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arXiv · 1308.1800

Orientation Sensitive Nonlinear Growth of Graphene: A Geometry-determined Epitaxial Growth Mechanism

Huijun Jiang·Ping Wu·Zhonghuai Hou·Zhenyu Li·Jinlong Yang
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Abstract

Although the corresponding carbon-metal interactions can be very different, a similar nonlinear growth behavior of graphene has been observed for different metal substrates. To understand this interesting experimental observation, a multiscale $\lq\lq$standing-on-the-front" kinetic Monte Carlo study is performed. An extraordinary robust geometry effect is identified, which solely determines the growth kinetics and makes the details of carbon-metal interaction not relevant at all. Based on such a geometry-determined mechanism, epitaxial growth behavior of graphene can be easily predicted in many cases. As an example, an orientation-sensitive growth kinetics of graphene on Ir(111) surface has been studied. Our results demonstrate that lattice mismatch pattern at the atomic level plays an important role for macroscopic epitaxial growth.

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Huijun Jiang, Ping Wu, Zhonghuai Hou, Zhenyu Li, Jinlong Yang. 2013-08-08. Orientation Sensitive Nonlinear Growth of Graphene: A Geometry-determined Epitaxial Growth Mechanism. https://doi.org/10.1103/physrevb.88.054304

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