arXiv subjects

Sebastian Deffner

Publications and source records attributed to Sebastian Deffner.

At least 19 recordsLinked to original sources

arXiv2026

Ideal heat engine cycles at maximal efficiency -- the ideal gas and beyond

Given a particular heat engine cycle, what is the optimal working medium that results in the highest efficiency? While one might jump to the conclusion that it must surely be the ideal gas, the situation is actually more intricate. Starting with a general Helmholtz potential that depends polynomially on molar volume and temperature we derive exact expressions for the ideal Stirling, Otto, and Brayton cycles. We find that for the thermodynamic systems described by our ansatz for the Helmholtz potential the maximal efficiency is achieved, if the working medium is described by a fundamental relation linear in temperature. This includes the ideal gas, but also classical harmonic oscillators and phenomenological models of the rubber band.

cond-mat.stat-mech↗

arXiv2026

Procrastinating einselection in non-Markovian quantum dynamics

Among the processes governed by open-system and dissipative quantum dynamics, environment-induced superselection, or einselection, is particularly foundational, since it describes the formation of a preferred set of pointer states through environmental monitoring and ultimately the emergence of classicality. Especially in the context of Quantum Darwinism, einselection can be studied in terms of the motion of an observable towards its pointer value. To this end, we derive a quantum speed limit for observables for finite-dimensional systems governed by differentiable time-local open dynamics. We identify two mechanisms through which non-Markovianity can enhance observable speed: direct dissipative motion supported by population retention or revival, and indirect enhancement through restoration of the asymmetry available for coherent motion. For permanent einselection, this delays the emergence of the pointer basis due to accumulated negativity.

quant-ph↗

arXiv2026

Quantum annealers as programmable thermal machines

Programmable quantum annealers are used for optimization, probabilistic sampling, and simulation, but their performance is commonly reported without the energy exchanged during computation. Here we characterize the D-Wave quantum annealer as a closed thermodynamic cycle. From initial and final Ising energies and an effective temperature fitted to the output distribution, we obtain lower bounds on entropy production, environment energy exchange, work, and power. By varying the prepared distribution and the reverse annealing turning point, we map heater-, accelerator-, refrigerator-, and engine-compatible regimes in one dimensional chains and higher connectivity instances, and apply the same analysis to Advantage and Advantage2 hardware. For an encoded optimization problem, the measured processor energy change states whether final candidates improve or worsen the programmed objective on average. For sampling, the fitted temperature provides an operational measure of how strongly probability is concentrated among low energy configurations. The thermodynamic mode therefore adds information absent from solution quality or runtime alone: it distinguishes driven refinement, net heating, and heat pumping while quantifying their energetic consequences. This framework connects quantum optimization, probabilistic computing, statistical physics simulation, hardware diagnostics, and energy-aware assessment without assuming that a thermodynamic label alone determines computational performance.

quant-ph↗

arXiv2026

Information Processing in Quantum Thermodynamic Systems: an Autonomous Hamiltonian Approach

Extending the quantum formulation of [Phys. Rev. X 3, 041003 (2013)] to a more general setting for studying the thermodynamics of information processing including initial correlations, we generalize the second law of thermodynamics to account for information processing in such autonomous systems. We consider a composite quantum system consisting of a principal system, heat bath, memory, and work source, and adopt an autonomous Hamiltonian framework. We derive constraints on the total Hamiltonian that ensure the work source to act as a catalyst preserving its original randomness, namely that the total unitary evolution must have a unitary partial transpose. We show that this requirement is equivalent to the commutativity of operators acting on the joint system of the principal system, bath, and memory, which underlies the Hamiltonian structure. Next, we generalize the quantum speed limit for the joint dynamics of system and memory to the quantum thermodynamic speed limit, from which we obtain a dynamical version of Landauer's bound. More importantly, we also interpret this quantum thermodynamic speed limit in the context of quantum hypothesis testing.

quant-ph↗

arXiv2026

Procrustes Tomography -- reconstructing noisy quantum channels made easy

What is the most expensive part of quantum device characterization? Clearly, the answer is quantum process tomography. However, especially for noisy intermediate-scale quantum (NISQ) computers, a comprehensive understanding of the noisy quantum dynamics is essential in interpreting the computational output. In this work, we introduce an efficient method -- Procrustes tomography -- that outperforms established methods in a number of aspects. After a pedagogical and constructive introduction, we demonstrate the utility of the method for representative examples of noisy quantum channels.

quant-ph↗

arXiv2026

Fluctuation theorems for autonomous work

Classical fluctuation theorems for work have been obtained theoretically, and verified experimentally, within a non-autonomous framework in which work is performed on a system of interest, ${\cal S}$, by the external manipulation of a work parameter, such as a piston's position. Here we obtain fluctuation theorems within an autonomous framework in which ${\cal S}$ exchanges energy with a reversible work source, ${\cal R}$. The two subsystems, ${\cal R}$ and ${\cal S}$, interact with one another as they evolve under Hamiltonian or stochastic dynamics, without external intervention. In this setting, we must account for the back-action of ${\cal S}$ on ${\cal R}$, which is absent in the non-autonomous setting. We obtain autonomous versions of standard fluctuation theorems for work and entropy production. In each case, we argue, the autonomous fluctuation theorem reduces to its non-autonomous counterpart when ${\cal R}$'s inertia becomes infinitely large.

