arXiv subjects

Y. Fu

Publications and source records attributed to Y. Fu.

At least 19 recordsLinked to original sources

arXiv2026

Euclid: Discovery of 31 new quasars at $6.6 < z < 7.8$

We report the discovery of 31 new high-$z$ quasars in the redshift range $6.6 < z < 7.8$. These quasars were selected from approximately 3000 deg$^2$ of sky covered during the first 1.5 years of the Euclid Wide Survey, representing the initial results of the Euclid high-$z$ quasar search. Our candidate selection employed multiple machine-learning and probabilistic techniques applied to the Euclid $I_E$, $Y_E$, $J_E$, and $H_E$ images, supplemented by ancillary $z$-band data when available. Spectroscopic follow-up observations were carried out with Keck, Magellan, and the Large Binocular Telescope (LBT). Among the new discoveries, there are 12 quasars at $z \geq 7$, more than doubling the number of previously known quasars at $z \geq 7$. The newly discovered quasars exhibit $21.2 < J_E < 23.2$ ($-25.5 < M_{1450} < -23.6$), extending quasar studies to the faint end of the quasar luminosity function (QLF) at $z \gtrsim 7$. The quasar with the highest-$z$, EUCL J172902.75+641018.1 at $z \approx 7.77$, sets the new redshift record for the most distant quasar ever reported. These discoveries demonstrate Euclid's transformative role in high-$z$ quasar discovery and set the stage for future follow-up studies of the early galaxies hosting quasars, supermassive black hole growth, and the intergalactic medium in the epoch of reionisation.

astro-ph.GA↗

arXiv2026

Euclid: A UV-faint quasar in a highly luminous star-forming host galaxy at $z \approx 7.7$

Constraining the co-evolution of supermassive black holes and their host galaxies in the first billion years after the Big Bang is essential for understanding the formation of the earliest cosmic structures. Here, we present IRAM/NOrthern Extended Millimeter Array (NOEMA) observations of the $z \approx 7.7$ quasar EUCL\,J125308.55+705432.3, recently discovered in the first data release of the Euclid Wide Survey. We report the most distant detections of [CII] 158$\mu\mathrm{m}$ and cold dust emission in a quasar host to date. The [CII] emission line sets the systemic redshift at $z=7.6980\pm0.0004$. The source exhibits luminosities of $L_{\rm FIR}=3.6\times10^{12}\,L_{\odot}$ and $L_{[CII]}=2\times10^9\,L_{\odot}$, respectively, a dust mass of 1.4$\times 10^{8}\,M_{\odot}$, and a dynamical mass in the range 0.33-1.3$\times10^{10}\,M_{\odot}$. Remarkably, despite being nearly two magnitudes fainter in the rest-frame UV ($M_{1450}=-24.06$) than previously known $z\approx7.5$ quasars ( $\sim-$26.5), EUCL\,J125308.55+705432.3 exhibits the brightest [CII] emission among them. This indicates that the host galaxy is actively star-forming, with a star-formation rate $>250\,M_{\odot}\,\mathrm{yr}^{-1}$, consistent with recent findings that UV-faint quasars at $z>6$ preferentially reside in [CII]-luminous galaxies. The UV-faintness likely reflects dust obscuration or sub-Eddington accretion, rather than lower host mass, suggesting these systems are at a different stage in their evolution compared to UV-bright quasars. These IRAM/NOEMA observations highlight the power of combining Euclid's wide-area quasar discovery potential with submillimetre follow-up observations to characterise the host galaxies of early supermassive black holes across a broader redshift and luminosity range than previously accessible.

astro-ph.GA↗

arXiv2026

Euclid: Scaled-up little red dots and other sources with v-shaped spectral energy distributions at z>4

