arXiv subjects

Jordi Sort

Publications and source records attributed to Jordi Sort.

18 recordsLinked to original sources

arXiv2026

Light-modulated exchange bias in multiferroic heterostructures

Magnetic straintronics, the strain-mediated control of magnetic anisotropy, has emerged as a key direction for next-generation energy-efficient technologies. In multiferroic heterostructures, magnetoelectric coupling is typically achieved by applying an electric field on a ferroelectric phase, inducing strain through the converse piezoelectric effect, which is then transferred to the adjacent ferromagnetic phase. As an alternative, strain can be remotely modulated through the photostrictive effect induced by light. While light-driven control of magnetic anisotropy has been explored, optical modulation of more complex phenomena such as exchange bias remains largely unaddressed. Here, we demonstrate significant light-induced modulation of exchange bias and magnetization switching at room temperature in a Pb(Mg1/3Nb2/3)O3-Pb(Zr,Ti)O3 (PMN-PZT)/Fe80Ga20(FeGa)/Ir20Mn80(IrMn) multiferroic heterostructure, driven by visible-light-photostriction. The magnetization state correlates with the light intensity, enabling multi-level states with light power densities as low as 0.1 W cm-2. These findings suggest a promising route toward low-power, multistate, and wireless opto-magnetic memory applications.

cond-mat.mtrl-sci↗

arXiv2025

Microsecond-Pulsed Nanocalorimetry: A Scalable Approach for Ultrasensitive Heat Capacity Measurements

We introduce a nanocalorimetric technique based on microsecond-pulsed heating (\mu s-PHnC) that enables high-sensitivity, quasi-isothermal heat capacity measurements on nanoscale samples. Such resolution is critical for exploring thermodynamic signatures in low-dimensional materials, where conventional techniques fall short. By confining thermal excitation to microsecond timescales, this approach minimizes lateral heat diffusion, reduces heat capacity addenda to below 10^{-9} J K^{-1}, and achieves noise densities as low as 75 pJ K^{-1} Hz^{-1/2} mm^{-2}, unlocking precise thermodynamic characterization of subnanogram samples in areas as small as 30 x 30 \mu m^{2}. The method delivers exceptional temperature homogeneity, as demonstrated by resolving sharp phase transitions, such as the antiferromagnetic transition in ultrathin CoO films, with unprecedented clarity. Its quasi-static operation is inherently compatible with external stimuli, including magnetic and electric fields, thereby expanding its utility for in-operando thermodynamic studies. This advancement establishes a robust and scalable platform for probing thermal phenomena in nanostructured and low-dimensional materials, significantly broadening the scope of nanocalorimetry.

cond-mat.mtrl-sci↗

arXiv2025

Magneto-Ionic Hardware Security Primitives: Embedding Data Protection at the Material Level

The Big Data revolution has heightened the demand for robust, energy-efficient security hardware capable of withstanding increasingly sophisticated cyber threats. Conventional encryption schemes, reliant on complex algorithms, are resource-intensive and remain vulnerable. To fortify sensitive information, society needs innovative anti-hacking and anti-counterfeiting technologies that exploit new materials and designs. Here, we present a magneto-ionic strategy for hardware-level security based on fully selective voltage-controlled N3- ion migration within pre-defined, initially paramagnetic FeCoN dots. This process generates ferromagnetic sublayers of tuneable thickness, resulting in either deterministic (single-domain or vortex) or probabilistic states (with coexisting magnetic configurations and voltage-adjustable probabilities), each exhibiting stochastic orientation and chirality, thereby providing a rich platform for magnetic fingerprinting. This approach enables self-protected primitives, including true random number generators, physical unclonable functions, and in-memory probabilistic inference. The resulting reconfigurable architecture combines tamper resistance, low energy consumption, and scalability, marking a significant leap toward next-generation hardware security rooted in emergent magnetic phenomena.

cs.CR↗

arXiv2025

Carbon magneto-ionics: Control of magnetism through voltage-driven carbon transport