cond-mat.stat-mech↗

arXiv2026

Energy-error tradeoff in encoding quantum error correction

While it has been widely recognized that genuine quantum advantage for practical problems might only be achieved with fault-tolerant quantum computers, it is still not entirely clear whether the required quantum error correction will be physically feasible. In the present work, we carefully analyze the required energy resources to encode the logical qubit states for repetition, perfect, and Steane codes. We find that there is a universal trade-off between the target precision and the required energetic resources. Importantly, we find that the energetic resources intimately depend on the specific physical realization of a quantum error correction code, and that the required resources scale exponentially with the targeted precision of the encoding.

quant-ph↗

arXiv2026

Over forty years of research towards the understanding of Quantum Brownian Motion -- the contributions of A. O. Caldeira

This article presents a brief account of Amir O. Caldeira's contributions to the theory of quantum Brownian motion. Motivated by its importance, we outline the description of Brownian motion in the quantum regime following Caldeira's first works. In this context, we particularly highlight the effect of dissipation on the tunneling rate out of a metastable state. We then journey along the alternative ways to approach quantum Brownian motion developed by Caldeira during his career, which go beyond the so-called Caldeira-Leggett model. We conclude by summarizing some of Caldeira's contributions to contemporary fields such as the theory of quantum decoherence and quantum thermodynamics, that were strongly inspired by his eponymous approach to quantum Brownian motion.

quant-ph↗

arXiv2026

Quantum speed limit for measurement probabilities

Any protocol to process quantum information has to conclude with a measurement, aimed at producing a specific set of probabilities of measurement outcomes. In this work, we investigate the time, energy and importantly the genuine quantum resources necessary for transforming a set of measurement probabilities generated by a positive-operator-valued measure (POVM), to a target set of measurement probabilities. To this end, we first show that the speed of measurement probabilities, defined as the average rate of the surprisal of measurement outcomes, is constrained by the genuine quantum fluctuations contained in the measurement probabilities. Interestingly, this quantum speed limit can act as a witness for bipartite quantum correlations by selecting an optimal local projective measurement. Furthermore, we obtain a minimum time to transform an initial measurement probabilities to a target measurement probabilities, and apply this result to analyzing the cost of generating a local athermality in terms of genuine quantum uncertainty.

quant-ph↗

arXiv2026

Quantum speed limit for observables from quantum asymmetry

Quantum asymmetry and coherence are genuinely quantum resources that are essential to realize quantum advantage in information technologies. However, all quantum processes are fundamentally constrained by quantum speed limits, which raises the question on the corresponding bounds on the rate of consumption of asymmetry and coherence. In the present work, we derive a formulation of the quantum speed limit for observables in terms of the trace-norm asymmetry of the time-dependent quantum state relative to the observable. This quantum speed limit can be directly observed in experiment through weak value measurement and provides a lower bound to the quantum Fisher information about the parameter conjugate to the observable. It can be further related to quantum coherence relative to the eigenbasis of the observable. We obtain a complementary relation for the speed of three mutually unbiased observables for a single qubit. As an application, we derive a notion of a quantum thermodynamic speed limit.

quant-ph↗

arXiv2026

Quantum timekeeping and the dynamics of scrambling in critical systems

In this work, we develop a quantum metrological framework for quantum chaos by showing that local subsystems of information scrambling systems naturally function as quantum stopwatches. The reduced quantum state of a subsystem encodes the passage of time through its growing distinguishability from the initial preparation. Treating time as the estimation parameter, we then derive a generalized quantum Cramer-Rao bound that directly relates the precision of time estimation to the decay of out-of-time ordered correlators (OTOCs) and subsystem quantum Fisher information (QFI). As a main result, we obtain continuity bounds for quantum Lyapunov exponent in terms of the subsystem QFI in quantumly chaotic dynamics. Furthermore, using a scaling analysis based on imaginary-time correlators, we show that the subsystem QFI exhibits universal critical amplification near quantum phase transitions. Our results are demonstrated and verified by a numerical analysis of the dynamics of a chaotic Ising chain.

quant-ph↗

arXiv2026

Variational Gibbs State Preparation on Trapped-Ion Devices

We implement a variational quantum algorithm for Gibbs state preparation of a transverse-field Ising model on IonQ's quantum computers. To this end, we train the variational parameters via classical simulation and perform state tomography on the quantum devices to evaluate the fidelity of the prepared Gibbs state. As a main result, we find that fidelity decreases (non-monotonically) as a function of the inverse temperature $β$ of the system. Fidelity also decreases as a function of the size of the system. Interestingly, we find that a Gibbs state prepared for a specified $β$ is a better representative of a Gibbs state prepared for a $\textit{lower}$ $β$; or in other words, thermal fluctuations in the quantum hardware lead to digital heating, that is, an increase in the temperature of the prepared Gibbs state above what was intended.

