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G. Gopakumar

Publications and source records attributed to G. Gopakumar.

5 recordsLinked to original sources

Lightweight Vision Transformer Compression for On-Device Plant Disease Detection in Resource-Constrained Agricultural Field Conditions

Chilli (Capsicum annuum) is one of India's most economically significant crops, yet its productivity is persistently threatened by diseases that are difficult to identify without expert intervention. While Vision Transformers (ViTs) have achieved high classification accuracy, their large computational footprint makes deployment on resource constrained devices challenging. Existing compression approaches typically address pruning, quantization, and knowledge distillation in isolation, leaving the potential benefits and interactions of their combined application insufficiently explored. We propose a unified Vision Transformer compression framework that combines Hessian-Balanced Adaptive Block Pruning (H-BAC), guided by second-order sensitivity estimation, with quantization and attention-based knowledge distillation. To systematically identify the most effective configuration within each compression family, each technique is first evaluated independently through controlled ablation studies, after which the best-performing components are integrated into a sequential deployment pipeline tailored to real-world agricultural constraints. On a chilli 3-class village-split dataset with a genuine cross-village, cross-device out-of-distribution test split, the resulting compressed models match or exceed the 95.13% FP32 baseline's accuracy, alongside 74-98% model size reduction, and the fully integrated compression pipeline achieves a 54.5x size reduction (327.42 MB to 6.01 MB) at 95.13 +/- 2.32% accuracy across four tested configurations. A direct comparison further reveals that, on this dataset, a directly-trained student of the same final size, without pruning or distillation, reaches comparable accuracy of 94.87%, at the same 6.01 MB INT8 size, indicating where H-BAC and knowledge distillation are, and are not yet shown to be, worth their computational cost.

cs.CV

Infrared Spectra and Chemical Abundance of Methyl Propionate in Icy Astrochemical Conditions

We carried out an experiment in order to obtain the InfraRed (IR) spectra of methyl propionate (CH3CH2COOCH3) in astrochemical conditions and present the IR spectra for future identification of this molecule in the InterStellar Medium (ISM). The experimental IR spectrum is compared with the theoretical spectrum and an attempt was made to assign the observed peak positions to their corresponding molecular vibrations in condensed phase. Moreover, our calculations suggest that methyl propionate must be synthesized efficiently within the complex chemical network of the ISM and therefore be present in cold dust grains, awaiting identification.

astro-ph.GA

Application of a Relativistic Coupled-Cluster Theory to the Effective Electric Field in YbF

An accurate determination of the effective electric field (Eeff) in YbF is important, as it can be combined with the results of future experiments to give an improved new limit for the electric dipole moment of the electron. We report a relativistic coupled-cluster calculation of this quantity in which all the core electrons were excited. It surpasses the approximations made in the previous reported calculations. We obtain a value of 23.1 GV/cm for Eeff in YbF with an estimated error of less than 10%. The crucial roles of the basis sets and the core excitations in our work are discussed.

physics.atom-ph

Chemical Bonding in the Boron Buckyball

A symmetry analysis of the valence shell in the boron buckyball B80, shows a perfect match with the symmetry of the valence shell in C60 .The cap atoms participate in the bonding by 30 orbitals which transform as the sigma bonds along the 6-6 edges. Far reaching consequences for chemical and physical properties of B80, which until now only exists in silico, are expected.

cond-mat.mtrl-sci

The Boron Buckyball has an Unexpected Th Symmetry

The boron buckyball avoids the high symmetry icosahedral cage structure. The previously reported Ih symmetric structure is not an energy minimum in the potential energy surface and exhibits a spontaneous symmetry breaking to yield a puckered cage with a rare Th symmetry. The HOMO-LUMO gap is twice as large as the reported value and amounts to 1.94 eV at B3LYP/6-31G(d) level. The valence orbital structure of boron buckyball is identical to the one in the carbon analogue.

cond-mat.other