Little Red Dots (LRDs) are some the most intriguing galaxy populations recently identified at z>~4 with JWST. They constitute the most extreme class of a more abundant population of sources with `V-shaped' spectral energy distributions (SEDs) and compact morphologies, which includes also Little Blue Dots (LBDs). Finding brighter analogues to these sources requires surveying sky areas which are significantly larger than those covered with JWST. Euclid deep images are ideally suited for this purpose. We make use of Euclid near-infrared images, complemented by Spitzer Infrared Array Camera (IRAC) data, over 0.75 sq. deg. of the COSMOS field to select a sample of 233 sources with `V-shaped' SEDs at z>4. Out of those, we identify 16 sources with compactness >1sigma above the median of all z>4 galaxies, which we consider robust LRD/LBD candidates in our sample. The stellar masses of these 16 sources are in the range 10^{8.5} - 10^{10.5} Msun, so they are significantly more massive than typical JWST-selected LRDs/LBDs. Interestingly, half of them are about as old as the Universe at their redshifts. In addition, we find that the median photometric properties of the Euclid LRDs/LBDs are similar to those of the so-called Blue Dust-Obscured Galaxies (Blue DOGs). Less than 10% of all our `V-shaped' SED sources, including only one of the Euclid LBDs, correspond to known AGN. The latter mostly constitute a population disjoint to the `V-shaped' SED sources. Spectroscopic follow up of the Euclid LRDs/LBD candidates remains necessary to probe whether they host BLAGN as fainter analogues do and whether constitute a transition phase from these fainter sources to standard AGN.

astro-ph.GA↗

arXiv2026

Precision QCD with the Electron-Ion Collider

This document summarizes the discussions at the program "Precision QCD with the Electron Ion Collider", held from May to June 2025 at the Institute for Nuclear Theory (INT) at the University of Washington. The program was co-sponsored by the INT and by the Center for Frontiers in Nuclear Science (CFNS, Stony Brook University). Over its five-week duration it brought together about 70 theorists, experimentalists and computer scientists all interested in the physics program at the future Electron Ion Collider in preparation at Brookhaven National Laboratory. Key topics at the program were: higher-order perturbative-QCD calculations and techniques; nuclear structure and tomography; comparisons of phenomenological and lattice determinations of parton distribution functions; identification of signature observables for saturated gluons; assessment of the importance of AI techniques for EIC studies and detector development.

hep-ph↗

arXiv2026

The high speed analog optical readout system designed for low temperature experiments

For low-temperature experiments such as liquid xenon dark matter detectors, it is crucial to read out detector signals from cryostats. Traditionally, photoelectrical signals are transmitted from the cryogenic region to the outside using coaxial cables through vacuum feedthroughs on the cryostats. In this paper, we investigate an analog optical transmission method in which the raw electrical signals are converted into optical signals with light intensity linearly proportional to the electrical amplitude, transmitted out of the cryogenic environment through optical fiber, and subsequently converted back into electrical signals by photoelectric devices while preserving the signal waveform. This new approach offers advantages, including low attenuation over long-distance transmission and reduced crosstalk across the feedthroughs. Additionally, the low-temperature optical wavelength multiplexing scheme has been investigated and applied, increasing the transmission capability of a single fiber. At -100 degree Celsius, the proposed analog optical readout system achieves a -3dB bandwidth of larger than 150MHz, a dynamic range of up to 500mV, and a low cryogenic-region power consumption of 70mW per channel, demonstrating its strong potential for low-temperature experiments.

physics.ins-det↗

arXiv2025

CT25: Progress toward next-generation PDFs for precision phenomenology at the LHC

We summarize recent progress toward the next generation of CTEQ-TEA parton distribution functions, CT25, based on a global NNLO analysis that incorporates a significant sample of newly included LHC data. We present a baseline fit within the forthcoming full CT25 fit, which includes new Drell-Yan, top-pair, and inclusive-jet data at 8 and 13 TeV, and exhibits non-trivial pulls on the high-$x$ gluon and the flavor structure of the quark sea. In the context of progress toward CT25, we also summarize several recent and ongoing studies of the interplay between phenomenological PDFs and lattice-QCD calculations, simultaneous extractions of $\alpha_s(M_Z)$ within the CT framework, and an expanded program of uncertainty quantification that treats parametrization dependence as an explicit source of epistemic uncertainty, among other issues. We also briefly highlight CT efforts to understand the effects of partial implementations of N$^3$LO corrections into PDF fits, which include benchmark calculations for Higgs and vector-boson processes. We comment on the implications of recent improvements to the CT analysis for precision phenomenology at the LHC and future facilities.

hep-ph↗

arXiv2025

Euclid Quick Data Release (Q1): Euclid spectroscopy of quasars. 1. Identification and redshift determination of 3500 bright quasars

