Search arXiv⌕ Search

arXiv subjects

Hong Guo

Publications and source records attributed to Hong Guo.

At least 37 records · Page 2Linked to original sources
arXiv2026

Region-Resolved Interface Descriptors in III-nitride-nanocluster photocatalysts

Understanding how nanocluster cocatalysts modify the electronic structure of III-nitride surfaces is central to the rational design of efficient photocatalytic interfaces. Here, we introduce a region-resolved first-principles framework for analyzing GaN-, InGaN-, and ScGaN-based slabs decorated with six-atom elemental nanoclusters. Using a region-resolved projected local density of states (PLDOS) analysis, we separate electronic response of nanocluster-covered regions from that of uncovered semiconductor surface regions, revealing that semiconductor--nanocluster interfaces behave as laterally heterogeneous systems. In this picture, nanocluster-covered regions are associated with local band bending, charge injection, and nanocluster-induced gap states, whereas uncovered nitride regions retain surface-localized states and in-plane dipoles that may influence adsorbate interactions and water-activation pathways. These distinct regional responses motivate the definition of region-resolved interface descriptors, which are further integrated into an Interface Score: a physics-informed comparative metric that combines injection, activation, and interfacial-coupling contributions to rank heterogeneous model interfaces on a common descriptor basis. Machine-learning models trained on global and region-resolved descriptors are used primarily as interpretability tools to assess their correlation with single-H adsorption energetics. The results show that spatially averaged descriptors capture broad adsorption-energy trends, while region-resolved descriptors expose complementary local information related to interfacial electrostatics and charge separation. Together, this work establishes a descriptor framework for moving beyond spatially averaged electronic-structure analysis and for bridging first-principles calculations with experimental interpretation of heterogeneous photocatalytic interfaces.

cond-mat.mtrl-sci↗
arXiv2026

Discrete-modulated continuous-variable quantum key distribution with uncertainty principle

Continuous-variable quantum key distribution is a compelling framework for scalable quantum networks due to its seamless integration with existing optical communication infrastructure. However, a fundamental gap persists between theoretical protocols requiring ideal Gaussian modulation and the constrained, discrete-modulated signals dictated by practical high-speed hardware. Current security proofs for discrete modulation rely on semidefinite programming, which suffers from prohibitive computational overhead for high-order constellations and lacks direct physical insight into non-Gaussian modulation.In this Letter, we overcome this limitation by developing a security framework that obviates semidefinite programming in favor of an approach grounded fundamentally in the Heisenberg uncertainty principle. By introducing a multi-mode entanglement-source model to characterize non-Gaussian state preparation, we establish an explicit mapping between constellation geometry and the secret key rate. This framework effectively quantifies the security implications of hardware-limited, finite state preparation, enabling both numerical and analytical security analysis under high-order constellations. We experimentally validate our method on both discrete-component and integrated photonic platforms, demonstrating that a quadrature amplitude modulation format with 256 constellation points can asymptotically approach the Gaussian capacity limit. Beyond quantum key distribution, the principle of tightening uncertainty-constrained bounds via source-mode expansion offers a paradigm for exploring the information-theoretic properties of complex non-Gaussian systems.

quant-ph↗
arXiv2026

CSST large-scale structure analysis pipeline: IV. Cosmic Voids Identified from Galaxy Group Samples as Probes of the Large-scale Structure

Because groups are directly associated with halos, they allow for considerably simpler theoretical modeling than approaches based on individual galaxies. We therefore propose to use voids identified in galaxy group catalogs, referred to as group-voids, to investigate the cosmic large-scale structure (LSS). Using the reference mock galaxy redshift survey (MGRS) designed for the Chinese Space-station Survey Telescope (CSST), we build two galaxy group catalogs representing ideal and realistic scenarios, derived from galaxy samples with 100\% and roughly 30\% spectroscopic redshift completeness, respectively. We then identify voids in these two mock group catalogs, as well as in the underlying halo catalog, and measure two void statistics, the void size function (VSF) and the void density profile, within five redshift intervals spanning $z=0$ to $1.0$. We compare the statistics obtained from two kinds of voids: those defined by galaxy groups (group-voids) and those defined by dark matter halos (halo-voids). In the void-finding process, we adopt the brightest central galaxy (BCG) as the group center to improve the accuracy of the inferred void centers. Our analysis shows that void statistics derived from group-voids with spectroscopic redshift completeness of at least 40\% can faithfully reproduce the corresponding statistics from halo-voids. Even when the redshift completeness of galaxies falls to as low as 30\%, we can still reliably describe group-voids via halo-voids by incorporating a redshift error term. This indicates that group-voids are a promising tool for probing LSS and offer a valuable complement to standard void studies, which is especially advantageous for emulator-based methods.

