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arXiv · 0809.5257

Chemical functionalization of graphene

D. W. Boukhvalov·M. I. Katsnelson
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Abstract

Experimental and theoretical results on chemical functionalization of graphene are reviewed. Using hydrogenated graphene as a model system, general principles of the chemical functionalization are formulated and discussed. It is shown that, as a rule, 100% coverage of graphene by complex functional groups (in contrast with hydrogen and fluorine) is unreachable. A possible destruction of graphene nanoribbons by fluorine is considered. The functionalization of infinite graphene and graphene nanoribbons by oxygen and by hydrofluoric acid is simulated step by step.

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D. W. Boukhvalov, M. I. Katsnelson. 2009-01-05. Chemical functionalization of graphene. https://arxiv.org/abs/0809.5257

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