The slitless spectroscopy mode of the NISP onboard Euclid has enabled efficient spectroscopy of objects within a large FoV. We present a large and homogeneous sample of bright quasars identified from the Euclid Quick Data Release (Q1) by combining high-purity candidate selections from Gaia and WISE with the NISP spectra. Through visual inspection of the Euclid spectra of these quasar candidates, we identify approximately 3500 quasars with reliable redshifts at $0<z\lesssim 4.8$. Of these, 2686 are new spectroscopic identifications relative to existing public compilations. We generate the first Euclid composite spectrum of quasars covering rest-frame NUV to NIR wavelengths without telluric lines, which will be pivotal to NIR quasar spectral analysis. We obtain an empirical spectroscopic depth of $J_{\rm E}\lesssim 21.5$ and $H_{\rm E}\lesssim 21.3$ at the sensitivity of the Wide Field Survey, beyond which the number of securely identified quasars declines sharply. We analyse VIS morphologies using Sersic and CAS metrics, and a deep-learning PSF fraction to track nuclear dominance. At low redshift ($z<0.5$), obvious host structures are common and a single Sersic model fits about half of the sources; at intermediate redshift ($0.5<z<2$), the nuclear component dominates, with 90% of the Sersic fits saturating at the upper index limit. In this intermediate redshift regime, $f_{\rm PSF}$ is available, and we use it as a more reliable compactness measure than the single-Sersic and CAS parameters to quantify nuclear versus host emission. We also explore the novel Euclid NIR colour space and discuss the role of these quasars in refining AGN selection techniques for future Euclid data releases. The spectroscopic bright quasar catalogue of this work, and the composite quasar spectrum, will be available at https://cdsarc.cds.unistra.fr/. (abridged)

astro-ph.GA↗

arXiv2025

Euclid Quick Data Release (Q1): Identification of massive galaxy candidates at the end of the Epoch of Reionisation

Probing the presence and properties of massive galaxies at high redshift is one of the most critical tests for galaxy formation models. In this work, we search for galaxies with stellar masses M* > 10^10.25 Msun at z in [5,7], i.e., towards the end of the Epoch of Reionisation, over a total of ~23 deg^2 in two of the Euclid Quick Data Release (Q1) fields: the Euclid Deep Field North and Fornax (EDF-N and EDF-F). In addition to the Euclid photometry, we incorporate Spitzer Infrared Camera (IRAC) and ground-based optical data to perform spectral energy distribution (SED) fitting, obtaining photometric redshifts and derived physical parameters. After applying rigorous selection criteria, we identify a conservative sample of 145 candidate massive galaxies with M* > 10^10.25 Msun at z in [5,7], including 5 objects with M* > 10^11 Msun. This makes for a surface density of about 6.3 deg^-2 at z in [5,7], which should be considered a lower limit because of the current depth of the Euclid data (H_E < 24, 5 sigma in Q1). We find that the inferred stellar masses are consistent with galaxy formation models with standard star-formation efficiencies. These massive galaxies have colour excess E(B-V) values up to 0.75, indicating significant dust attenuation in some of them. In addition, half of the massive galaxies have best-fit ages comparable to the age of the Universe at those redshifts, which suggests that their progenitors were formed very early in cosmic time. About 78% of the massive galaxies lie on the star-forming main sequence (MS) in the SFR-M* plane, ~12% are found in the starburst region, and 10% in the transition zone between the MS and starbursts. We find no significant evidence for outshining or AGN contamination that could account for the elevated specific star-formation rates (sSFR) observed in the ~12% of galaxies classified as starbursts.

astro-ph.GA↗

arXiv2025

Euclid Quick Data Release (Q1). Spectroscopic unveiling of highly ionised lines at z = 2.48-3.88

This study explores a rare population of sources in a currently uncharted region of spectroscopic redshift space in the Euclid Quick Data Release (Q1), and is intended potentially to support upcoming spectroscopic studies. Our goal is to identify and investigate a population of sources characterised by highly ionised emission lines in their spectra, which are indicative of active galactic nucleus activity, extreme shock phenomena, or Wolf--Rayet stars. A comprehensive visual inspection of spectra is conducted to ensure the reliability of the sample, focusing on the simultaneous detection of both NeV and OII emission-line measurements, a condition that restricts the Euclid spectroscopic redshift range to z=2.48--3.88. To characterise this population, we analysed the morpho-spectrophotometric properties of their host galaxies. This allowed for a direct comparison with control sources that exhibit similar OII properties and spectroscopic redshifts, but not NeV lines. We identify sources solely based on spectroscopic criteria in the redshift range beyond the Halpha regime. Encompassing 65 potential NeV candidates, the resulting sample delivers the first systematic probe of these NeV candidate emitters at high redshift. We found a good agreement, within 1$\sigma$, between the spectral measurements calculated using both direct integration and Gaussian fitting methodologies. The NeV candidates exhibit colours similar to bright QSOs, with only a few in the tail of very red quasars. We observed a higher stellar mass content, a lower continuum around the 4000A break, and a similar S\'{e}rsic index distribution compared to the control sample. This unique sample paves the way for a wide range of scientific investigations, which will be pursued in the forthcoming data releases.