Control of magnetism through voltage-driven ionic processes (i.e., magneto-ionics) holds potential for next-generation memories and computing. This stems from its non-volatility, flexibility in adjusting the magnitude and speed of magnetic modulation, and energy efficiency. Since magneto-ionics depends on factors like ionic radius and electronegativity, identifying alternative mobile ions is crucial to embrace new phenomena and applications. Here, the feasibility of C as a prospective magneto-ionic ion is investigated in a Fe-C system by electrolyte gating. In contrast to most magneto-ionic systems, Fe-C presents a dual-ion mechanism: Fe and C act as cation and anion, respectively, moving uniformly in opposite directions under an applied electric field. This leads to a 7-fold increase in saturation magnetization with magneto-ionic rates larger than 1 emu cm-3 s-1, and a 25-fold increase in coercivity. Since carbides exhibit minimal cytotoxicity, this introduces a biocompatible dimension to magneto-ionics, paving the way for the convergence of spintronics and biotechnology.

cond-mat.mtrl-sci↗

arXiv2025

Charge-transfer-mediated boron magneto-ionics: Towards voltage-driven multi-ion transport

Voltage control of magnetism via magneto-ionics, where ion transport and/or redox processes drive magnetic modulation, holds great promise for next-generation memories and computing. This stems from its non-volatility and ability to precisely tune both the magnitude and speed of magnetic properties in an energy-efficient manner. However, expanding magneto-ionics to incorporate novel mobile ions or even multiple ion species is crucial for unlocking new phenomena and enabling multifunctional capabilities. Here, we demonstrate voltage-driven multi-ion transport in a FeBO system with increasing oxygen content, progressively transitioning from an electrostatic-like response to a more pronounced electrochemical (magneto-ionic) behavior. The voltage-driven transport of both B and Fe is activated by oxidation state tuning, owing to the larger electronegativity of oxygen. Such charge-transfer effects allow multi-ion magneto-ionics, where O ions move oppositely to Fe and B ions. These results pave the way for programmable functionalities by leveraging elements with different electron affinities through charge-transfer engineering.

cond-mat.mtrl-sci↗

arXiv2024

Analog control of electrical conductivity in La0.5Sr0.5FeO3-{\delta} through oxygen deficiency induced magnetic transition

Switchability of materials properties by applying controlled stimuli such as voltage pulses is an emerging field of study with applicability in adaptive and programmable devices like neuromorphic transistors or non-emissive smart displays. One of the most exciting approaches to modulate materials performance is mobile ion/vacancy insertion for inducing changes in relevant electrical, optical, or magnetic properties, among others. Unveiling the interplay between changes in the concentration of mobile defects (like oxygen vacancies) and functional properties in relevant materials represents a step forward for underpinning the emerging oxide iontronics discipline. In this work, electrochemical oxide-ion pumping cells were fabricated for an analog control of the oxygen stoichiometry in thin films of mixed ionic-electronic conductor La0.5Sr0.5FeO3-{\delta}. We demonstrate over more than 4 orders of magnitude electronic conductivity control within the same crystallographic phase through the precise and continuous voltage control of the oxygen stoichiometry. We show that behind the modification of the transport properties of the material lays a paramagnetic-to-antiferromagnetic transition. We exploit such magnetoelectric coupling to show control over the exchange interaction between La0.5Sr0.5FeO3-{\delta} and a ferromagnetic Co layer deposited on top.

cond-mat.mtrl-sci↗

arXiv2024

Magneto-Ionic Vortices: Voltage-Reconfigurable Swirling-Spin Analog-Memory Nanomagnets

Rapid progress in information technologies has spurred the need for innovative memory concepts, for which advanced data-processing methods and tailor-made materials are required. Here we introduce a previously unexplored nanoscale magnetic object: an analog magnetic vortex controlled by electric-field-induced ion motion, termed magneto-ionic vortex or "vortion". This state arises from paramagnetic FeCoN through voltage gating and gradual N3-ion extraction within patterned nanodots. Unlike traditional vortex states, vortions offer comprehensive analog adjustment of key properties such as magnetization amplitude, nucleation/annihilation fields, or coercivity using voltage as an energy-efficient tuning knob. This manipulation occurs post-synthesis, obviating the need for energy-demanding methods like laser pulses or spin-torque currents. By leveraging an overlooked aspect of N3-magneto-ionics -- planar ion migration within nanodots -- precise control of the magnetic layer's thickness is achieved, which enables reversible transitions among paramagnetic, single-domain, and vortion states, offering future prospects for analog computing, multi-state data storage, or brain-inspired devices.

