Rajeev Gupta — Page 3

arXiv2000

An electron paramagnetic resonance study of Pr_{0.6}Ca_{0.4}MnO_{3} across the charge ordering transition

We report the first electron paramagnetic resonance studies of single crystals and powders of Pr_{0.6}Ca_{0.4}MnO_{3} in the 300-4.2 K range, covering the charge ordering transition at ~ 240 K and antiferromagnetic transition (T_N) at ~ 170 K. The asymmetry parameter for the Dysonian single crystal spectra shows anomalous increase at T_{co}. Below T_{co} the g-value increases continuously, suggesting a gradual strengthening of orbital ordering. The linewidth undergoes a sudden increase at T_{co} and continues to increase down to T_N. The intensity increases as the temperature is decreased till T_{co} due to the renormalization of magnetic susceptibility arising from the build up of ferromagnetic correlations. The value of the exchange constant, J, is estimated to be 154 K.

cond-mat.str-el↗

arXiv1996

Electronic Raman scattering and photoluminescence from La$_{0.7}$Sr$_{0.3}$MnO$_3$ exhibiting giant magnetoresistance

Raman and Photoluminescence (PL) experiments on correlated metallic La$_{0.7}$Sr$_{0.3}$MnO$_{3}$ have been carried out using different excitation wavelengths as a function of temperature from 15 K to 300 K. Our data suggest a Raman mode centered at 1800 cm$^{-1}$ and a PL band at 2.2 eV. The intensities of the two peaks decrease with increasing temperature. The Raman mode can be attributed to a plasmon excitation whose frequency and linewidths are consistent with the measured resistivities. The PL involves intersite electronic transitions of the manganese ions.

cond-mat↗