arXiv subjects

Xinting Yu

Publications and source records attributed to Xinting Yu.

At least 19 recordsLinked to original sources

arXiv2026

A Cross-Laboratory Comparison Study of Titan Haze Analogs: Surface Energy II

The organic haze particles on Titan play important roles in atmospheric cloud formation and aerosol-lake interactions. These processes are strongly influenced by the surface energy of the haze particles, which controls cohesion and wetting behavior. This study presents a comparative analysis of 32 laboratory-produced haze analog samples ("tholins") synthesized across three laboratories. Using contact angle measurements, we determine the total surface energy and its dispersive and polar components for all samples, systematically evaluating the effects of substrate choice, air exposure, initial N2/CH4 gas mixture, and experimental setup. We find that tholin samples exhibit minimal substrate dependence, whereas exposure to ambient air substantially modifies the surface chemistry, altering the balance between dispersive and polar components. Thus, future Titan-relevant surface property measurements may use any substrate but must keep samples pristine. Surface energies vary weakly across methane concentrations, from 1-10% CH4 in N2, indicating that Titan's hazes formed at different altitudes should exhibit broadly similar cohesiveness. In contrast, experimental conditions such as gas exposure time and energy source produce the dominant differences in surface energy, driven largely by variations in polar components. Despite these differences, tholin samples exhibit high dispersive components, implying that Titan's hazes should act as efficient cloud condensation nuclei for hydrocarbon clouds and should generally sink into Titan's lakes. Given observed ethane ice clouds, we conclude that cold plasma tholins may be better physical analogs for Titan's hazes than samples produced with far-ultraviolet irradiation, though intrinsic surface energies of UV tholins remain uncertain due to film thickness limitations.

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arXiv2026

Feeling the Pressure: Effects of Formation Pressure on the Physical Properties of Titan Haze Analogs

The Cassini-Huygens mission detected large negative ions in Titan's ionosphere at pressures as low as $10^{-6}$ torr. These ions ultimately polymerize to form Titan's complex organic haze particles, which are observed throughout the atmosphere and potentially on the surface. Laboratory analogs of these hazes, known as tholins, have been used to study Titan's aerosols; however, most are produced at much higher pressures. The influence of formation pressures on key physical properties -- such as particle size, density, surface energy, and mechanical strength -- remains poorly constrained. These properties govern the haze's aggregation efficiency, radiative behavior, and surface-atmosphere interactions, shaping Titan's climate and surface. To investigate the effects of formation pressure, we generate tholins using a newly developed cold plasma discharge system. A 95% nitrogen and 5% methane gas mixture is exposed to plasma at two pressures, 1 torr and 0.125 torr. For both samples, we measure the production rate, particle size, morphology, density, surface free energy, Young's modulus, and nanoindentation hardness. While particle size, morphology, surface energy, and Young's modulus are similar across both pressures, tholins produced at lower pressure exhibited a threefold lower production rate, but a higher density and nanoindentation hardness. These variations likely reflect pressure-dependent changes in chemical structure, porosity, and mechanical strength. Because Titan's hazes form at much lower pressures than investigated here, actual haze particles are potentially even denser and mechanically stronger than our analogs, with implications for aerosol aggregation, aeolian and fluvial transport, and surface modification on Titan.

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arXiv2026

Unusually Hot Interiors Could Reconcile the Missing Methane Problem for Warm-to-Hot Exoplanets with Hydrogen Atmospheres

JWST is revolutionizing the field of exoplanet atmospheres by delivering unprecedented spectroscopic constraints on their chemical compositions. It has provided tight constraints on the abundances of dominant carbon- and oxygen-bearing species on numerous warm-to-hot exoplanets with hydrogen-dominated atmospheres. Under thermochemical equilibrium, many of these exoplanets should have abundant methane (CH4); however, CH4 has, so far, only been spotted in a few cases. Here, we present a simple, geochemistry-inspired framework to explore whether elevated intrinsic temperatures (T$\rm_{int}$) can account for the CH4 depletions. Instead of using computationally expensive, forward grid models, our fast analytical framework focuses on two key chemical equilibria: CO-CH4 and CO-CO2, allowing us to quickly constrain the minimum Tint that is consistent with JWST-observed abundances of H2O, CO, CH4, and CO2. Applying this framework to 12 warm-to-hot exoplanets, we find that several targets require minimum Tint values exceeding those predicted by standard evolution models, while others remain consistent with lower Tint solutions or exhibit degeneracies with other solutions. Our sample enables an initial exploration of population-level trends: while many exoplanets broadly follow an empirical Teq-Tint relation derived from the hot Jupiter mass-radius population, a subset of targets lie well above this trend. The apparent need for hotter interiors suggests that while Ohmic dissipation is probably an important heat source among the general population, additional heating processes, such as tidal heating, may also play important roles for some planets. Our results demonstrate the diagnostic power of atmospheric chemistry as a complementary probe of exoplanet interiors.

