Orbital-engineered px,y-kagome lattice in a halogen monolayer
Multi-orbital kagome lattices with explicit orbital degrees of freedom remain largely unexplored, as most experimentally realized systems rely on complex d-electron manifolds that are approximated by isotropic single-orbital models. Here, we overcome this limitation by realizing a px,y-orbital kagome lattice through deposition of a Br monolayer on Ag(111), where orbital filtering selectively suppresses the pz channel. Scanning tunneling microscopy, angle-resolved photoemission spectroscopy, and density-functional-theory calculations reveal a large-area, highly ordered kagome structure whose band dispersions quantitatively match the anisotropic px,y tight-binding model. To extract the intrinsic manifold from the substrate background, we construct an effective H-passivated model, which uncover the intrinsic electronic structure and reveals nontrivial topological characteristics of the px,y kagome manifold driven by first-order spin-orbit coupling effect. Our work establishes Br/Ag(111) as an experimentally accessible platform for multi-orbital kagome physics, extending the kagome paradigm from the conventional d-orbital regime to an orbitally engineered topological setting.