astro-ph.CO↗
arXiv2026

LatticeMind: A Validation-Gated Agentic Framework for Density Functional Theory Workflows

First-principles calculations are rarely single solver calls: they are multistage workflows in which structures, settings, and saved densities must pass correctly between dependent stages. Language models can write a valid single input, but reliability collapses once stages are chained: a dropped dependency, wrong file handoff, or hallucinated keyword can invalidate results even when the solver runs, and such errors surface only after costly execution. We introduce LatticeMind, a validation-gated agentic framework that converts natural-language requests into executable, checkable density functional theory (DFT) projects. A workflow contract specifies required stages, files, and dependencies; deterministic validators inspect the project before any solver launch; failed checks trigger bounded repair; and reports remain traceable to project files. On a 44-case RESCU benchmark spanning total-energy, density-of-states, band-structure, magnetic, phonon workflows, three non-flagship LLM backends reproduced every reference value; 119 of 132 runs passed on the first validated plan and the rest after one repair cycle. Ablations identify the workflow contract and pre-execution validation as the principal reliability mechanisms; a conventional trial-and-repair baseline reaches 71% at twice the token cost per success. The same architecture reproduces every reference value on a 19-case VASP benchmark, demonstrating transfer across solvers. Beyond these task families, LatticeMind generated and validated the 23 inputs of a multistage study of Rh-induced electronic responses at a Rh$_6$/In$_x$Ga$_{1-x}$N photocatalyst interface. These results establish workflow contracts, deterministic validation, bounded repair, and traceable records as a practical foundation for reliable AI-assisted scientific computing, where preventable errors are caught before execution and the solver is never the first validator.

cond-mat.mtrl-sci↗
arXiv2026

First-principles predictions of band alignment in strained Si/Si1-xGex and Ge/Si1-xGex heterostructures

Accurate band offsets are essential for predictive continuum modeling of nanostructures such as quantum wells and quantum dots formed in strained Si/Si1-xGex and Ge/Si1-xGex heterostructures. Experimental offset data for these systems remain sparse away from endpoint compositions, making composition-dependent design difficult. We use atomistic first-principles density functional theory to compute valence- and conduction-band offsets across the full range 0 <= x <= 1. Random alloying is treated with special quasirandom structures, interface lineup terms are extracted from macroscopically averaged local Kohn-Sham potentials in thick periodic superlattices, valence-band spin-orbit coupling is included through species-resolved Mulliken weights, and conduction-band edges are refined using the screened hybrid Heyd-Scuseria-Ernzerhof functional. The resulting offsets show pronounced composition nonlinearity beyond the linear models explored in previous works, agree with experimental benchmarks, and reproduce the high-Ge slope change in the relaxed-alloy band gap. Analytic fitting expressions are provided for direct use in simulations, facilitating practical design of modern quantum technology devices.

cond-mat.mes-hall↗
arXiv2026

Scalarization of Einstein-Euler-Heisenberg black hole with multiple horizons

Scalarizations of the Einstein-Euler-Heisenberg (EEH) black hole (EEHBH) with multiple horizons are investigated in the EEH-scalar theory by introducing a quadratic scalar coupling to the Maxwell term. For mass $M=1$ and Euler-Heisenberg parameter $μ=0.03$, the magnetically charged EEHBH admits four horizon families (low, cold, negative, and hot), with triple horizons appearing in the narrow band of magnetic charge $q\in[0.95,1.0065]$. The onset scalarization around the low, cold, and high horizons is then analyzed for the magnetic charge $q=0.5,\,1,\,2$, implying infinite branches of scalarized black holes for each case. We construct the three fundamental branches of scalarized black holes. From the positivity condition of their mass, we find the upper bounds on primary scalar charges $q_{s}$ for scalarized low and cold horizons. These bounds determine the allowable regions for the Hawking temperature and entropy. Furthermore, we perform a time-domain stability analysis and find that the instabilities arise only at small scalar charge regime. Therefore, stable and physically viable scalarized black holes exist in an intermediate window of the primary scalar charge for low and cold horizon solutions and a lower bound for hot horizon solution.