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arXiv2025

Deciphering Sub-Neptune Atmospheres: New Insights from Geochemical Models of TOI-270 d

The nature of sub-Neptunes is one of the hottest topics in exoplanetary science. Temperate sub-Neptunes are of special interest because some could be habitable. Here, we consider whether these planets might instead be rocky worlds with thick, hot atmospheres. Can recent JWST observations of TOI-270 d be understood in terms of such a model? We perform thermochemical equilibrium calculations to infer conditions of quenching of C-H-O-N species. Our results indicate apparent CO$_2$-CH$_4$ equilibrium between ~900 and ~1100 K. The CO abundance should be quenched higher in the atmosphere where the equilibrium CO/CO$_2$ ratio is lower, potentially explaining a lack of CO. N$_2$ is predicted to dominate the nitrogen budget. We confirm that the atmosphere of TOI-270 d is strongly enriched in both C and O$_g$$_a$$_s$ relative to protosolar H, whereas N is likely to be less enriched or even depleted. We attempt to reproduce these enrichments by modeling the atmosphere as nebular gas that extracted heavy elements from accreted solids. This type of model can explain the C/H and O$_g$$_a$$_s$/H ratios, but despite supersolar C/N ratios provided by solids, the NH$_3$ abundance will probably be too high unless there is a nitrogen sink in addition to N$_2$. A magma ocean may be implied, and indeed the oxygen fugacity of the deep atmosphere seems sufficiently low to support the sequestration of reduced N in silicate melt. The evaluation presented here demonstrates that exoplanetary geochemistry now approaches a level of sophistication comparable to that achieved within our own solar system.

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arXiv2024

Volatile-rich Sub-Neptunes as Hydrothermal Worlds: The Case of K2-18 b

Temperate exoplanets between the sizes of Earth and Neptune, known as "sub-Neptunes", have emerged as intriguing targets for astrobiology. It is unknown whether these planets resemble Earth-like terrestrial worlds with a habitable surface, Neptune-like giant planets with deep atmospheres and no habitable surface, or something exotic in between. Recent JWST transmission spectroscopy observations of the canonical sub-Neptune, K2-18 b, revealed ~1% CH4, ~1% CO2, and a non-detection of CO in the atmosphere. While previous studies proposed that the observed atmospheric composition could help constrain the lower atmosphere's conditions and determine the interior structure of sub-Neptunes like K2-18 b, the possible interactions between the atmosphere and a hot, supercritical water ocean at its base remain unexplored. In this work, we investigate whether a global supercritical water ocean, resembling a planetary-scale hydrothermal system, can explain these observations on K2-18 b-like sub-Neptunes through equilibrium aqueous geochemical calculations. We find that the observed atmospheric CH4/CO2 ratio implies a minimum ocean temperature of ~710 K, whereas the corresponding CO/CO2 ratio allows ocean temperatures up to ~1070 K. These results indicate that a global supercritical water ocean on K2-18 b is plausible. While life cannot survive in such an ocean, this work represents the first step towards understanding how a global supercritical water ocean may influence observable atmospheric characteristics on volatile-rich sub-Neptunes. Future observations with better constrained CO and NH$_3$ mixing ratios could further help distinguish between possible interior compositions of K2-18 b.

