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E. Coldren

Publications and source records attributed to E. Coldren.

2 recordsLinked to original sources

Partial Antiferromagnetic Helical Order in Fe$_3$PO$_4$O$_3$

Magnetic frustration in Fe$_3$PO$_4$O$_3$ has been shown to produce to an unusual magnetic state below T$_N = 163$ K, where incommensurate antiferromagnetic order is restricted to nanosized needle-like domains, as inferred from neutron powder diffraction. Here we show using single-crystal neutron diffraction that Fe$_3$PO$_4$O$_3$ does not exhibit a preferred ordering wavevector direction in the $ab$ plane despite having a well-defined ordering wavevector length. This results in the observation of continuous rings of scattering rather than satellite Bragg peaks. The lack of a preferred incommensurate ordering wavevector direction can be understood in terms of an antiferromagnetic Heisenberg model with nearest-neighbor ($J_1$) and second-neighbor ($J_2$) interactions, which produces a quasi-degenerate manifold of ordering wavevectors. This state appears to be similar to the partially ordered phase of MnSi, but in Fe$_3$PO$_4$O$_3$ arises in a frustrated antiferromagnet rather than a chiral ferromagnet.

cond-mat.str-el

Short range order in the quantum XXZ honeycomb lattice material BaCo$_2$(PO$_4$)$_2$

We present observations of highly frustrated quasi two-dimensional (2D) magnetic correlations in the honeycomb lattice layers of the S$_{eff}$ = 1/2 compound $γ$-BaCo$_2$(PO$_4$)$_2$ ($γ$-BCPO). Specific heat shows a broad peak comprised of two weak kink features at $T_{N1} \sim$ 6 K and $T_{N2} \sim$ 3.5 K, the relative weights of which can be modified by sample annealing. Neutron powder diffraction measurements reveal short range quasi-2D order that is established below $T_{N1}$ and $T_{N2}$, at which two separate, incompatible, short range magnetic orders onset: commensurate antiferromagnetic correlations with correlation length $ξ_c = 60\pm2$ Å\ ($T_{N1}$) and in quasi-2D helical domains with $ξ_h = 350 \pm 11$ Å\ ($T_{N2}$). The ac magnetic susceptibility response lacks frequency dependence, ruling out spin freezing. Inelastic neutron scattering data on $γ$-BCPO is compared with linear spin wave theory, and two separate parameter regions of the XXZ $J_1$-$J_2$-$J_3$ model with ferromagnetic nearest-neighbor exchange $J_1$ are favored, both near regions of high classical degeneracy. High energy coherent excitations ($\sim 10$ meV) persist up to at least 40 K, suggesting strong in-plane correlations persist above $T_N$. These data show that $γ$-BCPO is a rare highly frustrated, quasi-2D S$_{eff}$ = 1/2 honeycomb lattice material which resists long range magnetic order and spin freezing.

cond-mat.str-el