Search arXiv⌕ Search

arXiv subjects

Eva-Maria Ahrer

Publications and source records attributed to Eva-Maria Ahrer.

At least 19 recordsLinked to original sources
arXiv2026

JWST MEP - A World Under Spotty Starlight: Detection of CO2 and H2O in the Hot Saturn WASP-52b with JWST NIRSpec G395H

Exoplanets orbiting active stars offer distinct challenges for atmospheric characterization with the JWST. Among such worlds, the hot Saturn WASP-52b (Teq $\sim$ 1300 K) orbits an active K-dwarf that complicates transmission spectroscopy via stellar contamination. Here, we present the first JWST NIRSpec G395H (2.8-5.2 $μ$m) limb-averaged transmission spectrum of WASP-52b obtained through the JWST Morning/Evening Program (GO-3969), which aims to measure limb asymmetries across a sample of hot giant exoplanets. Our spectrum reveals the first detection of CO2 in WASP-52b's atmosphere (ln B = 54 / >10$σ$), with a retrieved abundance of log CO2 = -5.09 (+1.09/-1.14), and confirmation of H2O (ln B = 5.9 / $\sim$3-4$σ$), with an abundance of log H2O = -3.41 (+1.04/-1.04). We find a steep near-infrared slope that cannot be explained solely by H2O absorption, necessitating unocculted starspots (ln B = 5.7 / $\sim$3-4$σ$), though with properties that vary across our data reductions. The shape and amplitude of the molecular bands additionally suggest high-altitude (<10 mbar) inhomogeneous clouds covering $\approx$40 $\pm$ 20% of the terminator (ln B = 1.9 / $\sim$2.5$σ$), which provides evidence for the morning-evening terminator differences that are consensus predictions of general circulation models. WASP-52b's atmospheric metallicity can be sub-solar, solar, or super-solar, due to order-of-magnitude uncertainties in the molecular abundances caused by degeneracies between compositions, clouds, and starspots. However, chemical equilibrium retrievals provide a similar statistical fit while favoring a tighter constraint with a super-solar metallicity (M/H = 14.8 (+12.1/-5.9) $\times$ solar). These results highlight that chemical detections and aerosol properties may still be recovered for planets orbiting active stars via transmission spectroscopy.

astro-ph.EP↗
arXiv2026

Recovering the Morning and Evening Limbs of WASP-94Ab from Its Limb-Averaged JWST Transmission Spectrum

Recent JWST observations have revealed that the morning and evening limbs of the hot Jupiter WASP-94Ab have very different transmission spectra. An analysis of these resolved limb spectra yielded a metallicity more than an order of magnitude below that obtained from the limb-averaged spectrum, which calls into question the accuracy of traditional retrievals for heterogenous planets. Here we analyze the limb-averaged JWST NIRISS and NIRSpec transmission spectra of WASP-94Ab using both a standard one-temperature-profile (1-TP) retrieval with patchy clouds, and a new two-temperature-profile (2-TP) retrieval. The 2-TP retrieval assumes a linear combination of two atmospheric components that share the same bulk elemental composition but have independent thermal structures, chemistries, and aerosol properties. This model is implemented in PLATON 7.0, a JAX-accelerated code that is over 100 times faster than its predecessor, which is key to making the retrieval computationally tractable. The limb-averaged spectrum of WASP-94Ab favors the 2-TP model by a Bayes factor K=1.8x10^{5} and shifts the metallicity downward to Zatm/Zsun = 11^{+9}_{-4} from 170^{+30}_{-24} obtained with the 1-TP model. The 2-TP retrieval predicts two, equally weighted components that reproduce the limb-resolved spectra across both instruments without prior knowledge of them. This work demonstrates that compositional information survives limb averaging for WASP-94Ab, suggesting that 2-TP retrievals can be used to identify limb-asymmetry and extend metallicity studies beyond the small set of planets amenable to limb-resolved spectroscopy.