astro-ph.GA↗

arXiv2025

Mechanism of the electrochemical hydrogenation of graphene

The electrochemical hydrogenation of graphene induces a robust and reversible conductor-insulator transition, of strong interest in logic-and-memory applications. However, its mechanism remains unknown. Here we show that it proceeds as a reduction reaction in which proton adsorption competes with the formation of H2 molecules via an Eley-Rideal process. Graphene's electrochemical hydrogenation is up to $10^6$ times faster than alternative hydrogenation methods and is fully reversible via the oxidative desorption of protons. We demonstrate that the proton reduction rate in defect-free graphene can be enhanced by an order of magnitude by the introduction of nanoscale corrugations in its lattice, and that the substitution of protons for deuterons results both in lower potentials for the hydrogenation process and in a more stable compound. Our results pave the way to investigating the chemisorption of ions in 2D materials at high electric fields, opening a new avenue to control these materials' electronic properties.

physics.chem-ph↗

arXiv2025

Euclid: A machine-learning search for dual and lensed AGN at sub-arcsec separations

Cosmological models of hierarchical structure formation predict the existence of a widespread population of dual accreting supermassive black holes (SMBHs) on kpc-scale separations, corresponding to projected distances < 0".8 at redshifts higher than 0.5. However, close companions to known active galactic nuclei (AGN) or quasars (QSOs) can also be multiple images of the object itself, strongly lensed by a foreground galaxy, as well as foreground stars in a chance superposition. Thanks to its large sky coverage, sensitivity, and high spatial resolution, Euclid offers a unique opportunity to obtain a large, homogeneous sample of dual/lensed AGN candidates with sub-arcsec projected separations. Here we present a machine learning approach, in particular a Convolutional Neural Network (CNN), to identify close companions to known QSOs down to separations of $\sim\,$0".15 comparable to the Euclid VIS point spread function (PSF). We studied the effectiveness of the CNN in identifying dual AGN and demonstrated that it outperforms traditional techniques. Applying our CNN to a sample of $\sim\,$6000 QSOs from the Q1 Euclid data release, we find a fraction of about 0.25% dual AGN candidates with separation $\sim\,$0".4 (corresponding to $\sim$3 kpc at z=1). Estimating the foreground contamination from stellar objects, we find that most of the pair candidates with separation higher than 0".5 are likely contaminants, while below this limit, contamination is expected to be less than 20%. For objects at higher separation (>0".5, i.e. 4 kpc at z=1), we performed PSF subtraction and used colour-colour diagrams to constrain their nature. We present a first set of dual/lensed AGN candidates detected in the Q1 Euclid data, providing a starting point for the analysis of future data releases.

astro-ph.GA↗

arXiv2025

Euclid Quick Data Release (Q1). NIR processing and data products

This paper describes the near-infrared processing function (NIR PF) that processes near-infrared images from the Near-Infrared Spectrometer and Photometer (NISP) instrument onboard the Euclid satellite. NIR PF consists of three main components: (i) a common pre-processing stage for both photometric (NIR) and spectroscopic (SIR) data to remove instrumental effects; (ii) astrometric and photometric calibration of NIR data, along with catalogue extraction; and (iii) resampling and stacking. The necessary calibration products are generated using dedicated pipelines that process observations from both the early performance verification (PV) phase in 2023 and the nominal survey operations. After outlining the pipeline's structure and algorithms, we demonstrate its application to Euclid Q1 images. For Q1, we achieve an astrometric accuracy of 9-15 mas, a relative photometric accuracy of 5 mmag, and an absolute flux calibration limited by the 1% uncertainty of the Hubble Space Telescope (HST) CALSPEC database. We characterise the point-spread function (PSF) that we find very stable across the focal plane, and we discuss current limitations of NIR PF that will be improved upon for future data releases.

astro-ph.CO↗

arXiv2025

Euclid Quick Data Release (Q1) Exploring galaxy properties with a multi-modal foundation model

