transit spectra to investigate the apparent contradiction between cloudy models and assumed cloud-free transit spectra. Clouds are predicted to be ubiquitous throughout the atmosphere of WASP-96b. Silicate materials contribute between 40% and 90%, hence, also metal oxides contribute with up to 40% in the low-pressure regimes that effect the spectra. We explore how to match these cloudy models with currently available atmospheric transit spectra. A reduced vertical mixing acts to settle clouds to deeper in the atmosphere, and an increased cloud particles porosity reduces the opacity of clouds in the near-IR and optical region. Both these effects allow for clearer molecular features to be observed, while still allowing clouds to be in the atmosphere. The atmosphere of WASP-96b is unlikely to be cloud free. Also retrievals of HST, Spitzer and VLT spectra show that multiple cloudy solutions reproduce the data. JWST observations will be affected by clouds, where within even the NIRISS wavelength range the cloud top pressure varies by an order of magnitude. The long wavelength end of NIRSpec and short end of MIRI may probe atmospheric asymmetries between the limbs of the terminator on WASP-96b.

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arXiv2022

Exoplanet weather and climate regimes with clouds and thermal ionospheres: A model grid study in support of large-scale observational campaigns

With observational efforts moving from the discovery into the characterisation mode, systematic campaigns that cover large ranges of global stellar and planetary parameters will be needed. We aim to uncover cloud formation trends and globally changing chemical regimes due to the host star's effect on the thermodynamic structure of their atmospheres. We aim to provide input for exoplanet missions like JWST, PLATO, and Ariel, as well as potential UV missions ARAGO, PolStar or POLLUX. Pre-calculated 3D GCMs for M, K, G, F host stars are the input for our kinetic cloud model. Gaseous exoplanets fall broadly into three classes: i) cool planets with homogeneous cloud coverage, ii) intermediate temperature planets with asymmetric dayside cloud coverage, and iii) ultra-hot planets without clouds on the dayside. In class ii),} the dayside cloud patterns are shaped by the wind flow and irradiation. Surface gravity and planetary rotation have little effect. Extended atmosphere profiles suggest the formation of mineral haze in form of metal-oxide clusters (e.g. (TiO2)_N). The dayside cloud coverage is the tell-tale sign for the different planetary regimes and their resulting weather and climate appearance. Class (i) is representative of planets with a very homogeneous cloud particle size and material compositions across the globe (e.g., HATS-6b, NGTS-1b), classes (ii, e.g., WASP-43b, HD\,209458b) and (iii, e.g., WASP-121b, WP0137b) have a large day/night divergence of the cloud properties. The C/O ratio is, hence, homogeneously affected in class (i), but asymmetrically in class (ii) and (iii). The atmospheres of class (i) and (ii) planets are little affected by thermal ionisation, but class (iii) planets exhibit a deep ionosphere on the dayside. Magnetic coupling will therefore affect different planets differently and will be more efficient on the more extended, cloud-free dayside.

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arXiv2022

Mineral Snowflakes on Exoplanets and Brown Dwarfs: Coagulation and Fragmentation of Cloud Particles with {\sc HyLandS}

Brown dwarfs and exoplanets provide unique atmospheric regimes that hold information about their formation routes and evolutionary states. Modelling mineral cloud particle formation is key to prepare for missions and instruments like CRIRES+, JWST and ARIEL as well as possible polarimetry missions like {\sc PolStar}. The aim is to support more detailed observations that demand greater understanding of microphysical cloud processes. We extend our kinetic cloud formation model that treats nucleation, condensation, evaporation and settling of mixed material cloud particles to consistently model cloud particle-particle collisions. The new hybrid code, {\sc HyLandS}, is applied to a grid of {\sc Drift-Phoenix} (T, p)-profiles. Effective medium theory and Mie theory are used to investigate the optical properties. Turbulence is the main driving process of collisions, with collisions becoming the dominant process at the cloud base ($p>10^{-4}\,{\rm bar}$). Collisions produce one of three outcomes: fragmenting atmospheres ($\log_{10}(g)=3$), coagulating atmospheres ($\log_{10}(g)=5$, $T_{\rm eff} \leq 1800\, {\rm K}$) and condensational growth dominated atmospheres ($\log_{10}(g\,)=5$, $T_{\rm eff} > 1800\, {\rm K}$). Cloud particle opacity slope at optical wavelengths (HST) is increased with fragmentation, as are the silicate features at mid-infrared wavelengths. The hybrid moment-bin method {\sc HyLandS} demonstrates the feasibility of combining a moment and a bin method whilst assuring element conservation. It provides a powerful and fast tool for capturing general trends of particle collisions, consistently with other microphysical processes. Collisions are important in exoplanet and brown dwarf atmospheres but cannot be assumed to be hit-and-stick only. The spectral effects of collisions complicates inferences of cloud particle size and material composition from observational data.