astro-ph.EP↗
arXiv2026

The asymmetric limbs of HD 209458 b observed with JWST NIRCam F322W2/F444W

We present a reanalysis of JWST NIRCam F322W2/F444W transit observations of the hot Jupiter HD 209458 b to extract morning and evening transmission spectra. To determine whether asymmetries in the transit light curves arise from atmospheric structure, we refine the HD 209458 system parameters through a reanalysis of archival transit and radial velocity data. We then extract limb-resolved spectra using two independent light curve modelling frameworks, Harmonica and catwoman,which yield consistent results. We interpret the transmission spectra using both 1D and 1.5D (i.e.,retrievals in which each limb of the planet is modelled independently) atmospheric retrievals. From our 1.5D free-chemistry retrievals, we find a strong preference (Delta ln Z = 2.81 +/- 0.49) for a model in which the morning and evening limbs are retrieved independently over one in which they share atmospheric parameters, despite the additional free parameters this requires. This asymmetry is most pronounced in the retrieved cloud properties, consistent with 3D atmospheric circulation models that predict longitudinally varying cloud distributions, and to a lesser extent in the CH4 and CO abundances. In contrast, the H2O and CO2 abundances and the isothermal temperature structure remain largely consistent between limbs. Similarly, our 1.5D equilibrium chemistry retrieval reveals a uniform composition between the limbs, alongside a marginally hotter evening limb relative to the morning limb. While the retrieved temperatures, chemical abundances, metallicities and carbon-to-oxygen ratios (C/O) are uniform across both limbs, they exhibit significant differences from our 1D retrieval results, highlighting the importance of multidimensional modelling in mitigating 1D retrieval biases.

astro-ph.EP↗
arXiv2026

KRONOS II: Solar-like Umbra and Penumbra Properties on the Young Sun V1298~Tau

Transiting exoplanets provide a unique laboratory for studying stellar surface heterogeneities via starspot or facular occultations. When observed at multiple wavelengths, this configuration enables spectroscopic characterization of spot thermal contrasts, distributions, and morphology. In this work, we leverage JWST NIRISS/SOSS transit observations of the 20--30~Myr planets V1298~Tau~bcd to study the surface properties of their solar analog host star V1298~Tau. We identify 14 starspot crossing events across two visits. We derive $0.8-2.8μ$m starspot contrast spectra and demonstrate the contrasts can only be explained when accounting for the umbral and penumbral components of the starspots, robust to which stellar model grid is assumed. The spot temperatures are broadly consistent between visits, suggesting that V1298~Tau ($T_\mathrm{phot}=4866\pm33$\,K) has starspots with $T_{\mathrm{umbra}}$ = 3300--3600\,K umbrae and $T_{\mathrm{penumbra}}$ = 4400--4600\,K penumbrae, and are $\sim$25--30\% umbrae by area. The differences between these spot components and the stellar photosphere are consistent with sunspots. Additionally, the relation between the spot contrast and the ratio of umbral to penumbral area is similar to that of the Sun. Combining these JWST observations with long baseline multi-band photometry from the Las Cumbres Observatory, we also estimated the global unocculted spot distribution, revealing at least 5 additional large unocculted active regions. Altogether, these measurements suggest that while the total spot coverage evolves in time, the relative temperatures of surface heterogeneities on Sun-like stars may be consistent throughout their lifetimes. Furthermore, these results demonstrate that JWST exoplanet transit observations can be useful for starspot substructure characterization.

astro-ph.SR↗
arXiv2026

Atmospheric asymmetries in WASP-121 b revealed by rotational transits detected with JWST

Close-in exoplanets are tidally locked to their host star and thus exhibit extreme atmospheric temperature gradients. It has been theorized that the fraction of star light absorbed by such planets during transit changes as a function of orbital phase as progressively hotter or colder atmospheric gas rotates into view, but this effect has not been observed so far. Here, we show that two transits of the ultra-hot Jupiter WASP-121 b, acquired with JWST/NIRSpec and NIRISS, exhibit asymmetric transit light curves caused by the planet's rotation during transit. We observe increasing CO absorption and slightly decreasing H$_2$O absorption in the transmission spectrum, as the planet rotates. These results are indicative of a stronger longitudinal temperature gradient across the evening than across the morning terminator, consistent with higher temperatures in the eastern half than in the western half of the dayside. The observed changes of the transmission spectrum with orbital phase are in line with the temperature increase causing thermal dissociation of H$_2$O, while CO remains abundant. The observation of longitudinal gradients of atmospheric temperature and chemistry from the planet's rotational transit provides a new probe for constraining atmospheric heterogeneity using JWST beyond differences between morning and evening terminators from limb asymmetries.