Modern astronomical surveys, such as the Euclid mission, produce high-dimensional, multi-modal data sets that include imaging and spectroscopic information for millions of galaxies. These data serve as an ideal benchmark for large, pre-trained multi-modal models, which can leverage vast amounts of unlabelled data. In this work, we present the first exploration of Euclid data with AstroPT, an autoregressive multi-modal foundation model trained on approximately 300 000 optical and infrared Euclid images and spectral energy distributions (SEDs) from the first Euclid Quick Data Release. We compare self-supervised pre-training with baseline fully supervised training across several tasks: galaxy morphology classification; redshift estimation; similarity searches; and outlier detection. Our results show that: (a) AstroPT embeddings are highly informative, correlating with morphology and effectively isolating outliers; (b) including infrared data helps to isolate stars, but degrades the identification of edge-on galaxies, which are better captured by optical images; (c) simple fine-tuning of these embeddings for photometric redshift and stellar mass estimation outperforms a fully supervised approach, even when using only 1% of the training labels; and (d) incorporating SED data into AstroPT via a straightforward multi-modal token-chaining method improves photo-z predictions, and allow us to identify potentially more interesting anomalies (such as ringed or interacting galaxies) compared to a model pre-trained solely on imaging data.

astro-ph.GA↗

arXiv2025

Euclid Quick Data Release (Q1) First study of red quasars selection

Red quasars constitute an important but elusive phase in the evolution of supermassive black holes, where dust obscuration can significantly alter their observed properties. They have broad emission lines, like other quasars, but their optical continuum emission is significantly reddened, which is why they were traditionally identified based on near- and mid-infrared selection criteria. This work showcases the capability of the \Euclid space telescope to find a large sample of red quasars, using \Euclid near infrared (NIR) photometry. We first conduct a forecast analysis, comparing a synthetic catalogue of red QSOs with COSMOS2020. Using template fitting, we reconstruct \Euclid-like photometry for the COSMOS sources and identify a sample of candidates in a multidimensional colour-colour space achieving $98\%$ completeness for mock red QSOs with $30\%$ contaminants. To refine our selection function, we implement a probabilistic Random Forest classifier, and use UMAP visualisation to disentangle non-linear features in colour-space, reaching $98\%$ completeness and $88\%$ purity. A preliminary analysis of the candidates in the \Euclid Deep Field Fornax (EDF-F) shows that, compared to VISTA+DECAm-based colour selection criteria, \Euclid's superior depth, resolution and optical-to-NIR coverage improves the identification of the reddest, most obscured sources. Notably, the \Euclid exquisite resolution in the $I_E$ filter unveils the presence of a candidate dual quasar system, highlighting the potential for this mission to contribute to future studies on the population of dual AGN. The resulting catalogue of candidates, including more the 150 000 sources, provides a first census of red quasars in \Euclid Q1 and sets the groundwork for future studies in the Euclid Wide Survey (EWS), including spectral follow-up analyses and host morphology characterisation.

astro-ph.GA↗

arXiv2025

Euclid Quick Data Release (Q1). The active galaxies of Euclid

We present a catalogue of candidate active galactic nuclei (AGN) in the $Euclid$ Quick Release (Q1) fields. For each $Euclid$ source we collect multi-wavelength photometry and spectroscopy information from Galaxy Evolution Explorer (GALEX), $Gaia$, Dark Energy Survey (DES), Wise-field Infrared Survey Explorer (WISE), $Spitzer$, Dark Energy Survey (DESI), and Sloan Digital Sky Survey (SDSS), including spectroscopic redshift from public compilations. We investigate the AGN contents of the Q1 fields by applying selection criteria using $Euclid$ colours and WISE-AllWISE cuts finding respectively 292,222 and 65,131 candidates. We also create a high-purity QSO catalogue based on $Gaia$ DR3 information containing 1971 candidates. Furthermore, we utilise the collected spectroscopic information from DESI to perform broad-line and narrow-line AGN selections, leading to a total of 4392 AGN candidates in the Q1 field. We investigate and refine the Q1 probabilistic random forest QSO population, selecting a total of 180,666 candidates. Additionally, we perform SED fitting on a subset of sources with available $z_{\text{spec}}$, and by utilizing the derived AGN fraction, we identify a total of 7766 AGN candidates. We discuss purity and completeness of the selections and define two new colour selection criteria ($JH$_$I_{\text{E}}Y$ and $I_{\text{E}}H$_$gz$) to improve on purity, finding 313,714 and 267,513 candidates respectively in the Q1 data. We find a total of 229,779 AGN candidates equivalent to an AGN surface density of 3641 deg$^{-2}$ for $18<I_{\text{E}}\leq 24.5$, and a subsample of 30,422 candidates corresponding to an AGN surface density of 482 deg$^{-2}$ when limiting the depth to $18<I_{\text{E}}\leq 22$. The surface density of AGN recovered from this work is in line with predictions based on the AGN X-ray luminosity functions.

