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arXiv · 1002.0962

Structure and Correlation Effects in Semiconducting SrTiO$_{3}$

Young Jun Chang·Aaron Bostwick·Yong Su Kim·Karsten Horn·Eli Rotenberg
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Abstract

We have investigated the effects of structure change and electron correlation on SrTiO$_{3}$ single crystals using angle-resolved photoemission spectroscopy. We show that the cubic to tetragonal phase transition at 105$^\circ$K is manifested by a charge transfer from in-plane ($d_{yz}$ and $d_{zx}$) bands to out-of-plane ($d_{xy}$) band, which is opposite to the theoretical predictions. Along this second-order phase transition, we find a smooth evolution of the quasiparticle strength and effective masses. The in-plane band exhibits a peak-dip-hump lineshape, indicating a high degree of correlation on a relatively large (170 meV) energy scale, which is attributed to the polaron formation.

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Young Jun Chang, Aaron Bostwick, Yong Su Kim, Karsten Horn, Eli Rotenberg. 2010-02-04. Structure and Correlation Effects in Semiconducting SrTiO$_{3}$. https://doi.org/10.1103/physrevb.81.235109

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