astro-ph.EP↗
arXiv2026

Characterizing Transiting Exoplanet Atmospheres in the 2030s with the Hubble Space Telescope

The Hubble Space Telescope inaugurated the era of exoplanet atmospheric characterization. While the James Webb Space Telescope has largely taken up the mantle of infrared atmospheric characterization, Hubble's unique short-wavelength capabilities remain unmatched. Recent theoretical advances in exoplanet atmospheric science combined with new observing strategies, like those offered by WFC3-UVIS/G280, have opened science cases that only Hubble can address for the foreseeable future. In this white paper, we discuss these new windows into the atmospheres of other worlds, focusing on characterization of their hydrostatic lower atmosphere, and identify the critical capabilities necessary for future observations. We highlight three overall science cases that will depend on the continued short-wavelength capabilities of Hubble: measuring aerosol scattering slopes, characterizing metal absorption in ultra-hot Jupiters, and understanding stellar activity with Transit Light Source effect decontamination and flare monitoring. Throughout, we highlight useful synergies between HST and JWST. This article is a response to the call for white papers by the Space Telescope Science Institute on "Building a Roadmap for Hubble science into the 2030s."

astro-ph.IM↗
arXiv2026

Super-Solar Metallicity and Tentative Evidence for Photochemistry on WASP-96b from JWST and Ground-Based VLT Transmission Spectroscopy

With its expanded wavelength coverage and increased precision compared to previous space-based observatories, JWST provides the opportunity to revisit benchmark planets and view them in a new light. Here, we conduct an in-depth study of the atmosphere of the hot-Saturn WASP-96b combining a new JWST NIRSpec/G395H transit with archival NIRISS/SOSS and VLT/FORS2 transmission spectra. The combined spectrum shows clearly-visible features from H2O, CO2, and Na. CO, though, remains unconstrained, precluding a firm metallicity derivation from free retrievals alone. However, self-consistent grids yield a broadly super-stellar atmospheric metallicity of 2-6x stellar. When combined with a roughly stellar C/O ratio ($0.41^{+0.10}_{-0.09}$ from self-consistent grids), we find that WASP-96b potentially formed via core-accretion beyond the H2O snowline and subsequently accreted volatile-rich material. Free retrievals also find a moderate preference (ln B=2.69) for models with SO2 versus without. WASP-96b falls directly on the proposed "SO2 shoreline" and the retrieved SO2 abundance is well-matched to predictions from photochemical models. Our combined spectrum displays an optical slope, which our models fit with opacity from scattering aerosols -- either small-particle condensate clouds or photochemical hazes -- though we cannot completely rule out the broad wings of Na or the effects of stellar contamination. Future observations are necessary to disentangle these effects. Finally, we explore the possibility for limb asymmetry in WASP-96b's transmission spectrum and provide several tests to identify asymmetries in our data. We encourage the community to prioritize the development of a robust pathway to quantify the presence of limb asymmetry -- particularly for low signal-to-noise cases.

astro-ph.EP↗
arXiv2026

BOWIE-ALIGN: Exploring degeneracies in the muted transmission spectrum of the aligned hot Jupiter NGTS-2b with NIRSpec/G395H

We present the first atmospheric observation and characterisation of the aligned, 1468 K hot Jupiter, NGTS-2b, with one JWST NIRSpec/G395H transit. These observations complete the GO 3838 observing campaign of the BOWIE-ALIGN program, which aims to investigate the link between hot Jupiter atmospheric composition and formation history through the atmospheric analysis of planets orbiting F stars that are aligned and misaligned with the host stellar spin axis. The 2.84-5.18 micron spectrum shows weak absorption features attributed to H$_2$O and CO$_2$ absorption, which our free chemistry retrievals fit with posteriors that converge on high mean molecular weight solutions attained through significant H$_2$O mixing ratios. By comparing our results to interior modelling, we show that some of these solutions exceed the 43.5x solar upper limit we obtained from our interior structure models. Such solutions are likely due to cloud-metallicity degeneracies and insufficient wavelength coverage to resolve them. We show that, in the case of our observations, the likelihood distribution of H$_2$O abundances is flat and uninformative, such that our retrievals are biased by the prior. Additionally, our statistically favoured atmospheric solution contains absorption from SO. The chemical abundances retrieved with this model are likely not astrophysically feasible and we demonstrate that the presence of SO is driven by only two data points. Our equilibrium chemistry retrievals hint at a subsolar C/O ratio and supersolar metallicity; however, we find wide posterior distributions that extend to solar values.

