P. James Joyce | Search arXiv

arXiv2026

PCFBench: A Diagnostic Benchmark for Product Carbon Footprint Estimation

AI systems are being deployed on high-stakes, domain-specific workflows that demand correctness not just in the final output, but at every intermediate step. One such workflow is estimating a product carbon footprint (PCF), the greenhouse-gas emissions attributable to a physical product. AI agents are increasingly being used to generate PCFs, but existing evaluations score either total emissions (hiding error sources and cancelling mistakes) or sub-tasks in isolation (missing compositional interactions). We introduce PCFBench, the first benchmark to carve PCF modeling into independently-evaluable tasks that require decomposition, retrieval, ontology matching, and numerical extraction. It comprises 614 expert-labelled items across six tasks. Together they probe reasoning under under-specification, conflicting context, and numerical constraints. Across eight frontier LLMs from four providers, no single model dominates. Although the strongest models estimate total product emissions within 2 times of declared totals on 77% of products, this rate drops to 37-58% when the PCF is generated step by step, with only 45-75% obeying mass conservation. These failures undermine the transparency practitioners need to compare products and drive decarbonization. We release the dataset and evaluation harness to support targeted progress.

cs.AI↗

arXiv2025

Criteria for Credible AI-assisted Carbon Footprinting Systems: The Cases of Mapping and Lifecycle Modeling

As organizations face increasing pressure to understand their corporate and products' carbon footprints, artificial intelligence (AI)-assisted calculation systems for footprinting are proliferating, but with widely varying levels of rigor and transparency. Standards and guidance have not kept pace with the technology; evaluation datasets are nascent; and statistical approaches to uncertainty analysis are not yet practical to apply to scaled systems. We present a set of criteria to validate AI-assisted systems that calculate greenhouse gas (GHG) emissions for products and materials. We implement a three-step approach: (1) Identification of needs and constraints, (2) Draft criteria development and (3) Refinements through pilots. The process identifies three use cases of AI applications: Case 1 focuses on AI-assisted mapping to existing datasets for corporate GHG accounting and product hotspotting, automating repetitive manual tasks while maintaining mapping quality. Case 2 addresses AI systems that generate complete product models for corporate decision-making, which require comprehensive validation of both component tasks and end-to-end performance. We discuss the outlook for Case 3 applications, systems that generate standards-compliant models. We find that credible AI systems can be built and that they should be validated using system-level evaluations rather than line-item review, with metrics such as benchmark performance, indications of data quality and uncertainty, and transparent documentation. This approach may be used as a foundation for practitioners, auditors, and standards bodies to evaluate AI-assisted environmental assessment tools. By establishing evaluation criteria that balance scalability with credibility requirements, our approach contributes to the field's efforts to develop appropriate standards for AI-assisted carbon footprinting systems.

cs.CY↗