astro-ph.HE↗

arXiv2024

Control of proton transport and hydrogenation in double-gated graphene

The basal plane of graphene can function as a selective barrier that is permeable to protons but impermeable to all ions and gases, stimulating its use in applications such as membranes, catalysis and isotope separation. Protons can chemically adsorb on graphene and hydrogenate it, inducing a conductor-insulator transition that has been explored intensively in graphene electronic devices. However, both processes face energy barriers and various strategies have been proposed to accelerate proton transport, for example by introducing vacancies, incorporating catalytic metals or chemically functionalizing the lattice. However, these techniques can compromise other properties, such as ion selectivity or mechanical stability. Here we show that independent control of the electric field, E, at around 1 V nm-1, and charge-carrier density, n, at around 1 x 10^14 cm-2, in double-gated graphene allows the decoupling of proton transport from lattice hydrogenation and can thereby accelerate proton transport such that it approaches the limiting electrolyte current for our devices. Proton transport and hydrogenation can be driven selectively with precision and robustness, enabling proton-based logic and memory graphene devices that have on-off ratios spanning orders of magnitude. Our results show that field effects can accelerate and decouple electrochemical processes in double-gated 2D crystals and demonstrate the possibility of mapping such processes as a function of E and n, which is a new technique for the study of 2D electrode-electrolyte interfaces.

cond-mat.mes-hall↗

arXiv2023

$\mathcal R(3780)$ Resonance Interpreted as the $1^3D_1$-Wave Dominant State of Charmonium from Precise Measurements of the Cross Section of $e^+e^-\rightarrow$ Hadrons

We report the precise measurements of the cross section of $e^+e^-\rightarrow$ hadrons at center-of-mass energies from 3.645 to 3.871 GeV. We thereby perform the most precise study of the cross sections and find a complex system composed of three resonances of $\mathcal R(3760)$, $\mathcal R(3780)$, and $\mathcal R(3810)$. For the first time, we measure the $\mathcal R(3810)$ electronic width to be $(19.4 \pm 7.4 \pm 12.1)$ eV. For the $\mathcal R(3760)$ resonance, we measure the mass to be $(3751.9\pm 3.8\pm 2.8)$ MeV/$c^2$, the total width to be $(32.8 \pm 5.8 \pm 8.7)$ MeV, and the electronic width to be $(184\pm 75\pm 86)$ eV. For the $\mathcal R(3780)$ resonance, we measure its mass to be $(3778.7\pm 0.5\pm 0.3)$ MeV/$c^2$, total width to be $(20.3 \pm 0.8 \pm 1.7)$ MeV, and electronic width to be $(265\pm 67\pm 83)$ eV. Forty-seven years ago, the $\psi(3770)$ resonance was discovered, and was subsequently interpreted as the $1^3D_1$-wave dominant state of charmonium. However, our analysis of the total-hadron cross sections indicates that the $\psi(3770)$ is not a single state, but a complex system composed of the $\mathcal R(3760)$, $\mathcal R(3780)$, and $\mathcal R(3810)$ resonances. Among these, we interpret the $\mathcal R(3780)$ is a resonance dominated by the $1^3D_1$ charmonium state.

hep-ex↗

arXiv2023

Gate-controlled suppression of light-driven proton transport through graphene electrodes

Recent experiments demonstrated that proton transport through graphene electrodes can be accelerated by over an order of magnitude with low intensity illumination. Here we show that this photo-effect can be suppressed for a tuneable fraction of the infrared spectrum by applying a voltage bias. Using photocurrent measurements and Raman spectroscopy, we show that such fraction can be selected by tuning the Fermi energy of electrons in graphene with a bias, a phenomenon controlled by Pauli blocking of photo-excited electrons. These findings demonstrate a dependence between graphene's electronic and proton transport properties and provide fundamental insights into molecularly thin electrode-electrolyte interfaces and their interaction with light.

cond-mat.mes-hall↗