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arXiv · 1404.6062

Emerging quasi-0D states at vanishing total entropy of the 1D hard sphere system: a coarse-grained similarity to the car parking problem

Abstract

A coarse-grained system of one-dimensional (1D) hard spheres (HSs) is created using the Delaunay tessellation, which enables one to define the quasi-0D state. It is found from comparing the quasi-0D and 1D free energy densities that a frozen state due to the emergence of quasi-0D HSs is thermodynamically more favorable than fluidity with a large-scale heterogeneity above crossover volume fraction of $ϕ_c=e/(1+e)=0.731\cdots$, at which the total entropy of the 1D state vanishes. The Delaunay-based lattice mapping further provides a similarity between the dense HS system above $ϕ_c$ and the jamming limit in the car parking problem.

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BibTeXRIS

Hiroshi Frusawa. 2014-04-24. Emerging quasi-0D states at vanishing total entropy of the 1D hard sphere system: a coarse-grained similarity to the car parking problem. https://doi.org/10.1016/j.physleta.2014.04.066

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