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Jiani Lin

Publications and source records attributed to Jiani Lin.

2 recordsLinked to original sources

A Priori Error Estimation of Physics-Informed Neural Networks Solving Allen--Cahn and Cahn--Hilliard Equations

Physics-Informed Neural Networks (PINNs) encounter accuracy limitations when solving the Allen--Cahn (AC) and Cahn--Hilliard (CH) partial differential equations (PDEs). To overcome this, we employ a novel loss function, Residuals-weighted Region Activation Evaluation (Residuals-RAE), featuring a { pre-training weight update scheme}. { Unlike conventional self-adaptive PINNs where weights evolve simultaneously with network parameters, Residuals-RAE-PINNs computes weights from current residuals before each training step and holds them constant during gradient updates. We establish weight convergence under standard neural network optimization assumptions, which justifies analyzing the converged network with constant weights.} Based on this theoretical framework, we derive the error estimation for PINNs with Residuals-RAE when solving AC and CH equations. {The analysis is aligned with Monte-Carlo sampling for the discretization of integrals, consistent with the numerical experiments.} Numerical experiments on one- and two-dimensional AC and CH systems confirm our theoretical results. Additionally, our analysis reveals that feedforward neural networks with two hidden layers and the tanh activation function bound the approximation errors of the solution, its temporal derivative, and the nonlinear term, constrained by the training loss and the number of collocation points.

math.NA

Reverse chemistry of iron in the deep Earth

In this work, we demonstrate a remarkable change of chemical trend of Iron under high pressure that is of great importance for understanding the distribution of elements in the Earth's mantle and core. Using first principles crystal structure search method, we conduct a systematic study of the propensity of p block elements to chemically bind with iron under high pressures ranging from ambient conditions to that of Earth's core. We show that under increasing pressure, iron tends to reverse its chemical nature, changing from an electron donor (reductant) to an electron acceptor, and oxidizes p-block elements in many compounds. Such reverse chemistry has a significant impact on the stoichiometries, bond types and strengths, structures and properties of iron compounds under deep planetary conditions.

physics.chem-ph