Polar and antipolar polymorphs of metastable perovskite BiFe0.5Sc0.5O3

D. D. Khalyavin; A. N. Salak; N. M. Olekhnovich; A. V. Pushkarev; Yu. V. Radyush; P. Manuel; I. P. Raevski; M. L. Zheludkevich; M. G. S. Ferreira

doi:10.1103/physrevb.89.174414

arXiv · 1403.4078

Polar and antipolar polymorphs of metastable perovskite BiFe0.5Sc0.5O3

D. D. Khalyavin·A. N. Salak·N. M. Olekhnovich·A. V. Pushkarev·Yu. V. Radyush·P. Manuel·I. P. Raevski·M. L. Zheludkevich·M. G. S. Ferreira

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Abstract

A metastable perovskite BiFe0.5Sc0.5O3 synthesized under high-pressure (6 GPa) and high- temperature (1500 K) conditions was obtained in two different polymorphs, antipolar Pnma and polar Ima2, through an irreversible behaviour under a heating/cooling thermal cycling. The Ima2 phase represents an original type of a canted ferroelectric structure where Bi3+ cations exhibit both polar and antipolar displacements along the orthogonal [110]p and [1-10]p pseudocubic directions, respectively, and are combined with antiphase octahedral tilting about the polar axis. Both the Pnma and Ima2 structural modifications exhibit a long-range antiferromagnetic ordering with a weak-ferromagnetic component below TN ~ 220 K. Analysis of the coupling between the dipole, magnetic and elastic order parameters based on a general phenomenological approach revealed that the weak-ferromagnetism in both phases is mainly caused by the presence of the antiphase octahe- dral tilting whose axial nature directly represents the relevant part of Dzyaloshinskii vector. The magnetoelectric contribution to the spontaneous magnetization allowed in the polar Ima2 phase is described by a fifth-degree free-energy invariant and is expected to be small.

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D. D. Khalyavin, A. N. Salak, N. M. Olekhnovich, A. V. Pushkarev, Yu. V. Radyush, P. Manuel, I. P. Raevski, M. L. Zheludkevich, M. G. S. Ferreira. 2014-03-17. Polar and antipolar polymorphs of metastable perovskite BiFe0.5Sc0.5O3. https://doi.org/10.1103/physrevb.89.174414

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