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arXiv2013

Noise induced rupture process: Phase boundary and scaling of waiting time distribution

A bundle of fibers has been considered here as a model for composite materials, where breaking of the fibers occur due to a combined influence of applied load (stress) and external noise. Through numerical simulation and a mean-field calculation we show that there exists a robust phase boundary between continuous (no waiting time) and intermittent fracturing regimes. In the intermittent regime, throughout the entire rupture process avalanches of different sizes are produced and there is a waiting time between two consecutive avalanches. The statistics of waiting times follows a Gamma distribution and the avalanche distribution shows power law scaling, similar to what have been observed in case of earthquake events and bursts in fracture experiments. We propose a prediction scheme that can tell when the system is expected to reach the continuous fracturing point from the intermittent phase.

cond-mat.stat-mech↗

arXiv2013

Residual discrete symmetry of the five-state clock model

It is well-known that the $q$-state clock model can exhibit a Kosterlitz-Thouless (KT) transition if $q$ is equal to or greater than a certain threshold, which has been believed to be five. However, recent numerical studies indicate that helicity modulus does not vanish in the high-temperature phase of the five-state clock model as predicted by the KT scenario. By performing Monte Carlo calculations under the fluctuating twist boundary condition, we show that it is because the five-state clock model does not have the fully continuous U(1) symmetry even in the high-temperature phase while the six-state clock model does. We suggest that the upper transition of the five-state clock model is actually a weaker cousin of the KT transition so that it is $q \ge 6$ that exhibits the genuine KT behavior.

cond-mat.stat-mech↗

arXiv2013

Packing and Self-assembly of Truncated Triangular Bipyramids

Motivated by breakthroughs in the synthesis of faceted nano- and colloidal particles, as well as theoretical and computational studies of their packings, we investigate a family of truncated triangular bipyramids. We report dense periodic packings with small unit cells that were obtained via numerical and analytical optimization. The maximal packing fraction $ϕ_{\max}$ changes continuously with the truncation parameter $t$. Eight distinct packings are identified based on discontinuities in the first and second derivatives of $ϕ_{\max}(t)$. These packings differ in the number of particles in the fundamental domain (unit cell) and the type of contacts between the particles. In particular, we report two packings with four particles in the unit cell for which both $ϕ_{\max}(t)$ and $ϕ'_{\max}(t)$ are continuous and the discontinuity occurs in the second derivative only. In the self-assembly simulations that we perform for larger boxes with 2048 particles, only one out of eight packings is found to assemble. In addition, the degenerate quasicrystal reported previously for triangular bipyramids without truncation [{http://prl.aps.org/abstract/PRL/v107/i21/e215702}{Haji-Akbari \emph{et al.}, \emph{Phys. Rev. Lett.} \textbf{107}: 215702 (2011)}] assembles for truncations as high as 0.45. The self-assembly propensities for the structures formed in the thermodynamic limit are explained using the isoperimetric quotient of the particles and the coordination number in the disordered fluid and in the assembled structure.

cond-mat.stat-mech↗

arXiv2013

Model for the catalytic oxidation of CO, including gas-phase impurities and CO desorption

We present results of kinetic Monte Carlo simulations of a modified Ziff-Gulari-Barshad model for the reaction CO+O --> CO_2 on a catalytic surface. Our model includes impurities in the gas phase, CO desorption, and a modification known to eliminate the unphysical O poisoned phase. The impurities can adsorb and desorb on the surface, but otherwise remain inert. In a previous work that did not include CO desorption [G. M. Buendia and P. A. Rikvold, Phys. Rev. E, 85 031143 (2012)], we found that the impurities have very distinctive effects on the phase diagram and greatly diminish the reactivity of the system. If the impurities do not desorb, once the system reaches a stationary state, the CO_2 production disappears. When the impurities are allowed to desorb, there are regions where the CO_2 reaction window reappears, although greatly reduced. Following experimental evidence that indicates that temperature effects are crucial in many catalytic processes, here we further analyze these effects by including a CO desorption rate. We find that the CO desorption has the effect to smooth the transition between the reactive and the CO rich phase, and most importantly it can counteract the negative effects of the presence of impurities by widening the reactive window such that now the system remains catalytically active in the whole range of CO pressures.

cond-mat.mtrl-sci↗

arXiv2013

Re-entrant Disordered Phase in a System of Repulsive Rods on a Bethe-like Lattice