astro-ph.EP↗
arXiv2026

LRG-BEASTS: Detection of sodium and evidence for water absorption in the hot Saturn HAT-P-44b

We present the low-resolution optical transmission spectrum of the inflated hot Saturn HAT-P-44b. The planet is a close sibling in radius (1.24 $\mathrm{R_{Jup}}$), temperature (1100 K), and mass (0.35 $\mathrm{M_{Jup}}$) to the exceedingly well-characterized WASP-39b. Using the ACAM instrument on the William Herschel Telescope (WHT), we obtain a transmission spectrum with sub-scale height precision of 246 ppm, with a wavelength range of 495 -- 874 nm and a 20 nm resolution, despite a relatively faint host star ($V\mathrm{_{mag} = 13.2}$). We detect absorption due to sodium with 3.9$σ$ confidence. Atmospheric retrieval of the transmission spectrum also reveals evidence for \ch{H2O} absorption and Rayleigh scattering from \ch{H2} gas consistent with a cool 800 K atmosphere and a super-solar metallicity of 7$\substack{+16 \\ -5}$$\times$solar. Comparison of retrieval models disfavour the inclusion of a super-Rayleigh scattering slope or high-altitude clouds (at $<1$ mbar) while being agnostic towards the presence of mid-altitude clouds. Our transmission spectrum of HAT-P-44b shows strong similarity to that of its sibling WASP-39b.} This is the tenth planet in the LRG-BEASTS (Low-Resolution Ground-Based Exoplanet Atmosphere Survey using Transmission Spectroscopy) survey.

astro-ph.EP↗
arXiv2026

BOWIE-ALIGN: Sub-solar C/O ratio and metallicity atmosphere of the misaligned hot Jupiter HAT-P-30b

We present the JWST NIRSpec/G395H transmission spectrum of the misaligned hot Jupiter HAT-P-30b from 2.8--5.2 $μ$m as part of the BOWIE-ALIGN survey, a comparative survey designed to probe the link between planet formation and atmospheric composition in samples of misaligned and aligned hot Jupiters orbiting F-type stars. Through independent data reductions and retrieval analyses, we find evidence for absorption features of H$_2$O and CO$_2$ in the atmosphere of HAT-P-30b. Our retrieved abundances are consistent with equilibrium chemistry, from which we infer a sub-solar C/O ratio (0.16--0.45), and sub-solar and sub-stellar metallicity (0.2--0.8$\times$solar, compared to a stellar metallicity of 1.1--1.6$\times$solar), with muted spectral features. This composition challenges formation models of continuous migration and accretion within a steady disc of stellar metallicity, and could be the result of low C/O ratio gas accretion within the water ice line, low metallicity accretion due to the trapping of volatiles further out in the disc, or the combined accretion of low metallicity gas and carbon-poor solids.

