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arXiv · 1002.4726

Lattice structure and magnetization of LaCoO3 thin films

A. D. Rata·A. Herklotz·L. Schultz·K. Doerr
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Abstract

We investigate the structure and magnetic properties of thin films of the LaCoO$_{3}$ compound. Thin films are deposited by pulsed laser deposition on various substrates in order to tune the strain from compressive to tensile. Single-phase (001) oriented LaCoO$_{3}$ layers were grown on all substrates despite large misfits. The tetragonal distortion of the films covers a wide range from -2% to 2.8%. Our LaCoO$_{3}$ films are ferromagnetic with Curie temperature around 85 K, contrary to the bulk. The total magnetic moment is below $1\mu_{B}$/Co$^{3+}$, a value relatively small for an exited spin-state of the Co$^{3+}$ ions, but comparable to values reported in literature. A correlation of strain states and magnetic moment of Co$^{3+}$ ions in LaCoO$_{3}$ thin films is observed.

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A. D. Rata, A. Herklotz, L. Schultz, K. Doerr. 2010-02-25. Lattice structure and magnetization of LaCoO3 thin films. https://doi.org/10.1140/epjb/e2010-00203-6

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