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G. Collins

Publications and source records attributed to G. Collins.

8 recordsLinked to original sources

Nanosecond timescale plasticity in shock-compressed polycrystalline MgO: evidence for transition in mechanism above 100 GPa

The mechanical properties of ceramics under extreme conditions directly impact applications ranging from shielding spacecrafts, designing plasma facing materials in nuclear fusion to understanding the rheology of deep planetary interiors. Here, we use polycrystalline MgO as a model ceramic to understand the high-pressure-temperature mechanical behaviour of such materials under extreme strain rates. We use laser-driven shock compression up to 175(15) GPa on the principal Hugoniot along with ultrafast diagnostics at the European X-ray Free Electron Laser to probe the dominant deformation mechanisms with changing P -T conditions. These near-instantaneous time-resolved snapshots, coupled with elasto-viscoplastic self-consistent (EVPSC) simulations, strongly suggest that MgO attains plastic regime in the nanoseconds scale accompanied by a pressure-mediated change in dominant slip system between 95 and 175 GPa. This work provides a new direct window into the deformation dynamics of polycrystalline ceramics under high-velocity impacts.

cond-mat.mtrl-sci

Volume Collapse Without a Structural Transition in Shock-Compressed FeO

We report x-ray diffraction and emission spectroscopy of FeO under laser-driven shock compression between 31-199 GPa. FeO retains the B1 (rocksalt) structure along the Hugoniot to the melt boundary at 191 GPa. While the phase and volume are broadly consistent with results from static compression, we observe an anomalous 7-10% volume collapse around 60 GPa absent in static experiments. We identify this as an isostructural high-spin to low-spin metallic transition in FeO. The low-spin state is directly evidenced by x-ray emission spectroscopy at 180 GPa.

cond-mat.mtrl-sci

X-ray thermal diffuse scattering as a texture-robust temperature diagnostic for dynamically compressed solids

We present a model of x-ray thermal diffuse scattering (TDS) from a cubic polycrystal with an arbitrary crystallographic texture, based on the classic approach of Warren. We compare the predictions of our model with femtosecond x-ray diffraction patterns obtained from ambient and dynamically compressed rolled copper foils obtained at the High Energy Density (HED) instrument of the European X-Ray Free-Electron Laser (EuXFEL), and find that the texture-aware TDS model yields more accurate results than does the conventional powder model owed to Warren. Nevertheless, we further show that: with sufficient angular detector coverage, the TDS signal is largely unchanged by sample orientation and in all cases strongly resembles the signal from a perfectly random powder; shot-to-shot fluctuations in the TDS signal resulting from grain-sampling statistics are at the percent level, in stark contrast to the fluctuations in the Bragg-peak intensities (which are over an order of magnitude greater); and TDS is largely unchanged even following texture evolution caused by compression-induced plastic deformation. We conclude that TDS is robust against texture variation, making it a flexible temperature diagnostic applicable just as well to off-the-shelf commercial foils as to ideal powders.

physics.app-ph

Femtosecond temperature measurements of laser-shocked copper deduced from the intensity of the x-ray thermal diffuse scattering

We present 50-fs, single-shot measurements of the x-ray thermal diffuse scattering (TDS) from copper foils that have been shocked via nanosecond laser-ablation up to pressures above 135~GPa. We hence deduce the x-ray Debye-Waller (DW) factor, providing a temperature measurement. The targets were laser-shocked with the DiPOLE 100-X laser at the High Energy Density (HED) endstation of the European X-ray Free-Electron Laser (EuXFEL). Single x-ray pulses, with a photon energy of 18 keV, were scattered from the samples and recorded on Varex detectors. Despite the targets being highly textured (as evinced by large variations in the elastic scattering), and with such texture changing upon compression, the absolute intensity of the azimuthally averaged inelastic TDS between the Bragg peaks is largely insensitive to these changes, and, allowing for both Compton scattering and the low-level scattering from a sacrificial ablator layer, provides a reliable measurement of $T/\Theta_D^2$, where $\Theta_D$ is the Debye temperature. We compare our results with the predictions of the SESAME 3336 and LEOS 290 equations of state for copper, and find good agreement within experimental errors. We thus demonstrate that single-shot temperature measurements of dynamically compressed materials can be made via thermal diffuse scattering of XFEL radation.