astro-ph.EP↗
arXiv2025

Mapping the SO2 Shoreline in Gas Giant Exoplanets

JWST has revealed sulfur chemistry in giant exoplanet atmospheres, where molecules such as SO2 trace photochemistry, metallicity, and formation and migration. To ascertain the conditions that determine whether (or how much) SO2, H2S, and other sulfur-bearing species are present in exoplanet atmospheres, we present a grid of planetary atmospheres covering metallicities from 0.3-1000x Solar and temperatures from 250-2050 K. These models map out the 'SO2 shoreline,' the region of metallicity and irradiation for which SO2 may be sufficiently abundant to be detectable. SO2 is a sensitive indicator of metallicity; expected SO2 abundances also depend strongly on overall temperature and C/O ratio; the SO2 abundance depends surprisingly weakly on XUV irradiation, also weakly on Kzz (for Teq > 600 K), and is essentially independent of internal temperature. Despite its detection in a growing number of giant planets, SO2 is never the dominant sulfur-bearing molecule: depending on temperature and metallicity, H2S, S2, NS, SO, SH, and even S8 or atomic S are frequently as common (or more so) as SO2. Nonetheless SO2 remains the most easily detectable sulfur-bearing species, followed by H2S, though perhaps SO and SH could be detectable in some gas giants. Aside from a pressing need for additional observational constraints on sulfur, we also identify the need for future work to account for the effects of clouds and hazes, fully self-consistent atmospheric models, 2D and 3D models, a wider range of planetary masses and radii, and studies to measure and refine reaction rates and molecular opacities of sulfur-bearing species

astro-ph.EP↗
arXiv2025

Possible Evidence for the Presence of Volatiles on the Warm Super-Earth TOI-270 b

The search for atmospheres on rocky exoplanets is a crucial step in understanding the processes driving atmosphere formation, retention, and loss. Past studies have revealed the existence of planets interior to the radius valley with densities lower than would be expected for pure-rock compositions, indicative of the presence of large volatile inventories which could facilitate atmosphere retention. Here we present an analysis of the JWST NIRSpec/G395H transmission spectrum of the warm ($T_\mathrm{eq,{A_B}=0}$ = 569 K) super-Earth TOI-270 b ($R_\mathrm{p}$ = 1.306 $R_\oplus$), captured alongside the transit of TOI-270 d. The JWST white light-curve transit depth updates TOI-270 b's density to $ρ_\mathrm{p}$ = 3.7 $\pm$ 0.5 g/cm$^3$, inconsistent at 4.4$σ$ with an Earth-like composition. Instead, the planet is best explained by a non-zero, percent-level water mass fraction, possibly residing on the surface or stored within the interior. The JWST transmission spectrum shows possible spectroscopic evidence for the presence of this water as part of an atmosphere on TOI-270 b, favoring a H$_2$O-rich steam atmosphere model over a flat spectrum ($\ln\mathcal{B}$ = $0.3-3.2$, inconclusive to moderate), with the exact significance depending on whether an offset parameter between the NIRSpec detectors is included. We leverage the transit of the twice-larger TOI-270 d crossing the stellar disk almost simultaneously to rule out the alternative hypothesis that the transit-light-source effect could have caused the water feature in TOI-270 b's observed transmission spectrum. Planetary evolution modeling furthermore shows that TOI-270 b could sustain a significant atmosphere on Gyr timescales, despite its high stellar irradiation, if it formed with a large initial volatile inventory.

astro-ph.EP↗
arXiv2025

BOWIE-ALIGN: Weak spectral features in KELT-7b's JWST NIRSpec/G395H transmission spectrum imply a high cloud deck or a low-metallicity atmosphere

Hot Jupiters and their atmospheres are prime targets for transmission spectroscopy due to their extended atmospheres and the corresponding large signal-to-noise, providing the best possible constraints for the atmospheric carbon-to-oxygen (C/O) ratio and metallicity of exoplanets. Within BOWIE-ALIGN, we aim to compare JWST spectra of a sample of orbitally aligned and misaligned hot Jupiters orbiting F-type stars to probe the link between hot Jupiter atmospheres and planet formation history. Here, we present a near-infrared transmission spectrum of the aligned planet KELT-7b using one transit observed with JWST NIRSpec/G395H. We find weak features, only tentative evidence for H$_2$O and CO$_2$ in the atmosphere of KELT-7b. This poses a challenge to constrain the atmospheric properties of KELT-7b and two possible scenarios emerge from equilibrium chemistry and free chemistry retrievals: a high-altitude cloud deck muting all features or an extremely low metallicity atmosphere, respectively. The retrieved C/O ratios from our data reductions range from $0.43 - 0.74$, while the atmospheric metallicity is suggested to be solar to super-solar ($1-16 \times$ solar). Although these wide constraints prevent detailed conclusions about KELT-7b's formation history, a solar-to-super-solar metallicity would imply the accretion of solid material during its formation, which is valuable information for the survey's wider goals of understanding the relative importance of gaseous to solid accretion.