cond-mat.mtrl-sci↗

arXiv2024

Mechanical Properties of Minerals in Lunar and HED Meteorites from Nanoindentation Testing: Implications for Space Mining

This study analyzes the mechanical and elemental properties of lunar meteorites DHOFAR 1084, JAH 838, NWA 11444, and HED meteorite NWA 6013. Utilizing microscale rock mechanics experiments, i.e., nanoindentation testing, this research reveals significant heterogeneity in both mechanical and elemental attributes across the minerals of the samples. Olivines, pyroxen, feldspar, and spinel demonstrate similar compositional and mechanical characteristics. Conversely, other silicate and oxide minerals display variations in their mechanical properties. Terrestrial olivines subjected to nanoindentation tests exhibit increased hardness and a higher Young's modulus compared to their lunar counterparts. A linear correlation is observed between the H/Er ratio and both plastic and elastic energies. Additionally, the alignment of mineral phases along a constant H/Er ratio suggests variations in local porosity. This study also highlights the need for further research focusing on porosity, phase insertions within the matrix, and structural orientations to refine our understanding of these mechanical characteristics. The findings have direct implications for in-situ resource utilization (ISRU) strategies and future state-of-the-art impact models. This comprehensive characterization serves as a foundational resource for future research efforts in space science and mining.

cond-mat.mtrl-sci↗

arXiv2023

Wireless magneto-ionics: voltage control of magnetism by bipolar electrochemistry

Modulation of magnetic properties through voltage-driven ion motion and redox processes, i.e., magneto-ionics, is a unique approach to control magnetism with electric field for low-power memory and spintronic applications. So far, magneto-ionics has been achieved through direct electrical connections to the actuated material. Here we evidence that an alternative way to reach such control exists in a wireless manner. Induced polarization in the conducting material immersed in the electrolyte, without direct wire contact, promotes wireless bipolar electrochemistry, an alternative pathway to achieve voltage-driven control of magnetism based on the same electrochemical processes involved in direct-contact magneto-ionics. A significant tunability of magnetization is accomplished for cobalt nitride thin films, including transitions between paramagnetic and ferromagnetic states. Such effects can be either volatile or non-volatile depending on the electrochemical cell configuration. These results represent a fundamental breakthrough that may inspire future device designs for applications in bioelectronics, catalysis, neuromorphic computing, or wireless communications.

cond-mat.mtrl-sci↗

arXiv2020

Reversible and magnetically unassisted voltage-driven switching of magnetization in FeRh/PMN-PT

Reversible control of magnetization by electric fields without assistance from a subsidiary magnetic field or electric current could help reduce the power consumption in spintronic devices. When increasing temperature above room temperature, FeRh displays an uncommon antiferromagnetic to ferromagnetic phase transition linked to a unit cell volume expansion. Thus, using the strain exerted by an adjacent piezoelectric layer, the relative amount of antiferromagnetic and ferromagnetic regions can be tuned by an electric field applied to the piezoelectric material. Indeed, large variations in the saturation magnetization have been observed when straining FeRh films grown on suitable piezoelectric substrates. In view of its applications, the variations in the remanent magnetization rather than those of the saturation magnetization are the most relevant. Here, we show that in the absence of any bias external magnetic field, permanent and reversible magnetization changes as high as 34% can be induced by an electric field, which remain after this has been zeroed. Bulk and local magnetoelectric characterization reveals that the fundamental reason for the large magnetoelectric response observed at remanence is the expansion (rather than the nucleation) of ferromagnetic nanoregions.