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arXiv2024

Probing Cold-to-Temperate Exoplanetary Atmospheres: The Role of Water Condensation on Surface Identification with JWST

Understanding the surface temperature and interior structure of cold-to-temperate sub-Neptunes is critical for assessing their habitability, yet direct observations are challenging. In this study, we investigate the impact of water condensation on the atmospheric compositions of sub-Neptunes, focusing on the implications for JWST spectroscopic observations. By modeling the atmospheric photochemistry of two canonical sub-Neptunes, K2-18 b and LHS 1140 b, both with and without water condensation and with and without thick atmospheres, we demonstrate that water condensation can significantly affect the predicted atmospheric compositions. This effect is driven by oxygen depletion from the condensation of water vapor and primarily manifests as an increase in the C/O ratio within the photochemically active regions of the atmosphere. This change in composition particularly affects planets with thin H2-dominated atmospheres, leading to a transition in dominant nitrogen and carbon carriers from N2 and oxygen-rich species like CO/CO2 towards heavier hydrocarbons and nitriles. While our models do not fully account for the loss mechanisms of these higher-order species, such molecules can go on to form more refractory molecules or hazes. Planets with thin H2-rich atmospheres undergoing significant water condensation are thus likely to exhibit very hazy atmospheres. The relatively flat JWST spectra observed for LHS 1140 b could be consistent with such a scenario, suggesting a shallow surface with extensive water condensation or a high atmospheric C/O ratio. Conversely, the JWST observations of K2-18 b are better aligned with a volatile-rich mini-Neptune with a thick atmosphere.

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arXiv2024

The Fate of Simple Organics on Titan's Surface: A Theoretical Perspective

Atmospheric photochemistry on Titan continuously transforms methane and nitrogen gases into various organic compounds. This study explores the fate of these molecules when they land on Titan's surface. Our analytical exploration reveals that most simple organics found in Titan's atmosphere, including all nitriles, triple-bonded hydrocarbons, and benzene, land as solids. Only a few compounds are in the liquid phase, while only ethylene remains gaseous. For the simple organics that land as solids, we further examine their interactions with Titan's lake liquids. Utilizing principles of buoyancy, we found that flotation can be achieved via porosity-induced (25-60% porosity) or capillary force-induced buoyancy for HCN ices on ethane-rich lakes. Otherwise, these ices would sink and become lakebed sediments. By evaluating the timescale of flotation, our findings suggest that porosity-induced flotation of millimeter-sized and larger sediments is the only plausible mechanism for floating solids to explain the transient "magic islands" phenomena on Titan's lakes.

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arXiv2022

Material Properties of Organic Liquids, Ices, and Hazes on Titan

Titan has a diverse range of materials in its atmosphere and on its surface: the simple organics that reside in various phases (gas, liquid, ice) and the solid complex refractory organics that form Titan's haze layers. These materials all actively participate in various physical processes on Titan, and many material properties are found to be important in shaping these processes. Future in-situ exploration on Titan would likely encounter a range of materials, and a comprehensive database to archive the material properties of all possible material candidates will be needed. Here we summarize several important material properties of the organic liquids, ices, and the refractory hazes on Titan that are available in the literature and/or that we have computed. These properties include thermodynamic properties (phase change points, sublimation and vaporization saturation vapor pressure, and latent heat), physical property (density), and surface properties (liquid surface tensions and solid surface energies). We have developed a new database to provide a repository for these data and make them available to the science community. These data can be used as inputs for various theoretical models to interpret current and future remote sensing and in-situ atmospheric and surface measurements on Titan. The material properties of the simple organics may also be applicable to giant planets and icy bodies in the outer solar system, interstellar medium, protoplanetary disks, and exoplanets.

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arXiv2022

Microphysics of Water Clouds in the Atmospheres of Y Dwarfs and Temperate Giant Planets

Water clouds are expected to form on Y dwarfs and giant planets with equilibrium temperatures near or below that of Earth, drastically altering their atmospheric compositions and their albedos and thermal emission spectra. Here we use the 1D Community Aerosol and Radiation Model for Atmospheres (CARMA) to investigate the microphysics of water clouds on cool substellar worlds to constrain their typical particle sizes and vertical extent, taking into consideration nucleation and condensation, which have not been considered in detail for water clouds in H/He atmospheres. We compute a small grid of Y dwarf and temperate giant exoplanet atmosphere models with water clouds forming through homogeneous nucleation and heterogeneous nucleation on cloud condensation nuclei composed of meteoritic dust, organic photochemical hazes, and upwelled potassium chloride cloud particles. We present comparisons with the Ackerman & Marley parameterization of cloud physics to extract the optimal sedimentation efficiency parameter (f$_{sed}$) using Virga. We find that no Virga model replicates the CARMA water clouds exactly and that a transition in f$_{sed}$ occurs from the base of the cloud to the cloud top. Furthermore, we generate simulated thermal emission and geometric albedo spectra and find large, wavelength-dependent differences between the CARMA and Virga models, with different gas absorption bands reacting differently to the different cloud distributions and particularly large differences in the M band. Therefore, constraining the vertically-dependent properties of water clouds will be essential to estimating the gas abundances in these atmospheres.