gr-qc↗
arXiv2026

The FAST All Sky HI Survey DR2: the FASHI Catalog and the HI Mass Function

The FAST All Sky HI Survey (FASHI) conducted with the Five-hundred-meter Aperture Spherical radio Telescope (FAST) has mapped $\sim 19500\,\mathrm{deg}^2$ of the sky north of DEC $= -14^{\circ}$, detecting $156411$ extragalactic HI sources at $z< 0.09$ with a median sensitivity of $0.57\,\mathrm{mJy}\,\mathrm{beam}^{-1}$ at a velocity resolution of $6.4\,\mathrm{km}\,\mathrm{s}^{-1}$. The survey achieves unprecedented depth and area coverage, significantly improving upon previous single-dish surveys. Through a detailed completeness analysis that accounts for the survey's non-uniform sensitivity and line-width dependence, we construct a robust HI mass function (HIMF) using a completeness-corrected sample of over $109000$ sources. The HIMF is robustly constrained down to $M_{\mathrm{HI}}\sim 10^{6.2}\,M_{\odot}$. When systematic uncertainties are included, the HIMF is well described by a single-Schechter function with a characteristic mass $\log (M_{*} / h_{70}^{-2}M_{\odot}) = 9.89\pm 0.02$, low-mass end slope $α= -1.31\pm 0.02$, and amplitude $ϕ_{*} = (6.38\pm 0.49)\times 10^{-3}\,h_{70}^{3}\,\mathrm{Mpc}^{-3}\,\mathrm{dex}^{-1}$. The derived cosmic HI density is $Ω_{\mathrm{HI}} = (4.71\pm 0.03_{\mathrm{stat}}\pm 0.40_{\mathrm{sys}})\times 10^{-4}\,h_{70}^{-1}$. FASHI provides the most extensive and sensitive HI catalog to date, establishing an important benchmark for studies of gas accretion, galaxy evolution, and large-scale structure in the local universe.

astro-ph.GA↗
arXiv2026

Moiré Phonon Condensation in Magic-Angle Twisted Bilayer Graphene

Twisted bilayer graphene reconstructs from weak breathing corrugation to large common bending near the magic angle, but the origin of this collective crossover has remained unclear. Here we show that the crossover is a soft-mode condensation of layer-symmetric $A_1$ moiré flexural phonons: these modes soften on the breathing branch, lose stiffness near the magic angle, and freeze into the bending morphology. We call this mechanism Moiré Phonon Condensation (MPC). At $θ=1.08^\circ$, it is extremely surprising that displacements of all 11164 atoms in the moiré supercell, with a maximum atomic position shift of 2.30 Angstrom, is captured by only two $A_1$ phonon modes at more than $99.5\%$ spectral weight. A first-harmonic continuum theory identifies a dimensionless control parameter of the phenomenon, showing that as the twist approaches the magic angle, the growing moiré length scale amplifies a smooth stress-bending competition until the flexural stiffness changes sign. Mode-resolved tight-binding calculations further show that the condensed phonon coordinates are electronically active. This work identifies MPC as a twist-controlled structural order parameter for moiré reconstruction.

cond-mat.mes-hall↗
arXiv2026

Weak Evolution of Cosmic Atomic Hydrogen over the Past 4.5 Billion Years

The cosmic star formation rate density (CSFRD) has declined sharply toward the present day, but the roles of the atomic and molecular gas reservoirs remain uncertain. We measure the cosmic HI density, $Ω_{\mathrm{HI}}$, over $0<z<0.41$ by combining HI spectra from the Five-hundred-meter Aperture Spherical Telescope with optical spectroscopy from the Dark Energy Spectroscopic Instrument for $\sim2.5$ million galaxies across $\sim12,000\,{\rm deg}^2$. We measure a raw decrease in $Ω_{\mathrm{HI}}$ by a factor of $1.35\pm0.10$ over the past 4.5 Gyr. Even after applying the conservative systematic corrections from our forward model, the inferred decline is only $1.12\pm0.10$ -- still far weaker than the CSFRD decline (a factor of 2.46). The molecular gas density, in contrast, is known to evolve more closely with star formation. At fixed stellar mass, the average HI gas fraction evolves by less than 0.2 dex, showing that the weak evolution is present across the galaxy population. These quantitative differences rule out rapid depletion of galaxy HI as the primary driver of the late-time CSFRD decline, and provide a stringent benchmark for models of gas accretion, phase conversion and star-formation regulation.