cond-mat.mtrl-sci↗

arXiv2020

Nitrogen magneto-ionics

So far, magneto-ionics, understood as voltage-driven ion transport in magnetic materials, has largely relied on controlled migration of oxygen ion/vacancy and, to a lesser extent, lithium and hydrogen. Here, we demonstrate efficient, room-temperature, voltage-driven nitrogen transport (i.e., nitrogen magneto-ionics) by electrolyte-gating of a single CoN film (without an ion-reservoir layer). Nitrogen magneto-ionics in CoN is compared to oxygen magneto-ionics in Co3O4, both layers showing a nanocrystalline face-centered-cubic structure and reversible voltage-driven ON-OFF ferromagnetism. In contrast to oxygen, nitrogen transport occurs uniformly creating a plane-wave-like migration front, without assistance of diffusion channels. Nitrogen magneto-ionics requires lower threshold voltages and exhibits enhanced rates and cyclability. This is due to the lower activation energy for ion diffusion and the lower electronegativity of nitrogen compared to oxygen. These results are appealing for the use of magneto-ionics in nitride semiconductor devices, in applications requiring endurance and moderate speeds of operation, such as brain-inspired computing.

cond-mat.mtrl-sci↗

arXiv2020

Boosting room temperature magneto-ionics in Co3O4

Voltage control of magnetism through electric field-induced oxygen motion (magneto-ionics) could represent a significant breakthrough in the pursuit for new strategies to enhance energy efficiency in a large variety of magnetic devices, such as magnetic micro-electro-mechanical systems (MEMS), magnetic logics, spin electronics, or neuromorphic computing, i.e., envisaging ultra-low power emulation of the biological synapse. Boosting the induced changes in magnetization, magneto-ionic motion and cyclability (endurance) continue to be key challenges to turn magneto-ionic phenomena into real applications. Here, we demonstrate that, without degrading cyclability, room temperature magneto-ionic motion in electrolyte-gated paramagnetic and fairly thick (> 100 nm) Co3O4 films largely depends on the configuration used to apply the electric field. In particular, magneto-ionic effects are significantly increased both in terms of generated magnetization (6 times larger: from 118.5 to 699.2 emu cm-3) and speed (35 times faster: from 33.1 to 1170.8 emu cm-3 h-1) if the electric field is applied across a conducting buffer layer (grown underneath the Co3O4 films), instead of directly contacting Co3O4. This is attributed to a greater uniformity and strength of the applied electric field when using the conducting layer. These results may trigger the use of oxygen magneto-ionics into promising new technologies, such as magnetic MEMS or brain-inspired computing, which require endurance and moderate speeds of operation.

cond-mat.mtrl-sci↗

arXiv2018

Flexoelectric fracture-filter effect in ferroelectrics

The propagation front of a crack generates large strain gradients and it is therefore a strong source of gradient-induced polarization (flexoelectricity). Herein, we demonstrate that, in piezoelectric materials, a consequence of flexoelectricity is that crack propagation will be helped or hindered depending on whether it is parallel or antiparallel to the piezoelectric polar axis. This means that the theory of fracture physics can no longer assume mechanical symmetry in polar materials. The discovery of fracture asymmetry also has practical repercussions for the electromechanical fatigue of ferroelectrics and piezoelectric transducers, as well enabling a new degree of freedom for crack-based nanopatterning.

cond-mat.mtrl-sci↗

arXiv2016

Nanoindenting the Chelyabinsk meteorite to learn about impact deflection effects in asteroids

The Chelyabinsk meteorite is a highly shocked, low porosity, ordinary chondrite, probably similar to S- or Q-type asteroids. Therefore, nanoindentation experiments on this meteorite allow us to obtain key data to understand the physical properties of near-Earth asteroids. Tests at different length scales provide information about the local mechanical properties of the minerals forming this meteorite: reduced Young's modulus, hardness, elastic recovery, and fracture toughness. Those tests are also useful to understand the potential to deflect threatening asteroids using a kinetic projectile. We found that the differences in mechanical properties between regions of the meteorite, which increase or reduce the efficiency of impacts, are not a result of compositional differences. A low mean particle size, attributed to repetitive shock, can increase hardness, while low porosity promotes a higher momentum multiplication. Momentum multiplication is the ratio between the change in momentum of a target due to an impact, and the momentum of the projectile, and, therefore higher values imply more efficient impacts. In the Chelyabinsk meteorite, the properties of the light-colored lithology materials facilitate obtaining higher momentum multiplication values, compared to the other regions described for this meteorite. Also, we found a low value of fracture toughness in the shock-melt veins of Chelyabinsk, which would promote the ejection of material after an impact and, therefore, increase the momentum multiplication. These results are relevant considering the growing interest in missions to test asteroid deflection, such as the recent collaboration between the European Space Agency and NASA, known as the Asteroid Impact and Deflection Assessment mission.

