arXiv subjects

Zhenyu Zhang

Publications and source records attributed to Zhenyu Zhang.

At least 325 records · Page 18Linked to original sources

arXiv2015

Converting a topologically trivial superconductor into a topological superconductor via magnetic doping

We present a comparative theoretical study of the effects of standard Anderson and magnetic disorders on the topological phases of two-dimensional Rashba spin-orbit coupled superconductors, with the initial state to be either topologically trivial or nontrivial. Using the self-consistent Born approximation approach, we show that the presence of Anderson disorders will drive a topological superconductor into a topologically trivial superconductor in the weak coupling limit. Even more strikingly, a topologically trivial superconductor can be driven into a topological superconductor upon diluted doping of independent magnetic disorders, which gradually narrow, close, and reopen the quasi-particle gap in a nontrivial manner. These topological phase transitions are distinctly characterized by the changes in the corresponding topological invariants. The central findings made here are also confirmed using a complementary numerical approach by solving the Bogoliubov-de Gennes equations self-consistently within a tight-binding model. The present study offers appealing new schemes for potential experimental realization of topological superconductors.

cond-mat.supr-con↗

arXiv2015

Rayleigh scattering of linear alkylbenzene in large liquid scintillator detectors

Rayleigh scattering poses an intrinsic limit for the transparency of organic liquid scintillators. This work focuses on the Rayleigh scattering length of linear alkylbenzene (LAB), which will be used as the solvent of the liquid scintillator in the central detector of the Jiangmen Underground Neutrino Observatory. We investigate the anisotropy of the Rayleigh scattering in LAB, showing that the resulting Rayleigh scattering length will be significantly shorter than reported before. Given the same overall light attenuation, this will result in a more efficient transmission of photons through the scintillator, increasing the amount of light collected by the photosensors and thereby the energy resolution of the detector.

physics.ins-det↗

arXiv2015

High-Temperature Quantum Anomalous Hall Effect in n-p Codoped Topological Insulators

The quantum anomalous Hall effect (QAHE) is a fundamental quantum transport phenomenon that manifests as a quantized transverse conductance in response to a longitudinally applied electric field in the absence of an external magnetic field, and promises to have immense application potentials in future dissipation-less quantum electronics. Here we present a novel kinetic pathway to realize the QAHE at high temperatures by $n$-$p$ codoping of three-dimensional topological insulators. We provide proof-of-principle numerical demonstration of this approach using vanadium-iodine (V-I) codoped Sb$_2$Te$_3$ and demonstrate that, strikingly, even at low concentrations of $\sim$2\% V and $\sim$1\% I, the system exhibits a quantized Hall conductance, the tell-tale hallmark of QAHE, at temperatures of at least $\sim$ 50 Kelvin, which is three orders of magnitude higher than the typical temperatures at which it has been realized so far. The proposed approach is conceptually general and may shed new light in experimental realization of high-temperature QAHE.

cond-mat.mtrl-sci↗

arXiv2015

Equivalence of Electronic and Mechanical Stresses in Structural Phase Stabilization: A Case Study of Indium Wires on Si(111)

It was recently proposed that the stress state of a material can also be altered via electron or hole doping, a concept termed electronic stress (ES), which is different from the traditional mechanical stress (MS) due to lattice contraction or expansion. Here we demonstrate the equivalence of ES and MS in structural stabilization, using In wires on Si(111) as a prototypical example. Our systematic density-functional theory calculations reveal that, first, for the same degrees of carrier doping into the In wires, the ES of the high-temperature metallic 4x1 structure is only slightly compressive, while that of the low-temperature insulating 8x2 structure is much larger and highly anisotropic. As a consequence, the intrinsic energy difference between the two phases is significantly reduced towards electronically phase-separated ground states. Our calculations further demonstrate quantitatively that such intriguing phase tunabilities can be achieved equivalently via lattice-contraction induced MS in the absence of charge doping. We also validate the equivalence through our detailed scanning tunneling microscopy experiments. The present findings have important implications in understanding the underlying driving forces involved in various phase transitions of simple and complex systems alike.

