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Francesco Colangelo

Publications and source records attributed to Francesco Colangelo.

13 recordsLinked to original sources

Annealing-enhanced spin-orbit effects in non-centrosymmetric superconducting NbRe films

$\text{Nb}_{0.18}\text{Re}_{0.82}$ (NbRe) is a non-centrosymmetric superconductor with a transition temperature $T_\mathrm{c}$ reaching $9\text{ K}$ in bulk form. While bulk and single-crystalline NbRe exhibit signatures of multigap superconductivity, thin films generally display a single-gap superconducting state due to structural disorder and reduced crystallite dimensions. Here, we investigate the impact of thermal annealing on the superconducting and normal-state magnetotransport properties of NbRe films. The temperature dependence of the upper critical field, $B_{\mathrm{c2}}(T)$, is analyzed within the microscopic Werthamer--Helfand--Hohenberg (WHH) framework, while the normal-state magnetoconductivity is described using the three-dimensional Kawabata weak-localization/weak-anti-localization model. Annealing drives a pronounced change in the electronic response, manifested by a strong weak anti-localization behavior in the normal state and an upper critical field that surpasses both the conventional orbital-limiting field and the Pauli paramagnetic limit. The microscopic analysis reveals a strong intrinsic increase in the relative spin--orbit scattering strength, with the annealed film showing a significantly enhanced spin--orbit-to-dephasing field ratio. These findings provide direct, independent evidence that thermal modification of the NbRe microstructure successfully amplifies spin--orbit-mediated quantum transport, which acts as the key mechanism protecting the non-centrosymmetric superconducting state against paramagnetic pair-breaking well beyond conventional theoretical boundaries.

cond-mat.supr-con

Annealing-induced grain coarsening and voltage kinks in superconducting NbRe films

NbRe, a non-centrosymmetric superconductor with a transition temperature $T_\mathrm{c}$ up to 9\,K, attracts interest for its strong antisymmetric spin-orbit coupling and suitability for single-photon detection. While bulk and thin-film polycrystalline NbRe are well studied, how superconductivity and vortex dynamics evolve with increasing grain size in thin films is largely unknown. Here, we investigate as-grown and annealed 20\,nm-thick NbRe films, where annealing increases the average crystallite size from approximately $2$\,nm to $8$\,nm, and study vortex dynamics via current-voltage ($I$-$V$) measurements over a broad temperature and magnetic field range. In contrast to as-grown films, where the low-resistive state breaks down due to flux-flow instability, annealed films exhibit multiple voltage kinks in the $I$-$V$ curves. We attribute these kinks to the nucleation and growth of normal domains, as further suggested by time-dependent Ginzburg-Landau simulations. Overall, the annealed films form superconducting networks with vortex-channeling paths along the grain boundaries, while localized heating and voltage kinks could be harnessed for discrete-resistance switching and sensing.

cond-mat.supr-con

Configurations in the Euclidean plane associated to a system of equations

In the Euclidean plane ${\bf{E}}^2$, fix four pairwise distinct points \begin{equation*} \label{eqA} \begin{array}{ccc} A=(a_1,a_2),\ B=(b_1,b_2),\ C=(c_1,c_2),\ D=(d_1,d_2), \end{array} \end{equation*} together with four non-zero real numbers $k_A,k_B,k_C,k_D$. We show that System (*) consisting of the following four equations in the unknowns $X=(x_1,x_2)$ and $Y=(y_1,y_2)$ \begin{equation*} \label{egy} \frac{1}{\|X-T\|^2} +\frac{1}{\|Y-T\|^2}=k_T, \quad T\in\{A,B,C,D\} \end{equation*} has finitely many solutions $(X,Y)$ (counting also those with complex coordinates) provided that both of the following two conditions are satisfied: ($i$) no three of the fixed points $A,B,C,D$ are coplanar; ($ii$) no three of the four circles of center $T$ and radius $1/\sqrt{k_T}$ with share a common point in ${\bf{E}}^2$. Furthermore, we exhibit a configuration $ABCD$ showing that System (*) satisfying $(i)$ and $(ii)$ may have many real solutions $(X,Y)$. This result is the planar version of an analog problem in the Euclidean space arising from applications to genetics, investigated in the recent papers \cite{cif} and \cite{ak2024}.