astro-ph.EP↗
arXiv2025

A Comprehensive Reanalysis of K2-18 b's JWST NIRISS+NIRSpec Transmission Spectrum

Sub-Neptunes are the most common type of planet in our galaxy. Interior structure models suggest that the coldest sub-Neptunes could host liquid water oceans underneath their hydrogen envelopes -- sometimes called ``hycean'' planets. JWST transmission spectra of the $\sim$ 250 K sub-Neptune K2-18 b were recently used to report detections of CH$_4$ and CO$_2$, alongside weaker evidence of (CH$_3$)$_2$S (dimethyl sulfide, or DMS). Atmospheric CO$_2$ was interpreted as evidence for a liquid water ocean, while DMS was highlighted as a potential biomarker. However, these notable claims were derived using a single data reduction and retrieval modeling framework, which did not allow for standard robustness tests. Here we present a comprehensive reanalysis of K2-18 b's JWST NIRISS SOSS and NIRSpec G395H transmission spectra, including the first analysis of the second-order NIRISS SOSS data. We incorporate multiple well-tested data reduction pipelines and retrieval codes, spanning 60 different data treatments and over 250 atmospheric retrievals. We confirm the detection of CH$_4$ ($\approx 4σ$), with a volume mixing ratio range $-2.14 \leq \log_{10} \mathrm{CH_4} \leq -0.53$, but we find no statistically significant or reliable evidence for CO$_2$ or DMS. Finally, we assess the retrieved atmospheric composition using photochemical-climate and interior models, demonstrating that our revised composition of K2-18\,b can be explained by an oxygen-poor mini-Neptune without requiring a liquid water surface or life.

astro-ph.EP↗
arXiv2025

Detailed Architecture of the L 98-59 System and Confirmation of a Fifth Planet in the Habitable Zone

The L 98-59 system, identified by TESS in 2019, features three transiting exoplanets in compact orbits of 2.253, 3.691, and 7.451 days around an M3V star, with an outer 12.83-day non-transiting planet confirmed in 2021 using ESPRESSO. The planets exhibit a diverse range of sizes (0.8-1.6 R$_{\oplus}$), masses (0.5-3 M$_{\oplus}$), and likely compositions (Earth-like to possibly water-rich), prompting atmospheric characterization studies with HST and JWST. Here, we analyze 16 new TESS sectors and improve radial velocity (RV) precision of archival ESPRESSO and HARPS data using a line-by-line framework, enabling stellar activity detrending via a novel differential temperature indicator. We refine the radii of L 98-59 b, c, and d to 0.837 $\pm$ 0.019 R$_{\oplus}$, 1.329 $\pm$ 0.029 R$_{\oplus}$, 1.627 $\pm$ 0.041 R$_{\oplus}$, respectively. Combining RVs with transit timing variations (TTV) of L 98-59 c and d from TESS and JWST provides unprecedented constraints on the masses and eccentricities of the planets. We report updated masses of 0.46 $\pm$ 0.11 M$_{\oplus}$ for b, 2.00 $\pm$ 0.13 M$_{\oplus}$ for c, and 1.64 $\pm$ 0.07 M$_{\oplus}$ for d, and a minimum mass of 2.82 $\pm$ 0.19 M$_{\oplus}$ for e. We additionally confirm L 98-59\,f, a non-transiting super-Earth with a minimal mass of 2.80 $\pm$ 0.30 M$_{\oplus}$ on a 23.06-day orbit inside the Habitable Zone. The TTVs of L 98-59 c and d (<3 min, $P_{\rm TTV} = 396$ days) constrain the eccentricities of all planets to near-circular orbits ($e \lesssim 0.04$). An internal structure analysis of the transiting planets reveals increasing water-mass fractions ($f_{\rm H_{2}O}$) with orbital distance, reaching $f_{\rm H_{2}O} \approx 0.16$ for L 98-59\ d. We predict eccentricity-induced tidal heating in L 98-59 b with heat fluxes comparable to those of Io, potentially driving volcanic activity.