cond-mat.mes-hall↗

arXiv2015

Spectroscopic study of light scattering in linear alkylbenzene for liquid scintillator neutrino detectors

We has set up a light scattering spectrometer to study the depolarization of light scattering in linear alkylbenzene. From the scattering spectra it can be unambiguously shown that the depolarized part of light scattering belongs to Rayleigh scattering. The additional depolarized Rayleigh scattering can make the effective transparency of linear alkylbenzene much better than it was expected. Therefore sufficient scintillation photons can transmit through the large liquid scintillator detector of JUNO. Our study is crucial to achieving the unprecedented energy resolution 3\%/$\sqrt{E\mathrm{(MeV)}}$ for JUNO experiment to determine the neutrino mass hierarchy. The spectroscopic method can also be used to judge the attribution of the depolarization of other organic solvents used in neutrino experiments.

physics.chem-ph↗

arXiv2015

Densities, isobaric thermal expansion coefficients and isothermal compressibilities of linear alkylbenzene

We report the measurements of the densities of linear alkylbenzene at three temperatures over 4 to 23 Celsius degree with pressures up to 10 MPa. The measurements have been analysed to yield the isobaric thermal expansion coefficients and, so far for the first time, isothermal compressibilities of linear alkylbenzene. Relevance of results for current generation (i.e. Daya Bay) and next generation (i.e. JUNO) large liquid scintillator neutrino detectors are discussed.

physics.ins-det↗

arXiv2015

Single-Valley Engineering in Graphene Superlattices

The two inequivalent valleys in graphene preclude the protection against inter-valley scattering offered by an odd-number of Dirac cones characteristic of Z2 topological insulator phases. Here we propose a way to engineer a chiral single-valley metallic phase with quadratic crossover in a honeycomb lattice through tailored \sqrt{3}N *\sqrt{3}N or 3N *3N superlattices. The possibility of tuning valley-polarization via pseudo-Zeeman field and the emergence of Dresselhaus-type valley-orbit coupling are proposed in adatom decorated graphene superlattices. Such valley manipulation mechanisms and metallic phase can also find applications in honeycomb photonic crystals.

cond-mat.mtrl-sci↗

arXiv2015

Quantum Anomalous Hall Effect in Graphene Proximity Coupled to an Antiferromagnetic Insulator

We propose realizing the quantum anomalous Hall effect by proximity coupling graphene to an antiferromagnetic insulator that provides both broken time-reversal symmetry and spin-orbit coupling. We illustrate our idea by performing ab initio calculations for graphene adsorbed on the (111) surface of BiFeO3. In this case, we find that the proximity-induced exchange field in graphene is about 70 meV, and that a topologically nontrivial band gap is opened by Rashba spin-orbit coupling. The size of the gap depends on the separation between the graphene and the thin film substrate, which can be tuned experimentally by applying external pressure.

cond-mat.mes-hall↗

arXiv2014

Persistent ferromagnetism and topological phase transition at the interface of a superconductor and a topological insulator

At the interface of an s-wave superconductor and a three-dimensional topological insulator, Ma- jorana zero modes and Majorana helical states have been proposed to exist respectively around magnetic vortices and geometrical edges. Here we first show that a single magnetic impurity at such an interface splits each resonance state of a given spin channel outside the superconducting gap, and also induces two new symmetric impurity states inside the gap. Next we find that an increase in the superconducting gap suppresses both the oscillation magnitude and period of the RKKY inter- action between two interface magnetic impurities mediated by BCS quasi-particles. Within a mean field approximation, the ferromagnetic Curie temperature is found to be essentially independent of the superconducting gap, an intriguing phenomenon due to a compensation effect between the short-range ferromagnetic and long-range anti-ferromagnetic interactions. The existence of persis- tent ferromagnetism at the interface allows realization of a novel topological phase transition from a non-chiral to a chiral superconducting state at sufficiently low temperatures, providing a new platform for topological quantum computation.