We solve exactly a model of monodispersed rigid rods of length $k$ with repulsive interactions on the random locally tree like layered lattice. For $k\geq 4$ we show that with increasing density, the system undergoes two phase transitions: first from a low density disordered phase to an intermediate density nematic phase and second from the nematic phase to a high density re-entrant disordered phase. When the coordination number is $4$, both the phase transitions are continuous and in the mean field Ising universality class. For even coordination number larger than $4$, the first transition is discontinuous while the nature of the second transition depends on the rod length $k$ and the interaction parameters.

cond-mat.stat-mech↗

arXiv2013

Uniform asymptotic approximation of diffusion to a small target

The problem of the time required for a diffusing molecule, within a large bounded domain, to first locate a small target is prevalent in biological modeling. Here we study this problem for a small spherical target. We develop uniform in time asymptotic expansions in the target radius of the solution to the corresponding diffusion equation. Our approach is based on combining short-time expansions using pseudo-potential approximations with long-time expansions based on first eigenvalue and eigenfunction approximations. These expansions allow the calculation of corresponding expansions of the first passage time density for the diffusing molecule to find the target. We demonstrate the accuracy of our method in approximating the first passage time density and related statistics for the spherically symmetric problem where the domain is a large concentric sphere about a small target centered at the origin.

physics.bio-ph↗

arXiv2013

Gaussian field theory for the Brownian motion of a solvated particle

An alternative derivation of Brownian motion is presented. Instead of supplementing the linearized Navier-Stokes equation with a fluctuating force, we directly assume a Gaussian action functional for solvent velocity fluctuations. Solvating a particle amounts to expelling the solvent and prescribing a boundary condition to the solvent on the interface that is shared with the solute. We study the dynamical effects of this boundary condition on the solvent and derive explicit expressions for the solvent mean flow and velocity correlations. Moreover, we show that the probability to observe solvent velocity fluctuations that are compatible with the boundary condition reproduces random Brownian motion of the solvated particle. We explicitly calculate the translational and rotational diffusion coefficients of a spherical particle using the presented formalism.

cond-mat.stat-mech↗

arXiv2013

Manipulation of extreme events on scale-free networks

Extreme events taking place on networks are not uncommon. We show that it is possible to manipulate the extreme events occurrence probabilities and its distribution over the nodes on scale-free networks by tuning the nodal capacity. This can be used to reduce the number of extreme events occurrences on a network. However monotonic nodal capacity enhancements, beyond a point, do not lead to any substantial reduction in the number of extreme events. We point out the practical implication of this result for network design in the context of reducing extreme events occurrences.

cond-mat.stat-mech↗

arXiv2013

Dynamics of Influence on Hierarchical Structures

Dichotomous spin dynamics on a pyramidal hierarchical structure (the Bethe lattice) are studied. The system embodies a number of \emph{classes}, where a class comprises of nodes that are equidistant from the root (head node). Weighted links exist between nodes from the same and different classes. The spin (hereafter, \emph{state}) of the head node is fixed. We solve for the dynamics of the system for different boundary conditions. We find necessary conditions so that the classes eventually repudiate or acquiesce in the state imposed by the head node. The results indicate that to reach unanimity across the hierarchy, it suffices that the bottom-most class adopts the same state as the head node. Then the rest of the hierarchy will inevitably comply. This also sheds light on the importance of mass media as a means of synchronization between the top-most and bottom-most classes. Surprisingly, in the case of discord between the head node and the bottom-most classes, the average state over all nodes inclines towards that of the bottom-most class regardless of the link weights and intra-class configurations. Hence the role of the bottom-most class is signified.

physics.soc-ph↗

arXiv2013

Commutative law for products of infinitely large isotropic random matrices

Ensembles of isotropic random matrices are defined by the invariance of the probability measure under the left (and right) multiplication by an arbitrary unitary matrix. We show that the multiplication of large isotropic random matrices is spectrally commutative and self-averaging in the limit of infinite matrix size $N \rightarrow \infty$. The notion of spectral commutativity means that the eigenvalue density of a product ABC... of such matrices is independent of the order of matrix multiplication, for example the matrix ABCD has the same eigenvalue density as ADCB. In turn, the notion of self-averaging means that the product of n independent but identically distributed random matrices, which we symbolically denote by AAA..., has the same eigenvalue density as the corresponding power A^n of a single matrix drawn from the underlying matrix ensemble. For example, the eigenvalue density of ABCCABC is the same as of A^2B^2C^3. We also discuss the singular behavior of the eigenvalue and singular value densities of isotropic matrices and their products for small eigenvalues $λ\rightarrow 0$. We show that the singularities at the origin of the eigenvalue density and of the singular value density are in one-to-one correspondence in the limit $N \rightarrow \infty$: the eigenvalue density of an isotropic random matrix has a power law singularity at the origin $\sim |λ|^{-s}$ with a power $s \in (0,2)$ when and only when the density of its singular values has a power law singularity $\sim λ^{-σ}$ with a power $σ= s/(4-s)$. These results are obtained analytically in the limit $N \rightarrow \infty$. We supplement these results with numerical simulations for large but finite N and discuss finite size effects for the most common ensembles of isotropic random matrices.