math.AG

The Perfect Matching Hamiltonian property in Prism and Crossed Prism graphs

A graph $G$ has the \emph{Perfect Matching Hamiltonian property} (or for short, $G$ is $PMH$) if, for each one of its perfect matchings, there is another perfect matching of $G$ such that the union of the two perfect matchings yields a Hamiltonian cycle of $G$. In this note, we show that \emph{Prism graphs} $\cP_n$ are not $PMH$, except for the $Cube\ graph$, and indicate for which values of $n$ the \emph{Crossed Prism graphs} $\cCP_n$ are $PMH$.

math.CO

The association scheme on the set of flags of a finite generalized quadrangle

In this paper, the association scheme defined on the flags of a finite generalized quadrangle is considered. All possible fusions of this scheme are listed, and a full description for those of classes 2 and 3 is given. Furthermore, it is showed that an association scheme with appropriate parameters must arise from the flags of a generalized quadrangle. The same is done for one of its 4-class symmetric fusion.

math.CO

Electron localization in periodically strained graphene

Pseudo-magnetic field (PMF) in deformed graphene has been proposed as a promising and flexible method to quantum-confine electronic states and create gaps in the local density of states. Motivated by this perspective, we numerically analyze various different configurations leading to electronic localization and band flattening in periodically strained graphene. In particular, we highlight the existence of a fine structure in the pseudo-Landau levels confined in large-PMF regions, the emergence of states confined to PMF nodes as well as of snake-like orbits. In our paper, we further analyze the importance of the relative rotation and asymmetry of the strain lattice with respect to the atomic lattice and show how it can be used to modulate the PMF periodicity and to create localized orbits far from the strain points. Possible implementations and applications of the simulated structures are discussed.

cond-mat.mes-hall

Stress-strain in electron-beam activated polymeric micro-actuators

Actuation of thin polymeric films via electron irradiation is a promising avenue to realize devices based on strain engineered two dimensional (2D) materials. Complex strain profiles demand a deep understanding of the mechanics of the polymeric layer under electron irradiation; in this article we report a detailed investigation on electron-induced stress on poly-methyl-methacrylate (PMMA) thin film material. After an assessment of stress values using a method based on dielectric cantilevers, we directly investigate the lateral shrinkage of PMMA patterns on epitaxial graphene, which reveals a universal behavior, independent of the electron acceleration energy. By knowing the stress-strain curve, we finally estimate an effective Young's modulus of PMMA on top of graphene which is a relevant parameter for PMMA based electron-beam lithography and strain engineering applications.

cond-mat.mes-hall

Local tuning of WS2 photoluminescence using polymeric micro-actuators in a monolithic van der Waals heterostructure

The control of the local strain profile in 2D materials offers an invaluable tool for tailoring the electronic and photonic properties of solid-state devices. In this paper, we demonstrate a local engineering of the exciton photoluminescence (PL) energy of monolayer tungsten disulfide (WS2) by means of strain. We apply a local uniaxial stress to WS2 by exploiting electron-beam patterned and actuated polymeric micrometric artificial muscles (MAMs), which we implement onto monolithic synthetic WS2/graphene heterostructures. We show that MAMs are able to induce an in-plane stress to the top WS2 layer of the van der Waals heterostructure and that the latter can slide on the graphene underneath with negligible friction. As a proof of concept for the local strain-induced PL shift experiments, we exploit a two-MAM configuration in order to apply uniaxial tensile stress on well-defined micrometric regions of WS2. Remarkably, our architecture does not require the adoption of fragile suspended microstructures. We observe a spatial modulation of the excitonic PL energy of the WS2 monolayers under stress, which agrees with the expected strain profile and attains a maximum redshift of about 40 meV at the maximum strain intensity point. After the actuation, a time-dependent PL blueshift is observed in agreement with the viscoelastic properties of the polymeric MAMs. Our approach enables inducing local and arbitrary deformation profiles and circumvents some key limitations and technical challenges of alternative strain engineering methods requiring the 2D material transfer and production of suspended membranes.

cond-mat.mes-hall

Local anodic oxidation on hydrogen-intercalated graphene layers: oxide composition analysis and role of the silicon carbide substrate

We investigate nanoscale local anodic oxidation (LAO) on hydrogen-intercalated graphene grown by controlled sublimation of silicon carbide (SiC). Scanning probe microscopy (SPM) was used as a lithographic and characterization tool in order to investigate the local properties of the nanofabricated structures. The anomalous thickness observed after the graphene oxidation process is linked to the impact of LAO on the substrate. Micro-Raman spectroscopy was employed to demonstrate the presence of two oxidation regimes depending on the applied bias. We show that partial and total etching of monolayer graphene can be achieved by tuning the bias voltage during LAO. Finally, a complete compositional characterization was achieved by scanning electron microscopy and energy dispersive spectroscopy (EDS).