cond-mat.mtrl-sci↗

arXiv2014

Proximity Effects in Topological Insulator Heterostructures

Topological insulators (TIs) are bulk insulators that possess robust helical conducting states along their interfaces with conventional insulators. A tremendous research effort has recently been devoted to TI-based heterostructures, in which conventional proximity effects give rise to a series of exotic physical phenomena. This paper reviews our recent works on the potential existence of topological proximity effects at the interface between a topological insulator and a normal insulator or other topologically trivial systems. Using first-principles approaches, we have established the tunability of the vertical location of the topological helical state via intriguing dual-proximity effects. To further elucidate the control parameters of this effect, we have used the graphene-based heterostructures as prototypical systems to reveal a more complete phase diagram. On the application side of the topological helical states, we have presented a catalysis example, where the topological helical state plays an essential role in facilitating surface reactions by serving as an effective electron bath. These discoveries lay the foundation for accurate manipulation of the real space properties of the topological helical state in TI-based heterostructures and pave the way for realization of the salient functionality of topological insulators in future device applications.

cond-mat.mtrl-sci↗

arXiv2013

Topological Proximity Effects in Graphene Nanoribbon Heterostructures

Topological insulators (TI) are bulk insulators that possess robust chiral conducting states along their interfaces with normal insulators. A tremendous research effort has recently been devoted to TI-based heterostructures, in which conventional proximity effects give rise to many exotic physical phenomena. Here we establish the potential existence of "topological proximity effects" at the interface of a topological graphene nanoribbon (GNR) and a normal GNR. Specifically, we show that the location of the topological edge states exhibits versatile tunability as a function of the interface orientation, as well as the strengths of the interface coupling and spin-orbit coupling in the normal GNR. For zigzag and bearded GNRs, the topological edge state can be tuned to be either at the interface or outer edge of the normal ribbon. For armchair GNR, the potential location of the topological edge state can be further enriched to be at the edge of or within the normal ribbon, at the interface, or diving into the topological GNR. We also discuss potential experimental realization of the predicted topological proximity effects, which may pave the way for integrating the salient functionality of TI and graphene in future device applications.

cond-mat.mes-hall↗

arXiv2013

NV-Center Based Digital Quantum Simulation of a Quantum Phase Transition in Topological Insulators

Nitrogen-vacancy centers in diamond are ideal platforms for quantum simulation, which allows one to handle problems that are intractable theoretically or experimentally. Here we propose a digital quantum simulation scheme to simulate the quantum phase transition occurring in an ultrathin topological insulator film placed in a parallel magnetic field [Zyuzin \textit{et al.}, Phys. Rev. B \textbf{83}, 245428 (2011)]. The quantum simulator employs high quality spin qubits achievable in nitrogen-vacancy centers and can be realized with existing technology. The problem can be mapped onto the Hamiltonian of two entangled qubits represented by the electron and nuclear spins. The simulation uses the Trotter algorithm, with an operation time of the order of 100 $μ$s for each individual run.

quant-ph↗

arXiv2013

Tuning the vertical location of helical surface states in topological insulator heterostructures via dual-proximity effects

In integrating topological insulators (TIs) with conventional materials, one crucial issue is how the topological surface states (TSS) will behave in such heterostructures. We use first-principles approaches to establish accurate tunability of the vertical location of the TSS via intriguing dual-proximity effects. By depositing a conventional insulator (CI) overlayer onto a TI substrate (Bi2Se3 or Bi2Te3), we demonstrate that, the TSS can float to the top of the CI film, or stay put at the CI/TI interface, or be pushed down deeper into the otherwise structurally homogeneous TI substrate. These contrasting behaviors imply a rich variety of possible quantum phase transitions in the hybrid systems, dictated by key material-specific properties of the CI. These discoveries lay the foundation for accurate manipulation of the real space properties of TSS in TI heterostructures of diverse technological significance.

cond-mat.mtrl-sci↗

arXiv2013

Gate-Tunable Exchange Coupling Between Cobalt Clusters on Graphene

We use spin-density-functional theory (SDFT) ab initio calculations to theoretically explore the possibility of achieving useful gate control over exchange coupling between cobalt clusters placed on a graphene sheet. By applying an electric field across supercells we demonstrate that the exchange interaction is strongly dependent on gate voltage, but find that it is also sensitive to the relative sublattice registration of the cobalt clusters. We use our results to discuss strategies for achieving strong and reproducible magneto-electric effects in graphene/transition-metal hybrid systems.