astro-ph.GA↗
arXiv2026

Search for a solar-bound axion halo using the Global Network of Optical Magnetometers for Exotic physics searches

We report on a search for a gravitationally bound solar axion halo using data from the Global Network of Optical Magnetometers for Exotic physics searches (GNOME), a worldwide array of magnetically shielded atomic magnetometers with sensitivity to exotic spin couplings. Motivated by recent theoretical work suggesting that self-interacting ultralight axions can be captured by the Sun's gravitational field and thermalize into the ground state, we develop a signal model for the pseudo-magnetic fields generated by axion-proton gradient couplings in such a halo. The analysis focuses on the fifth GNOME Science Run (69 days, 12 stations), employing a cross-correlation pipeline with time-shifted daily modulation templates to search for the global, direction-dependent, monochromatic signal expected from a solar axion halo. No statistically significant candidate signals are observed. We set 95% confidence-level upper limits on the amplitude of the axion-induced pseudo-magnetic field over the frequency range $\approx 0.05-20$ Hz, translating to constraints on the linear and quadratic axion-proton couplings for halo densities predicted by gravitational capture models and for the maximum overdensities allowed by planetary ephemerides. In the quadratic coupling case, our limits surpass existing astrophysical bounds by over two orders of magnitude across much of the accessible parameter space.

physics.atom-ph↗
arXiv2026

APEX4: Efficient Pure W4A4 LLM Inference via Intra-SM Compute Rebalancing

W4A4 quantization promises full utilization of INT4 Tensor Cores, yet group dequantization overhead on CUDA Cores has driven existing systems to mixed-precision fallbacks. We present the first systematic study of how intra-SM compute balance governs this bottleneck. Through controlled benchmarks across four GPUs from Ampere and Ada architectures, we identify the Tensor Cores to CUDA Cores throughput ratio ($ρ$) as the primary hardware indicator: the W4A4-g128 kernel yields $2.0$--$2.5\times$ speedup on RTX~3090 ($ρ=16$) yet degrades to $0.43$--$0.47\times$ on A100 ($ρ=64$) in compute-bond scenarios, establishing W4A4 viability as platform-dependent rather than universally infeasible. Guided by this finding, we build \textbf{APEX4}, which co-designs pure INT4 GEMM kernels with $ρ$-aware granularity adaptation to mitigate the CUDA Cores dequantization bottleneck. APEX4 achieves perplexity within 0.63 of FP16 on LLaMA-2-70B and outperforms W4Ax Atom-g128 by 4.0\%--4.4\% in zero-shot accuracy. Deployed as a drop-in replacement in unmodified vLLM, it delivers up to $1.66\times$ end-to-end speedup on L40S ($ρ=8$), and $1.78\times$ on RTX~3090 ($ρ=16$), $2.09\times$ on A40 ($ρ=16$), while recovering A100 ($ρ=64$) to $1.20$--$1.40\times$ via the mixed-granularity mode. Our code is available at https://github.com/APEX4-W4A4/APEX4-W4A4.

cs.DC↗
arXiv2026

Robustness of cosmic void statistics: insights from SDSS DR7 and the ELUCID simulation