astro-ph.EP↗
arXiv2025

Tracing the formation and migration history: molecular signatures in the atmosphere of misaligned hot Jupiter WASP-94Ab using JWST NIRSpec/G395H

The discovery of hot Jupiters that orbit very close to their host stars has long challenged traditional models of planetary formation and migration. Characterising their atmospheric composition - mainly in the form of the carbon-to-oxygen (C/O) ratio and metallicity - can provide insights into their formation locations and evolution pathways. With JWST we can characterise the atmospheres of these types of planets more precisely than previously possible, primarily because it allows us to determine both their atmospheric oxygen and carbon composition. Here, we present a JWST NIRSpec/G395H transmission spectrum from 2.8-5.1$μm$ of WASP-94Ab, an inflated hot Jupiter with a retrograde misaligned orbit around its F-type host star. We find a relatively cloud-free atmosphere, with absorption features of H$_2$O and CO$_2$ at detection significances of $\sim 4σ$ and $\sim 11σ$, respectively. In addition, we detect tentative evidence of CO absorption at $\sim3σ$, as well as hints of sulphur with the detection of H$_2$S at a $\sim 2.5σ$ confidence level. Our favoured equilibrium chemistry model determines a C/O ratio of $0.49^{+0.08}_{-0.13}$ for WASP-94Ab's atmosphere, which is substellar compared to the star's C/O ratio of $0.68 \pm 0.10$. The retrieved atmospheric metallicity is similar to the star's metallicity as both are $\sim 2\times$ solar. We find that this sub-stellar C/O ratio and stellar metallicity can be best explained by pebble accretion or planetesimal accretion in combination with large-distance migration of the planet.

astro-ph.EP↗
arXiv2025

SiO and a super-stellar C/O ratio in the atmosphere of the giant exoplanet WASP-121b

Refractory elements such as iron, magnesium, and silicon can be detected in the atmospheres of ultrahot giant planets. This provides an opportunity to quantify the amount of refractory material accreted during formation, along with volatile gases and ices. However, simultaneous detections of refractories and volatiles have proved challenging, as the most prominent spectral features of associated atoms and molecules span a broad wavelength range. Here, using a single JWST observation of the ultrahot giant planet WASP-121b, we report detections of H$_2$O (5.5-13.5$σ$), CO (10.8-12.8$σ$), and SiO (5.7-6.2$σ$) in the planet's dayside atmosphere, and CH$_4$ (3.1-5.1$σ$) in the nightside atmosphere. We measure super-stellar values for the atmospheric C/H, O/H, Si/H, and C/O ratios, which point to the joint importance of pebbles and planetesimals in giant planet formation. The CH$_4$-rich nightside composition is also indicative of dynamical processes, such as strong vertical mixing, having a profound influence on the chemistry of ultrahot giant planets.

astro-ph.EP↗
arXiv2025

WASP-121b's transmission spectrum observed with JWST/NIRSpec G395H reveals thermal dissociation and SiO in the atmosphere

WASP-121b has been established as a benchmark ultrahot Jupiter, serving as a laboratory for the atmospheric chemistry and dynamics of strongly irradiated extrasolar gas giants. Here, we present and analyze WASP-121b's transmission spectrum observed with NIRSpec G395H on board the James Webb Space Telescope and find evidence for the thermal dissociation of H$_2$O and H$_2$ on the planet's permanent dayside. Additionally, we detect SiO at a statistical significance of $5.2σ$ which is compatible with chemical equilibrium in the atmosphere. Constraining the abundance of SiO and abundance ratios between silicon and volatile atoms in WASP-121b's atmosphere could help discriminate between possible migration histories of the planet. The three-dimensional nature of thermal dissociation on WASP-121b's dayside and of recombination on its nightside, however, poses a challenge to constraining molecular abundances and elemental abundance ratios from the transmission spectrum. To account for this, we implemented an atmospheric model in the NEMESIS framework that splits the planet's atmosphere into dayside and nightside. A retrieval applying our atmospheric model to WASP-121b's transmission spectrum favors a higher H$_2$O abundance on the nightside than on the dayside, demonstrating the impact of hemispheric heterogeneity when attempting to constrain WASP-121b's bulk H$_2$O inventory.

astro-ph.EP↗