cond-mat.stat-mech↗

arXiv2013

Molecular theory of anomalous diffusion

We present a Master Equation formulation based on a Markovian random walk model that exhibits sub-diffusion, classical diffusion and super-diffusion as a function of a single parameter. The non-classical diffusive behavior is generated by allowing for interactions between a population of walkers. At the macroscopic level, this gives rise to a nonlinear Fokker-Planck equation. The diffusive behavior is reflected not only in the mean-squared displacement ($ \sim t^γ$ with $0 <γ\leq 1.5$) but also in the existence of self-similar scaling solutions of the Fokker-Planck equation. We give a physical interpretation of sub- and super-diffusion in terms of the attractive and repulsive interactions between the diffusing particles and we discuss analytically the limiting values of the exponent $γ$. Simulations based on the Master Equation are shown to be in agreement with the analytical solutions of the nonlinear Fokker-Planck equation in all three diffusion regimes.

cond-mat.stat-mech↗

arXiv2013

Typical and rare fluctuations in nonlinear driven diffusive systems with dissipation

We consider fluctuations of the dissipated energy in nonlinear driven diffusive systems subject to bulk dissipation and boundary driving. With this aim, we extend the recently-introduced macroscopic fluctuation theory to nonlinear driven dissipative media, starting from the fluctuating hydrodynamic equations describing the system mesoscopic evolution. Interestingly, the action associated to a path in mesoscopic phase-space, from which large-deviation functions for macroscopic observables can be derived, has the same simple form as in non-dissipative systems. This is a consequence of the quasi-elasticity of microscopic dynamics, required in order to have a nontrivial competition between diffusion and dissipation at the mesoscale. Euler-Lagrange equations for the optimal density and current fields that sustain an arbitrary dissipation fluctuation are also derived. A perturbative solution thereof shows that the probability distribution of small fluctuations is always gaussian, as expected from the central limit theorem. On the other hand, strong separation from the gaussian behavior is observed for large fluctuations, with a distribution which shows no negative branch, thus violating the Gallavotti-Cohen fluctuation theorem as expected from the irreversibility of the dynamics. The dissipation large-deviation function exhibits simple and general scaling forms for weakly and strongly dissipative systems, with large fluctuations favored in the former case but heavily supressed in the latter. (...) [see complete abstract by downloading the paper]

cond-mat.stat-mech↗

arXiv2013

Momentum distribution functions in ensembles: the inequivalence of microcannonical and canonical ensembles in a finite ultracold system

It is demonstrated that in many thermodynamic textbooks the equivalence of the different ensembles is achieved in the thermodynamic limit. In this present work we remark the inequivalence of microcannonical and canonical ensembles in a finite ultracold system at low energies. We calculate the microcanonical momentum distribution function (MDF) in a system of identical fermions (bosons). We find that, the microcanonical MDF deviates from the canonical one, which is the Fermi-Dirac (Bose-Einstein) function, in a finite system at low energies where the single-particle density of states and its inverse are finite.

cond-mat.stat-mech↗

arXiv2013

Critical manifold of globally coupled overdamped anharmonic oscillators driven by additive Gaussian white noise

We prove for an infinite array of globally coupled overdamped anharmonic oscillators subject to additive Gaussian white noise the existence of a well-behaved critical manifold in the parameter space which separates a symmetric phase from a symmetry broken phase. Given two of the system parameters there is an unique critical value of the third. The proof exploits that the critical control parameter a_c is bounded by its limit values for weak and for strong noise. In these limits the mechanism of symmetry breaking differs. For weak noise the distribution is Gaussian and the symmetry is broken as the whole distribution is shifted in either the positive or the negative direction. For strong noise there is a symmetric double-peak distribution and the symmetry is broken as the weights of the peaks become different. We derive an ordinary differential equation whose solution describes the critical manifold. Using a series ansatz to solve this differential equation we determine the critical manifold for weak and for strong noise and compare it to numerical results. We derive analytic expressions for the order parameter and the susceptibility close to the critical manifold.