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arXiv2021

Cleaning our Hazy Lens: Exploring Trends in Transmission Spectra of Warm Exoplanets

Relatively little is understood about the atmospheric composition of temperate to warm exoplanets (equilibrium temperature $T_{\rm eq}<$ 1000 K), as many of them are found to have uncharacteristically flat transmission spectra. Their flattened spectra are likely due to atmospheric opacity sources such as planet-wide photochemical hazes and condensation clouds. We compile the transmission spectra of 25 warm exoplanets previously observed by the Hubble Space Telescope and quantify the haziness of each exoplanet using a normalized amplitude of the water absorption feature ($A_{\rm H}$). By examining the relationships between $A_{\rm H}$ and various planetary and stellar forcing parameters, we endeavor to find correlations of haziness associated with planetary properties. We adopt new statistical correlation tests that are more suitable for the small, non-normally distributed warm exoplanet sample. Our analysis shows that none of the parameters hold statistically significant correlation with $A_{\rm H}$ ($p \le 0.01$) with the addition of new exoplanet data, including the previously identified linear trends between $A_{\rm H}$ and $T_{\rm{eq}}$ or hydrogen-helium envelope mass fraction (f$_{\rm{HHe}}$). This suggests that haziness in warm exoplanets is not simply controlled by any single planetary/stellar parameter. Among all the parameters we investigated, planet gravity ($g_{\rm p}$), atmospheric scale height ($H$), planet density ($\rho_{\rm p}$), orbital eccentricity ($e$), and age of the star ($t_{\rm age}$) hold tentative correlations with $A_{\rm H}$. Specifically, lower $H$, higher $g_{\rm p}$, $\rho_{\rm p}$, $e$, or $t_{\rm age}$ may lead to clearer atmospheres. We still need more observations and laboratory experiments to fully understand the complex physics and chemistry involved in creating hazy warm exoplanets.

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arXiv2021

A Cross-Laboratory Comparison Study of Titan Haze Analogs: Surface Energy

In Titan's nitrogen-methane atmosphere, photochemistry leads to the production of complex organic particles, forming Titan's thick haze layers. Laboratory-produced aerosol analogs, or "tholins", are produced in a number of laboratories; however, most previous studies have investigated analogs produced by only one laboratory rather than a systematic, comparative analysis. In this study, we performed a comparative study of an important material property, the surface energy, of seven tholin samples produced in three independent laboratories under a broad range of experimental conditions, and explored their commonalities and differences. All seven tholin samples are found to have high surface energies, and are therefore highly cohesive. Thus, if the surface sediments on Titan are similar to tholins, future missions such as Dragonfly will likely encounter sticky sediments. We also identified a commonality between all the tholin samples: a high dispersive (non-polar) surface energy component of at least 30 mJ/m2. This common property could be shared by the actual haze particles on Titan as well. Given that the most abundant species interacting with the haze on Titan (methane, ethane, and nitrogen) are non-polar in nature, the dispersive surface energy component of the haze particles could be a determinant factor in condensate-haze and haze-lake liquids interactions on Titan. With this common trait of tholin samples, we confirmed the findings of a previous study by Yu et al. (2020) that haze particles are likely good cloud condensation nuclei (CCN) for methane and ethane clouds and would likely be completely wetted by the hydrocarbon lakes on Titan.