We present a systematic analysis of the statistical properties of cosmic voids using galaxies from the Sloan Digital Sky Survey Data Release 7 (SDSS DR7) and subhaloes from the ELUCID constrained simulation. By comparing voids identified in redshift space, real space, and reconstructed volumes, we assess the impact of redshift-space distortions (RSD) and tracer bias. Using the \texttt{VAST} toolkit, we apply both the geometry-based \texttt{VoidFinder} algorithm and watershed-based methods. We find that void properties are not equally robust. The three-dimensional morphology of voids, quantified by their sphericity and triaxiality, remains stable across different reconstructions and tracer selections. In contrast, void size distributions and radial density profiles depend strongly on the identification algorithm, with watershed-based methods systematically producing larger voids and higher compensation walls than \texttt{VoidFinder}. Using the full ELUCID simulation box, we show that tracer bias mainly affects void density profiles, with noticeable changes only for the most massive subhaloes ($>10^{11.5}\,h^{-1}{\rm M}_\odot$). The agreement between SDSS observations, the ELUCID reconstruction, and the full simulation box demonstrates the high fidelity of constrained simulations and reveals a clear hierarchy in the robustness of void statistics.

astro-ph.CO↗
arXiv2026

Spin-Orbit Torque and Magnetization Switching in 2D Ferromagnetic Devices

Current-induced spin-orbit torque has emerged as a powerful technique for manipulating magnetization switching of ferromagnet/nonmagnet (FM/NM) based memory cell. By investigating nonequilibrium spin torque effect in a van der Waals heterobilayer, trigonal $\text{Cr}_{3}\text{Te}_{4}/\text{PtTe}_{2}$, the first-principles quantum transport calculations are applied to determine both local spin induction, resulting from Rashba-Edelstein effect in the FM layer, and spin current injection, flowing from the NM to the FM layer. Our work reveals that local spin induction significantly generates the fieldlike torque, which primarily governs the switching current in systems with strong in-plane magnetic anisotropy. Our work emphasizes the importance of optimizing spin Hall effect in the NM layer for perpendicular magnetic anisotropy (PMA)-based magnetization switching and maximizing the Rashba effect in the FM layer for in-plane magnetic anisotropy (IMA)-based switching.

cond-mat.mes-hall↗
arXiv2026

Sample Where You Struggle: Sharpening Base Model Reasoning via Entropy-Guided Power Sampling

Sampling from the sequence-level power distribution $p^α$ elicits RL-level reasoning from base language models without any parameter updates, but the standard Metropolis--Hastings (MH), a Markov Chain Monte Carlo (MCMC) sampler, is both expensive and slow-mixing. We trace both to a structural mismatch: $p^α$ mainly departs from $p$ at a sparse, spatially clustered set of high-entropy decision points, yet MH proposes resampling positions uniformly along the prefix -- wasting compute on near-degenerate conditionals while under-mixing precisely where modes diverge. We propose Entropy-Guided Power Sampling (EGPS), a training-free and verifier-free sampler that re-derives its proposal from token-level entropy already in the forward pass. EGPS skips deterministic blocks, localizes each MCMC move to a high-entropy neighborhood, and applies Multiple-Try Metropolis at decision points -- making sampling cost scale with \emph{entropy mass rather than sequence length}. On Qwen2.5-Math-7B, EGPS reaches best or tied-best accuracy on all three benchmarks (MATH500 $75.8\%$, HumanEval $62.2\%$, GPQA $42.4\%$) at up to a $12.6\times$ wall-clock speedup over the MH baseline.

cs.LG↗
arXiv2026

The FAST Hundred-Deg$^2$ HI Deep (HD$^2$) Survey: Early Results from the Pilot Survey

The Hundred-deg$^2$ HI Deep (HD$^2$) survey carried out with the Five-hundred-meter Aperture Spherical Telescope (FAST) is planned to map a contiguous region within the DESI DR1 footprint, achieving an effective integration time of 20 minutes for each pointing and a uniform detection sensitivity of 0.28 mJy beam$^{-1}$ at 4.8 km s$^{-1}$ resolution. We present early results from the pilot HD$^2$ survey: a 10 deg$^2$ field overlapping with HSC-SSP and the DESI EDR SV3, observed with an integration time of 7.3 minutes per beam and the rms of 0.45 mJy beam$^{-1}$ at 4.8 km s$^{-1}$ resolution. We identify 339 HI sources at $z<0.09$, corresponding to $\sim$34 detections per deg$^2$, nearly six times higher than the detection rate of the wide-field surveys. Optical counterparts are primarily identified using DESI redshifts, yielding a matching rate and correctness exceeding 90% for galaxies with $r<19.5$ mag, a substantial improvement over SDSS. Under the constraint of $r < 17.8$ mag and $0.01 < z < 0.05$, nearly 50% of galaxies in the DESI BGS samples have HI detections in this pilot survey. The optical properties of these HI-detected galaxies span nearly the entire parameter range of the DESI sample. The gas fraction scaling relations versus stellar mass, stellar mass surface density, NUV-r, and specific star formation rate are consistent with previous surveys, e.g., ALFALFA, DINGO, and xGASS. These results justify the feasibility of the full HD$^2$ survey, which will build a high-completeness HI census over a contiguous area to probe the cold gas scaling relations of galaxies over different scales.