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arXiv2020

Mineral snowflakes on exoplanets and brown dwarfs: Effects of micro-porosity, size distributions, and particle shape

Exoplanet atmosphere characterisation has become an important tool in understanding exoplanet formation, evolution. However, clouds remain a key challenge for characterisation: upcoming space telescopes (e.g. JWST, ARIEL) and ground-based high-resolution spectrographs (e.g. CRIRES+) will produce data requiring detailed understanding of cloud formation and cloud effects. We aim to understand how the micro-porosity of cloud particles affects the cloud structure, particle size, and material composition. We examine the spectroscopic effects of micro-porous particles, the particle size distribution, and non-spherical cloud particles. We expanded our kinetic non-equilibrium cloud formation model and use a grid of prescribed 1D (T_gas-p_gas) DRIFT-PHOENIX profiles. We applied the effective medium theory and the Mie theory to model the spectroscopic properties of cloud particles with micro-porosity and a derived particle size distribution. We used a statistical distribution of hollow spheres to represent the effects of non-spherical cloud particles. Highly micro-porous cloud particles (90% vacuum) have a larger surface area, enabling efficient bulk growth higher in the atmosphere than for compact particles. Increases in single-scattering albedo and cross-sectional area for these mineral snowflakes cause the cloud deck to become optically thin only at a wavelength of ~100 ${\rm \mu m}$ instead of at the ~20 ${\rm \mu m}$ for compact cloud particles. A significant enhancement in albedo is also seen when cloud particles occur with a locally changing Gaussian size distribution. Non-spherical particles increase the opacity of silicate spectral features, which further increases the wavelength at which the clouds become optically thin. JWST MIRI will be sensitive to signatures of micro-porous and non-spherical cloud particles based on the wavelength at which clouds are optically thin.

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arXiv2020

Understanding the atmospheric properties and chemical composition of the ultra-hot Jupiter HAT-P-7b II. Mapping the effects of gas kinetics

The atmospheres of ultra-hot Jupiters are commonly considered to be at thermochemical equilibrium. We aim to provide disequilibrium chemistry maps for a global understanding of the chemistry in HAT-P-7b's atmosphere and assess the importance of disequilibrium chemistry on UHJs. We apply a hierarchical modelling approach utilising 97 1D atmospheric profiles from 3D GCM of HAT-P-7b. For each 1D profile, we evaluate our kinetic cloud formation model consistently with the local gas-phase composition in chemical equilibrium. We then evaluate quenching results from a zeroth-order approximation in comparison to a kinetic gas-phase approach. We find that the zeroth-order approach of estimating quenching points agrees well with the full gas-kinetic modeling results. Chemical disequilibrium has the greatest effect on the nightside and morning abundance of species such as H, H$_2$O, CH$_4$, CO$_2$, HCN, and all C$_n$H$_m$ molecules; heavier C$_n$H$_m$ molecules are more affected by disequilibrium processes. CO abundance, however, is affected only marginally. While dayside abundances also notably change, those around the evening terminator of HAT-P-7b are the least affected by disequilibrium processes. The latter finding may partially explain the consistency of observed transmission spectra of UHJs with atmospheres in thermochemical equilibrium. Photochemistry only negligibly affects molecular abundances and quenching levels. In general, the quenching points of HAT-P-7b's atmosphere are at much lower pressures in comparison to the cooler hot-jupiters. We propose several avenues to look for the effect of disequilibrium processes on UHJs that are, in general, based on abundance and opacity measurements at different local times. It remains a challenge to completely disentangle this from the chemical effects of clouds and that of a primordial non-solar abundance.

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