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Irshad K A

Publications and source records attributed to Irshad K A.

2 recordsLinked to original sources

Tunability of the structural and magnetic transition in kagome material: PrIr$_3$B$_2$

We report the temperature and pressure tunability of an unusual structural transformation associated with a two-step metal-insulator-metal (MIM) transition in the kagome lattice compound PrIr$_3$B$_2$ using synchrotron X-ray powder diffraction. At ambient conditions of temperature and pressure, the monoclinic ($C2/m$) and the hexagonal ($P6/mmm$) phases coexist as twinned structure in the crystal. As the temperature (pressure) is decreased (increased), PrIr$_3$B$_2$ converts fully to monoclinic structure at $T =$ 280 K (at ambient pressure) and $P =$ 1.2 GPa (at room temperature). Temperature dependence of the monoclinic structure at ambient pressure presents complex evolution of lattice parameters with weak but clearly discernable anomalies at \SI{\sim 250} {\K} and \SI{\sim 110} {\K}, which are correlated with the second MIM transition and the linear to nonlinear temperature-dependent resistivity crossover, respectively. These anomalies are likely due to some charge order state causing a partially gapped Fermi surface. The magnetic phase diagram of PrIr$_3$B$_2$ is also investigated from anisotropic measurements. At 10 K, a superzone gap opens near the antiferromagnetic transition, which does not close even in the polarized state. From the tunability of the crystal structure and magnetic and electronic ground state, promising electronic orders are indicated in this kagome metallic magnet.

cond-mat.str-el↗

Pressure-driven vibrational and structural peculiarities in the honeycomb layered magnetoelectrics Mn4(B)2O9 (B= Nb, Ta)

The high-pressure behavior of two Mn-based honeycomb-structured magnetoelectric materials, Mn4Nb2O9 (MNO) and Mn4Ta2O9 (MTO), was investigated using Raman spectroscopy, synchrotron x-ray diffraction, and density functional theory (DFT) calculations. In MTO, the application of a small pressure of only 0.5 GPa induces an isostructural transition driven by local symmetry breaking. With further increase in pressure, three additional isostructural transitions are observed at about 3.2, 6, and 10 GPa, followed by the onset of a long-range structural transition near 14 GPa, where the ambient P-3c1 phase begins to transform into a P2/c phase. These two phases coexist up to 27 GPa. The Nb analogue, MNO, also exhibits similar isostructural transitions at about 2, 6.6, and 10 GPa. However, the onset of the mixed P2/c and P-3c1 phases occurs at a slightly lower pressure of 12.5 GPa, with phase coexistence extending up to 26.5 GPa. These long-range transitions are supported by pressure-dependent enthalpy changes obtained from DFT calculations. Rietveld refinement reveals pronounced anisotropic lattice compression, with a 42 to 49 percent difference between the c and a axes, leading to a notable reduction in the c/a ratio. This anisotropy may strengthen interlayer coupling and promote magnetic ordering under compression, consistent with the appearance of Raman modes similar to those reported at low temperatures, together with anomalous changes in Raman mode linewidth and intensity. The marked changes in Raman self-energy parameters, anomalies in the reduced pressure-Eulerian strain profile, and the onset of local symmetry breaking at much lower pressures in MTO than in MNO highlight the important role of differences in spin-orbit coupling strength and orbital hybridization associated with Nb5+ and Ta5+ cations.

cond-mat.mtrl-sci↗