astro-ph.GA↗
arXiv2026

Gauss-Bonnet scalarization of charged qOS-black holes

The Gauss-Bonnet (GB) scalarization for charged quantum Oppenheimer-Snyder (cqOS)-black holes is investigated in the Einstein-Gauss-Bonnet-scalar theory with the nonlinear electrodynamics (NED) term. Here, the scalar coupling function to GB term is given by $f(ϕ)=2λϕ^2$ with a coupling constant $λ$. Three parameters of mass ($M$), action parameter ($α$), and magnetic charge ($P$) are necessary to describe the cqOS-black hole, and it may become the qOS-black hole when $P=M$. The GB scalarization of cqOS-black holes comes into two cases GB$^\pm$, depending on the sign of GB term which triggers the different phenomena. For $α=0$ and $λ>0$, GB$^+$ scalarization is allowed, while for $α\not=0$ and $λ<0$, GB$^-$ scalarization appears for a narrow band of $3.5653\le α\le 4.6875$. After discussing the onset GB$^-$ scalarization, we construct scalarized cqOS-black holes which belong to the single branch. The scalar field decays much more rapidly compared to the GB$^+$ case. Stability analysis shows these scalarized black holes are linearly stable under scalar perturbations.

gr-qc↗
arXiv2026

Filtering Interlopers with Photometry and Diagnostic Features: A Machine Learning Framework Validated with CSST Slitless Spectroscopy

The slitless spectroscopic method employed by missions such as Euclid and the Chinese Space-station Survey Telescope (CSST) faces a fundamental challenge: spectroscopic redshifts derived from their data are susceptible to emission-line misidentification due to the limited spectral resolution and signal-to-noise ratio. This effect systematically introduces interloper galaxies into the sample. Conventional strict selection not only struggles to secure high redshift purity but also drastically reduces completeness by discarding valuable data. To overcome this limitation, we develop an XGBoost classifier that leverages photometric properties and spectroscopic diagnostics to construct a high-purity redshift catalog while maximizing completeness. We validate this method on a simulated sample with spectra generated by the CSST emulator for slitless spectroscopy. Of the $\sim$62 million galaxies that obtain valid redshifts (parent sample), approximately 43% achieve accurate measurements, defined as $|Δz| \leqslant 0.002(1+z)$. From this parent sample, the XGBoost classifier selects galaxies with a selection efficiency of 42.3% on the test set and 42.2% when deployed on the entire parent sample. Crucially, among the retained galaxies, 96.6% (parent sample: 96.5%) achieve accurate measurements, while the outlier fraction ($|Δz|>0.01(1+z)$) is constrained to 0.13% (0.11%). We verified that simplified configurations that exclude either spectroscopic diagnostics (except the measured redshift) or photometric data yield significantly higher outlier fractions, increasing by factors of approximately 3.5 and 6.3, respectively, with the latter case also introducing notable catastrophic interloper contamination. This framework effectively resolves the purity-completeness trade-off, enabling robust large-scale cosmological studies with CSST and similar surveys.

astro-ph.CO↗
arXiv2026

Termination-Controlled Fractionalization and Hybridization at Topological Interfaces in Organic Spin Chains

A single organic spin platform hosts both dimerized $S=\tfrac{1}{2}$ and effective Haldane $S=1$ sectors, linked by bond-texture inversion. At the junction, the fractional mode is controlled by termination parity: quenched by local fusion at one termination and released as an uncompensated spin-$\tfrac{1}{2}$-like degree of freedom at the parity-shifted one. Two such internal boundary modes of a finite embedded Haldane domain hybridize with an exponentially decaying splitting, establishing termination parity as a design principle for engineering and coupling fractional boundary modes.

cond-mat.str-el↗