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arXiv2021

Haze Evolution in Temperate Exoplanet Atmospheres Through Surface Energy Measurements

Photochemical hazes are important opacity sources in temperate exoplanet atmospheres, hindering current observations from characterizing exoplanet atmospheric compositions. The haziness of an atmosphere is determined by the balance between haze production and removal. However, the material-dependent removal physics of the haze particles is currently unknown under exoplanetary conditions. Here we provide experimentally-measured surface energies for a grid of temperate exoplanet hazes to characterize haze removal in exoplanetary atmospheres. We found large variations of surface energies for hazes produced under different energy sources, atmospheric compositions, and temperatures. The surface energies of the hazes were found to be the lowest around 400 K for the cold plasma samples, leading to the lowest removal rates. We show a suggestive correlation between haze surface energy and atmospheric haziness with planetary equilibrium temperature. We hypothesize that habitable zone exoplanets could be less hazy, as they would possess high-surface-energy hazes which can be removed efficiently.

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arXiv2021

How to identify exoplanet surfaces using atmospheric trace species in hydrogen-dominated atmospheres

Sub-Neptunes (Rp~1.25-4 REarth) remain the most commonly detected exoplanets to date. However, it remains difficult for observations to tell whether these intermediate-sized exoplanets have surfaces and where their surfaces are located. Here we propose that the abundances of trace species in the visible atmospheres of these sub-Neptunes can be used as proxies for determining the existence of surfaces and approximate surface conditions. As an example, we used a state-of-the-art photochemical model to simulate the atmospheric evolution of K2-18b and investigate its final steady-state composition with surfaces located at different pressures levels (Psurf). We find the surface location has a significant impact on the atmospheric abundances of trace species, making them deviate significantly from their thermochemical equilibrium and "no-surface" conditions. This result arises primarily because the pressure-temperature conditions at the surface determine whether photochemically-produced species can be recycled back to their favored thermochemical-equilibrium forms and transported back to the upper atmosphere. For an assumed H2-rich atmosphere for K2-18b, we identify seven chemical species that are most sensitive to the existence of surfaces: ammonia (NH3), methane (CH4), hydrogen cyanide (HCN), acetylene (C2H2), ethane (C2H6), carbon monoxide (CO), and carbon dioxide (CO2). The ratio between the observed and the no-surface abundances of these species, can help distinguish the existence of a shallow surface (Psurf < 10 bar), an intermediate surface (10 bar < Psurf < 100 bar), and a deep surface (Psurf > 100 bar). This framework can be applied together with future observations to other sub-Neptunes of interest.

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arXiv2020

Surface Energy of the Titan Aerosol Analog "Tholin"

The photochemical haze produced in the upper atmosphere of Titan plays a key role in various atmospheric and surface processes on Titan. The surface energy, one important physical properties of the haze, is crucial for understanding the growth of the haze particles and can be used to predict their wetting behavior with solid and liquid species on Titan. We produced Titan analog haze materials, so-called "tholin", with different energy sources and measured their surface energies through contact angle and direct force measurements. From the contact angle measurement, we found that the tholins produced by cold plasma and UV irradiation have total surface energy around 60-70 mJ/m2. The direct force measurement yields a total surface energy of ~66 mJ/m2 for plasma tholin. The surface energy of tholin is relatively high compared to common polymers, indicating its high cohesiveness. Therefore, the Titan haze particles would likely coagulate easily to form bigger particles, while the haze-derived surface sand particles would need higher wind speed to be mobilized because of the high interparticle cohesion. The high surface energy of tholins also makes them easily wettable by Titan's atmospheric hydrocarbon condensates and surface liquids. Thus, the hazes particles are likely good cloud condensation nuclei (CCN) for hydrocarbon clouds (methane and ethane) to nucleate and grow. And if the hazes particles are denser compared to the lake liquids, they would likely sink into the lakes instead of forming a floating film to dampen the lake surface waves.