cond-mat.stat-mech↗

arXiv2013

Renormalization group calculations for wetting transitions of infinite order and continuously varying order. I. Local interface Hamiltonian approach

We study the effect of thermal fluctuations on the wetting phase transitions of infinite order and of continuously varying order, recently discovered within a mean-field density-functional model for three-phase equilibria in systems with short-range forces and a two-component order parameter. Using linear functional renormalization group (RG) calculations within a local interface Hamiltonian approach, we show that the infinite-order transitions are robust. The exponential singularity (implying $2-α_s = \infty$) of the surface free energy excess at infinite-order wetting as well as the precise algebraic divergence (with $β_s = -1$) of the wetting layer thickness are not modified as long as $ω< 2$, with $ω$ the dimensionless wetting parameter that measures the strength of thermal fluctuations. The interface width diverges algebraically and universally (with $ν_{\perp} = 1/2$). In contrast, the non-universal critical wetting transitions of finite but continuously varying order are modified when thermal fluctuations are taken into account, in line with predictions from earlier calculations on similar models displaying weak, intermediate and strong fluctuation regimes.

cond-mat.stat-mech↗

arXiv2013

Bose-Einstein condensation of light: General theory

A theory of Bose-Einstein condensation of light in a dye-filled optical microcavity is presented. The theory is based on the hierarchical maximum entropy principle and allows one to investigate the fluctuating behavior of the photon gas in the microcavity for all numbers of photons, dye molecules, and excitations at all temperatures, including the whole critical region. The master equation describing the interaction between photons and dye molecules in the microcavity is derived and the equivalence between the hierarchical maximum entropy principle and the master equation approach is shown. The cases of a fixed mean total photon number and a fixed total excitation number are considered, and a much sharper, nonparabolic onset of a macroscopic Bose-Einstein condensation of light in the latter case is demonstrated. The theory does not use the grand canonical approximation, takes into account the photon polarization degeneracy, and exactly describes the microscopic, mesoscopic, and macroscopic Bose-Einstein condensation of light. Under certain conditions, it predicts sub-Poissonian statistics of the photon condensate and the polarized photon condensate, and a universal relation takes place between the degrees of second-order coherence for these condensates. In the macroscopic case, there appear a sharp jump in the degrees of second-order coherence, a sharp jump and kink in the reduced standard deviations of the fluctuating numbers of photons in the polarized and whole condensates, and a sharp peak, a cusp, of the Mandel parameter for the whole condensate in the critical region. The possibility of nonclassical light generation in the microcavity with the photon Bose-Einstein condensate is predicted.

cond-mat.quant-gas↗

arXiv2013

From local force-flux relationships to internal dissipations and their impact on heat engine performance: The illustrative case of a thermoelectric generator

We present an in-depth analysis of the sometimes understated role of the principle of energy conservation in linear irreversible thermodynamics. Our case study is that of a thermoelectric generator (TEG), which is a heat engine of choice in irreversible thermodynamics, owing to the coupling between the electrical and heat fluxes. We show why Onsager's reciprocal relations must be considered locally and how internal dissipative processes emerge from the extension of these relations to a global scale: the linear behavior of a heat engine at the local scale is associated with a dissipation process that must partake in the global energy balance. We discuss the consequences of internal dissipations on the so-called efficiency at maximum power, in the light of our comparative analyses of exoreversibility and endoreversibility on the one hand, and of two classes of heat engines, autonomous and periodically-driven, on the other hand. Finally, basing our analysis on energy conservation, we also discuss recent works which claim the possibility to overcome the traditional boundaries on efficiency imposed by finite-time thermodynamics in thermoelectric systems with broken time-reversal symmetry; this we do by introducing a "thermal" thermopower and an "electrical" thermopower which permits an analysis of the thermoelectric response of the TEG considering a possible dissymmetry between the electrical/thermal and the thermal/electrical couplings.

cond-mat.stat-mech↗

arXiv2013

Inexistence of equilibrium states at absolute negative temperatures

We show that states of macroscopic systems with purported absolute negative temperatures are not stable under small, yet arbitrary, perturbations. We prove the previous statement using the fact that, in equilibrium, the entropy takes its maximum value. We discuss that, while Ramsey theoretical reformulation of the Second Law for systems with negative temperatures is logically correct, it must be a priori assumed that those states are in thermodynamic equilibrium. Since we argue that those states cannot occur, reversible processes are impossible and, thus, Ramsey identification of negative absolute temperatures is untenable.

cond-mat.stat-mech↗