cond-mat.mtrl-sci

Multiscale modelling of de novo anaerobic granulation

A multiscale mathematical model is presented to describe the de novo granulation and the evolution of multispecies granular biofilms within a continuous reactor. The granule is modelled as a spherical free boundary domain with radial symmetry. The equation which governs the free boundary is derived from global mass balance considerations and takes into account the growth of sessile biomass and the exchange fluxes with the bulk liquid. Starting from a vanishing initial value, the expansion of the free boundary is initiated by the attachment process, which depends on the microbial species concentrations within the bulk liquid and their specific attachment velocity. Nonlinear hyperbolic PDEs model the growth of the sessile microbial species, while quasi-linear parabolic PDEs govern the dynamics of substrates and invading species within the granular biofilm. Nonlinear ODEs govern the evolution of soluble substrates and planktonic biomass within the bulk liquid. The model is applied to an anaerobic granular-based system and solved numerically to test its qualitative behaviour and explore the main aspects of de novo anaerobic granulation: ecology, biomass distribution, relative abundance, dimensional evolution of the granules and soluble substrates and planktonic biomass dynamics within the reactor. The numerical results confirm that the model accurately describes the ecology and the concentrically-layered structure of anaerobic granules observed experimentally, and is able to predict the effects of some significant factors, such as influent wastewater composition, granulation properties of planktonic biomass, biomass density and hydrodynamic and shear stress conditions, on the process performance.

q-bio.PE

Compact Low-Voltage, High-Power, Multi-beam Klystron for ILC: Initial Test Results

Initial test results of an L-band multi-beam klystron with parameters relevant for ILC are presented. The chief distinction of this tube from MBKs already developed for ILC is its low operating voltage of 60 kV, a virtue that implies considerable technological simplifications in the accelerator complex. To demonstrate the concept underlying the tubes design, a six-beamlet quadrant (a 54 inch high one-quarter portion of the full 1.3 GHz tube) was built and recently underwent initial tests, with main goals of demonstrating rated gun perveance, rated gain, and at least one-quarter of the full 10-MW rated power. Our initial three-day conditioning campaign without RF drive (140 microsec pulses @ 60 Hz) was stopped at 53% of full rated duty because of time-limits at the test-site; no signs appeared that would seem to prevent achieving full duty operation (i.e., 1.6 msec pulses @ 10 Hz). The subsequent tests with 10-15 microsec RF pulses confirmed the rated gain, produced output powers of up to 2.86 MW at 60 kV with high efficiency and 56 dB gain, and showed acceptable beam interception. These results suggest that a full version of the tube should be able to produce up to 11.5 MW. Follow-on tests are planned for later in 2015.

physics.acc-ph

x- and xi-scaling of the Nuclear Structure Function at Large x

Inclusive electron scattering data are presented for ^2H and Fe targets at an incident electron energy of 4.045 GeV for a range of momentum transfers from Q^2 = 1 to 7 (GeV/c)^2. Data were taken at Jefferson Laboratory for low values of energy loss, corresponding to values of Bjorken x greater than or near 1. The structure functions do not show scaling in x in this range, where inelastic scattering is not expected to dominate the cross section. The data do show scaling, however, in the Nachtmann variable ξ. This scaling may be the result of Bloom Gilman duality in the nucleon structure function combined with the Fermi motion of the nucleons in the nucleus. The resulting extension of scaling to larger values of ξopens up the possibility of accessing nuclear structure functions in the high-x region at lower values of Q^2 than previously believed.

nucl-ex

2Planning for Contingencies: A Decision-based Approach

A fundamental assumption made by classical AI planners is that there is no uncertainty in the world: the planner has full knowledge of the conditions under which the plan will be executed and the outcome of every action is fully predictable. These planners cannot therefore construct contingency plans, i.e., plans in which different actions are performed in different circumstances. In this paper we discuss some issues that arise in the representation and construction of contingency plans and describe Cassandra, a partial-order contingency planner. Cassandra uses explicit decision-steps that enable the agent executing the plan to decide which plan branch to follow. The decision-steps in a plan result in subgoals to acquire knowledge, which are planned for in the same way as any other subgoals. Cassandra thus distinguishes the process of gathering information from the process of making decisions. The explicit representation of decisions in Cassandra allows a coherent approach to the problems of contingent planning, and provides a solid base for extensions such as the use of different decision-making procedures.

cs.AI