quant-ph↗

arXiv2026

Metrological approach to the emergence of classical objectivity

We present a precise characterization of the onset of classicality that combines the formalism of quantum Darwinism with the tools from quantum metrology. We show that the quantum Fisher information provides a useful metric for assessing the rate at which classical objectivity emerges. Furthermore, our formalism allows us to explore how the choice of measurement impacts the precision with which an observer can determine the state of the system. For a paradigmatic example of the spin-star model, we demonstrate that optimal measurements lead to the emergence of classicality at an exponential rate. Although other measurements necessarily lead to slower emergence, we importantly show that suboptimal measurements can still saturate the Cramér-Rao bound. By recasting emergent classicality as an information acquisition protocol, our framework provides a precise operational description of quantum Darwinism.

quant-ph↗

arXiv2026

Roadmap on Quantum Thermodynamics

The last two decades has seen quantum thermodynamics become a well established field of research in its own right. In that time, it has demonstrated a remarkably broad applicability, ranging from providing foundational advances in the understanding of how thermodynamic principles apply at the nano-scale and in the presence of quantum coherence, to providing a guiding framework for the development of efficient quantum devices. Exquisite levels of control have allowed state-of-the-art experimental platforms to explore energetics and thermodynamics at the smallest scales which has in turn helped to drive theoretical advances. This Roadmap provides an overview of the recent developments across many of the field's sub-disciplines, assessing the key challenges and future prospects, providing a guide for its near term progress.

quant-ph↗

arXiv2026

From compatibility of measurements to exploring Quantum Darwinism on NISQ

Quantum Darwinism explains how tenets of classical reality, such as objectivity and repeatability, emerge within a quantum universe. As a mathematical framework, Quantum Darwinism also provides guiding principles that determine what physical models support emergent classical behavior, what specific observables obey classical laws, and much more. For instance, in a recent work we elucidated that the limit under which Kirkwood-Dirac quasiprobability distributions become effectively classical coincides with the regime where the underlying physical model obeys the rules of Quantum Darwinism. In the present work, we study the breaking of Quantum Darwinism in a specific model and how that translates to non-classical measurement statistics. Interestingly, this provides effective tools for benchmarking the genuine quantum characteristics of NISQ hardware, which we demonstrate with IonQ's trapped-ion and IBM's superconducting quantum computing platforms.

quant-ph↗

arXiv2026

Thermodynamic significance of QUBO encoding on quantum annealers

Quadratic unconstrained binary optimization (QUBO) is the standard interface to quantum annealers, yet a single constrained task admits many QUBO encodings whose penalty choices reshape the energy landscape experienced by hardware. We study a Job Shop Scheduling instance using a two-parameter family of encodings controlled by penalty weights $p_{\rm sum}$ (one-hot/sum constraints) and $p_{\rm pair}$ (precedence constraints). Sweeping $(p_{\rm sum},p_{\rm pair})$, we observe sharp transitions in feasibility and solver success across classical annealing-inspired heuristics and on a D-Wave Advantage processor. Going beyond solution probability, we treat the annealer as an open thermodynamic system and perform cyclic reverse-annealing experiments initialized from thermal samples, measuring the stochastic processor energy change. From the first two moments of this energy change we infer lower bounds on entropy production, work, and exchanged heat via thermodynamic uncertainty relations, and corroborate the observed trends with adiabatic master equation simulations. We find that the same encoding transitions that govern computational hardness also reorganize dissipation: weak penalties generate low-energy infeasible manifolds, while overly strong penalties suppress the effective problem energy scale and increase irreversibility, reducing the thermodynamic efficiency. Our results establish QUBO penalties as thermodynamic control knobs and motivate thermodynamics-aware encoding strategies for noisy intermediate-scale quantum annealers.

quant-ph↗

arXiv2025

Correcting noisy quantum gates with shortcuts to adiabaticity

Unitary quantum gates constitute the building blocks of Quantum Computing in the circuit paradigm. In this work, we engineer a locally driven two-qubit Hamiltonian whose instantaneous ground-state dynamics generates the controlled-NOT (CNOT) quantum gate. In practice, quantum gates have to be implemented in finite-time, hence non-adiabatic and external noise effects debilitate gate fidelities. Here, we show that counterdiabatic control can restore gate performance with near perfect fidelities even in open quantum systems subject to decoherence.

quant-ph↗

arXiv2025

Demon with dementia - the deterioration of information transcription

In introductory biology, aging is typically explained as a result of mutations during the DNA replication process within cells. Upon abstraction, we recognize that cellular aging can be understood as the gradual decay in fidelity of information transcription. Since cellular processes are microscopic and inherently stochastic, the abstracted process of information transcription can be understood using Markovian dynamics. In our work, we model the process of information transcription with an autonomous Maxwell's demon (AMD) which interacts with two bitstreams, a lifted mass, and a heat reservoir. As main results, we analyze the steady-state properties of the system with both time-independent and time-dependent transition rates, focusing on the statistics of extractable work, bit transcription fidelity, and two-bit mutual information. Together, these results provide a holistic view of a simplified model for DNA transcription as an information-theoretic process.

cond-mat.stat-mech↗