cond-mat.mtrl-sci↗

arXiv2012

Quantum Efficiency of Intermediate-Band Solar Cells Based on Non-Compensated n-p Codoped TiO2

As an appealing concept for developing next-generation solar cells, intermediate-band solar cells (IBSCs) promise to drastically increase the quantum efficiency of photovoltaic conversion. Yet to date, a standing challenge lies in the lack of materials suitable for developing IBSCs. Recently, a new doping approach, termed non-compensated n-p codoping, has been proposed to construct intermediate bands (IBs) in the intrinsic energy band gaps of oxide semiconductors such as TiO$_2$. We explore theoretically the optimal quantum efficiency of IBSCs based on non-compensated n-p codoped TiO$_2$ under two different design schemes. The first preserves the ideal condition that no electrical current be extracted from the IB. The corresponding maximum quantum efficiency for the codoped TiO$_2$ can reach 52.7%. In the second scheme, current is also extracted from the IB, resulting in a further enhancement in the maximum efficiency to 56.7%. Our findings also relax the stringent requirement that the IB location be close to the optimum value, making it more feasible to realize IBSCs with high quantum efficiencies.

cond-mat.mtrl-sci↗

arXiv2011

Activated Vibrational Modes and Fermi Resonance in Tip-Enhanced Raman Spectroscopy

Using p-aminothiophenol (PATP) molecules on a gold substrate as prototypical examples and high vacuum tip-enhanced Raman spectroscopy (HV-TERS), we show that the vibrational spectra of those molecules are distinctly different from those in typical surface-enhanced Raman spectroscopy. Detailed first-principles calculations help to assign the Raman peaks in the TERS measurements as Raman active and infrared (IR) active vibrational modes of dimercaptoazobenzene (DMAB), thus providing strong spectroscopic evidence for the conversion of PATP dimerization to DMAB. The activation of the IR active modes is due to enhanced electromagnetic field gradient effects within the gap region of the highly asymmetric tip-surface geometry. Our TERS measurements also realize splitting of certain vibrational modes due to Fermi resonance between a fundamental mode and the overtone of a different mode or a combinational mode. These findings help to broaden the versatility of TERS as a promising technique for ultrasensitive molecular spectroscopy.

physics.atm-clus↗

arXiv2011

Suppression of Grain Boundaries in Graphene Growth on Superstructured Mn-Cu(111) Surface

As undesirable defects, grain boundaries (GBs) are widespread in epitaxial graphene using existing growth methods on metal substrates. Employing density functional theory calculations, we first identify that the misorientations of carbon islands nucleated on a Cu(111) surface lead to the formation of GBs as the islands coalesce. We then propose a two-step kinetic pathway to effectively suppress the formation of GBs. In the first step, large aromatic hydrocarbon molecules are deposited onto a $\sqrt{3}\times\sqrt{3}$ superstructured Cu-Mn alloyed surface to seed the initial carbon clusters of a single orientation; in the second step, the seeded islands are enlarged through normal chemical vapor deposition of methane to form a complete graphene sheet. The present approach promises to overcome a standing obstacle in large scale single-crystal graphene fabrication.

cond-mat.mtrl-sci↗

arXiv2011

Atomic structure, energetics, and dynamics of topological solitons in Indium chains on Si(111) surfaces

Based on scanning tunneling microscopy and first-principles theoretical studies, we characterize the precise atomic structure of a topological soliton in In chains grown on Si(111) surfaces. Variable-temperature measurements of the soliton population allow us to determine the soliton formation energy to be ~60 meV, smaller than one half of the band gap of ~200 meV. Once created, these solitons have very low mobility, even though the activation energy is only about 20 meV; the sluggish nature is attributed to the exceptionally low attempt frequency for soliton migration. We further demonstrate local electric field-enhanced soliton dynamics.

cond-mat.mes-hall↗