cond-mat.mtrl-sci

Stretching graphene using polymeric micro-muscles

The control of strain in two-dimensional materials opens exciting perspectives for the engineering of their electronic properties. While this expectation has been validated by artificial-lattice studies, it remains elusive in the case of atomic lattices. Remarkable results were obtained on nanobubbles and nano-wrinkles, or using scanning probes; microscale strain devices were implemented exploiting deformable substrates or external loads. These devices lack, however, the flexibility required to fully control and investigate arbitrary strain profiles. Here, we demonstrate a novel approach making it possible to induce strain in graphene using polymeric micrometric artificial muscles (MAMs) that contract in a controllable and reversible way under an electronic stimulus. Our method exploits the mechanical response of poly-methyl-methacrylate (PMMA) to electron-beam irradiation. Inhomogeneous anisotropic strain and out-of-plane deformation are demonstrated and studied by Raman, scanning-electron and atomic-force microscopy. These can all be easily combined with the present device architecture. The flexibility of the present method opens new opportunities for the investigation of strain and nanomechanics in two-dimensional materials.

cond-mat.mes-hall

Anisotropic straining of graphene using micropatterned SiN membranes

We use micro-Raman spectroscopy to study strain profiles in graphene monolayers suspended over SiN membranes micropatterned with holes of non-circular geometry. We show that a uniform differential pressure load $\Delta P$ over elliptical regions of free-standing graphene yields measurable deviations from hydrostatic strain conventionally observed in radially-symmetric microbubbles. The top hydrostatic strain $\bar{\varepsilon}$ we observe is estimated to be $\approx0.7\%$ for $\Delta P = 1\,{\rm bar}$ in graphene clamped to elliptical SiN holes with axis $40$ and $20\,{\rm \mu m}$. In the same configuration, we report a $G_\pm$ splitting of $10\,{\rm cm^{-1}}$ which is in good agreement with the calculated anisotropy $\Delta\varepsilon \approx 0.6\%$ for our device geometry. Our results are consistent with the most recent reports on the Gr\"uneisen parameters. Perspectives for the achievement of arbitrary strain configurations by designing suitable SiN holes and boundary clamping conditions are discussed.

cond-mat.mtrl-sci

Thermal noise and optomechanical features in the emission of a membrane-coupled compound cavity laser diode

We demonstrate the use of a compound optical cavity as linear displacement detector, by measuring the thermal motion of a silicon nitride suspended membrane acting as the external mirror of a near-infrared Littrow laser diode. Fluctuations in the laser optical power induced by the membrane vibrations are collected by a photodiode integrated within the laser, and then measured with a spectrum analyzer. The dynamics of the membrane driven by a piezoelectric actuator is investigated as a function of air pressure and actuator displacement in a homodyne configuration. The high Q-factor ($\sim 3.4\cdot 10^4$ at $8.3 \cdot 10^{-3}$ mbar) of the fundamental mechanical mode at $\sim 73$ kHz guarantees a detection sensitivity high enough for direct measurement of thermal motion at room temperature ($\sim 87$ pm RMS). The compound cavity system here introduced can be employed as a table-top, cost-effective linear displacement detector for cavity optomechanics. Furthermore, thanks to the strong optical nonlinearities of the laser compound cavity, these systems open new perspectives in the study of non-Markovian quantum properties at the mesoscale.

cond-mat.mes-hall

Revealing the atomic structure of the buffer layer between SiC(0001) and epitaxial graphene

On the SiC(0001) surface (the silicon face of SiC), epitaxial graphene is obtained by sublimation of Si from the substrate. The graphene film is separated from the bulk by a carbon-rich interface layer (hereafter called the buffer layer) which in part covalently binds to the substrate. Its structural and electronic properties are currently under debate. In the present work we report scanning tunneling microscopy (STM) studies of the buffer layer and of quasi-free-standing monolayer graphene (QFMLG) that is obtained by decoupling the buffer layer from the SiC(0001) substrate by means of hydrogen intercalation. Atomic resolution STM images of the buffer layer reveal that, within the periodic structural corrugation of this interfacial layer, the arrangement of atoms is topologically identical to that of graphene. After hydrogen intercalation, we show that the resulting QFMLG is relieved from the periodic corrugation and presents no detectable defect sites.

cond-mat.mes-hall