astro-ph.EP↗

arXiv2015

High temperature magnetic stabilization of cobalt nanoparticles by an antiferromagnetic proximity effect

Thermal activation tends to destroy the magnetic stability of small magnetic nanoparticles, with crucial implications in ultra-high density recording among other applications. Here we demonstrate that low blocking temperature ferromagnetic (FM) Co nanoparticles (TB<70 K) become magnetically stable above 400 K when embedded in a high N\'eel temperature antiferromagnetic (AFM) NiO matrix. The origin of this remarkable TB enhancement is due to a magnetic proximity effect between a thin CoO shell (with low N\'eel temperature, TN; and high anisotropy, KAFM) surrounding the Co nanoparticles and the NiO matrix (with high TN but low KAFM). This proximity effect yields an effective AFM with an apparent TN beyond that of bulk CoO, and an enhanced anisotropy compared to NiO. In turn, the Co core FM moment is stabilized against thermal fluctuations via core-shell exchange-bias coupling, leading to the observed TB increase. Mean-field calculations provide a semi-quantitative understanding of this magnetic- proximity stabilization mechanism.

cond-mat.mes-hall↗

arXiv2015

New Reversal Mode in Exchange Coupled Antiferromagnetic/Ferromagnetic Disks: Distorted Viscous Vortex

Magnetic vortices have generated intense interest in recent years due to their unique reversal mechanisms, fascinating topological properties, and exciting potential applications. Additionally, the exchange coupling of magnetic vortices to antiferromagnets has also been shown to lead to a range of novel phenomena and functionalities. Here we report a new magnetization reversal mode of magnetic vortices in exchange coupled Ir20Mn80/Fe20Ni80 microdots: distorted viscous vortex reversal. Contrary to the previously known or proposed reversal modes, the vortex is distorted close to the interface and viscously dragged due to the uncompensated spins of a thin antiferromagnet, which leads to unexpected asymmetries in the annihilation and nucleation fields. These results provide a deeper understanding of the physics of exchange coupled vortices and may also have important implications for applications involving exchange coupled nanostructures.

cond-mat.mtrl-sci↗

arXiv2005

Magnetic relaxation of exchange biased (Pt/Co) multilayers studied by time-resolved Kerr microscopy

Magnetization relaxation of exchange biased (Pt/Co)5/Pt/IrMn multilayers with perpendicular anisotropy was investigated by time-resolved Kerr microscopy. Magnetization reversal occurs by nucleation and domain wall propagation for both descending and ascending applied fields, but a much larger nucleation density is observed for the descending branch, where the field is applied antiparallel to the exchange bias field direction. These results can be explained by taking into account the presence of local inhomogeneities of the exchange bias field.

cond-mat.other↗

arXiv2005

Magnetic relaxation measurements of exchange biased (Pt/Co) multilayers with perpendicular anisotropy

Magnetic relaxation measurements were carried out by magneto-optical Kerr effect on exchange biased (Pt/Co)5/Pt/FeMn multilayers with perpendicular anisotropy. In these films the coercivity and the exchange bias field vary with Pt spacer thickness, and have a maximum for 0.2 nm. Hysteresis loops do not reveal important differences between the reversal for ascending and descending fields. Relaxation measurements were fitted using Fatuzzo's model, which assumes that reversal occurs by domain nucleation and domain wall propagation. For 2 nm thick Pt spacer (no exchange bias) the reversal is dominated by domain wall propagation starting from a few nucleation centers. For 0.2 nm Pt spacer (maximum exchange bias) the reversal is strongly dominated by nucleation, and no differences between the behaviour of the ascending and descending branches can be observed. For 0.4 nm Pt spacer (weaker exchange bias) the nucleation density becomes less important, and the measurements reveal a much stronger density of nucleation centers in the descending branch.

cond-mat.other↗