Search arXiv⌕ Search

arXiv subjects

Qiunan Liu

Publications and source records attributed to Qiunan Liu.

2 recordsLinked to original sources

SLCA-GRPO: Resolving Cross-Segment Credit Misattribution in Tool-Calling RL

Tool-calling agents produce heterogeneous outputs, interleaving structured tool invocations with user-facing natural language summaries. This output heterogeneity presents a structural failure mode in standard on-policy Reinforcement Learning (RL): algorithms like GRPO indiscriminately broadcast a homogeneous trajectory-level scalar advantage to all tokens. Consequently, gradient noise from summary generation leaks into tool-decision tokens, causing cross-segment credit misattribution and brittle optimization. In this work, we propose SLCA-GRPO, a framework incorporating Segment-Locked Credit Assignment (SLCA). To enable scalable exploration without costly real APIs and stable training, we first construct the Schema-Guided LLM Simulator (SGLS) as foundational training infrastructure. Building on this, SLCA decouples advantage estimation at the structural segment level within a single group of rollouts, without requiring additional rollouts from intermediate states. Supported by Hierarchical Rewards (HierR), SLCA routes execution advantages to tool tokens and preference advantages to summary tokens, eliminating advantage contamination (the dominant cross-segment credit misattribution channel) within each policy update. On a 7B backbone, SLCA-GRPO accelerates convergence and outperforms standard GRPO, ToolPO, and RLTR by +2.53 pp on in-domain evaluation, +1.36 pp on the Berkeley Function-Calling Leaderboard (BFCL), and +9.15 pp on $τ^2$-Bench under the same training budgets, achieving higher accuracy with reduced tool redundancy and costs.

cs.AI↗

Defect migration and phase transformations in 2D iron chloride inside bilayer graphene

The intercalation of metal chlorides, and particularly iron chlorides, into graphitic carbon structures has recently received lots of attention, as it can not only protect this two-dimensional (2D) magnetic system from the effects of the environment, but also substantially alter the magnetic, electronic, and optical properties of both intercalant and host material. At the same time, the intercalation can result in the formation of structural defects, or defects can appear under external stimuli, which can affect materials performance. These aspects have received so far little attention in the dedicated experiments. In this study, we investigate the behavior of atomic-scale defects in iron chlorides intercalated into bilayer graphene (BLG) by using scanning transmission electron microscopy (STEM) and first-principles calculations. We observe transformations between the FeCl2 and FeCl3 phases and elucidate the role of defects in the transformations. Specifically, three types of defects are identified: Fe vacancies in FeCl2 domains, Fe adatoms and interstitials in FeCl3 domains, each exhibiting distinct dynamic behaviors. We also observed a crystalline phase with an unusual stoichiometry of Fe5Cl18 which has not been reported before. Our findings not only advance the understanding of intercalation mechanism of 2D materials but also highlight the profound impact of atomic-scale defects on their properties and potential technological applications.

cond-mat.mtrl-sci↗