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arXiv2020

Haze Formation in Warm H2-rich Exoplanet Atmospheres

New observing capabilities coming online over the next few years will provide opportunities for characterization of exoplanet atmospheres. However, clouds/hazes could be present in the atmospheres of many exoplanets, muting the amplitude of spectral features. We use laboratory simulations to explore photochemical haze formation in H2-rich exoplanet atmospheres at 800 K with metallicity either 100 and 1000 times solar. We find that haze particles are produced in both simulated atmospheres with small particle size (20 to 140 nm) and relative low production rate (2.4 x 10-5 to 9.7 x 10-5 mg cm-3 h-1), but the particle size and production rate is dependent on the initial gas mixtures and the energy sources used in the simulation experiments. The gas phase mass spectra show that complex chemical processes happen in these atmospheres and generate new gas products that can further react to form larger molecules and solid haze particles. Two H2-rich atmospheres with similar C/O ratios (~0.5) yield different haze particles size, haze production rate, and gas products, suggesting both the elemental abundances and their bonding environments in an atmosphere can significantly affect the photochemistry. There is no methane (CH4) in our initial gas mixtures, although CH4 is often believed to be required to generate organic hazes. However, haze production rates from our experiments with different initial gas mixtures indicate that CH4 is neither required to generate organic hazes nor necessary to promote the organic haze formation. The variety and relative yield of the gas products indicate that CO and N2 enrich chemical reactions in H2-rich atmospheres.

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arXiv2020

Sulfur-driven Haze Formation in Warm CO2-rich Exoplanet Atmospheres

Sulfur gases significantly affect the photochemistry of planetary atmospheres in our Solar System, and are expected to be important components in exoplanet atmospheres. However, sulfur photochemistry in the context of exoplanets is poorly understood due to a lack of chemical-kinetics information for sulfur species under relevant conditions. Here, we study the photochemical role of hydrogen sulfide (H2S) in warm CO2-rich exoplanet atmospheres (800 K) by carrying out laboratory simulations. We find that H2S plays a significant role in photochemistry, even when present in the atmosphere at relatively low concentrations (1.6%). It participates in both gas and solid phase chemistry, leading to the formation of other sulfur gas products (CH3SH/SO, C2H4S/OCS, SO2/S2, and CS2) and to an increase in solid haze particle production and compositional complexity. Our study shows that we may expect thicker haze with small particle sizes (20 to 140 nm) for warm CO2-rich exoplanet atmospheres that possess H2S.

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arXiv2019

Single particle triboelectrification of Titan sand analogs

Sand electrification is important for aeolian sediment transportation on terrestrial bodies with silicate sand as the main sediment composition. However, it has not been thoroughly studied for icy bodies such as Titan with organic sand as the main dune-forming material. We used the colloidal probe atomic force microscopy (AFM) technique to study triboelectric charging processes using Titan and Earth sand analogs. We found that it is easy to generate triboelectric charges between naphthalene (a simple aromatic hydrocarbon), polystyrene (an aromatic hydrocarbon polymer), and borosilicate glass (Earth silicate sand analog). Strong electrostatic forces can be measured after contact and/or tribocharging. In contrast, tholin, a complex organic material, does not generate any detectable electrostatic forces with contact or tribocharging within the detection limit of the instrument. If Titan sand behaves more like tholin, this indicates that the tribocharging capacity of Titan sand is much weaker than Earth silicate sand and much less than previously measured by Mendez-Harper et al., (2017), where only simple organics were used for Titan sand analogs. Thus, triboelectrification may not contribute to increasing interparticle forces between sand particles on Titan as much as on Earth. Interparticle forces generated by other electrostatic processes or other interparticle forces such as van der Waals and capillary cohesion forces could be the dominant interparticle forces that govern Titan sand formation and sediment transportation on the surface. Titan sand is also unlikely to produce large electrical discharge through tribocharging to affect future missions to Titan's surface.

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arXiv2018

Where does Titan Sand Come From: Insight from Mechanical Properties of Titan Sand Candidates

Extensive equatorial linear dunes exist on Titan, but the origin of the sand, which appears to be organic, is unknown. We used nanoindentation to study the mechanical properties of a few Titan sand candidates, several natural sands on Earth, and common materials used in the Titan Wind Tunnel, to understand the mobility of Titan sand. We measured the elastic modulus (E), hardness (H), and fracture toughness (Kc) of these materials. Tholin's elastic modulus (10.4+/-0.5 GPa) and hardness (0.53+/-0.03 GPa) are both an order of magnitude smaller than silicate sand, and is also smaller than the mechanically weak white gypsum sand. With a magnitude smaller fracture toughness (Kc=0.036+/-0.007 MPa-m^(1/2)), tholin is also much more brittle than silicate sand. This indicates that Titan sand should be derived close to the equatorial regions where the current dunes are located, because tholin is too soft and brittle to be transported for long distances.

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