Multicomponent solution solidification with arrested phase separation model for liquid-to-glass transition

Vladimir Belostotsky

Home/Archive/arXiv

arXiv · 1409.2906

Multicomponent solution solidification with arrested phase separation model for liquid-to-glass transition

Vladimir Belostotsky

View original source ↗Read source document ↗Export metadata ↓

Abstract

Due to nonuniform aggregation in liquid state, from the thermodynamic point of view any glass-forming liquid in the vicinity of the liquid-to-solid phase transition temperature, irrespective of its actual chemical composition, shall be described in terms of a complex multicomponent solution whose comprised of the same chemical elements components have characteristic atomic arrangement deviating to various extent from the thermodynamic ground state with respect to the size, shape, density, structure, and stoichiometry. Therefore, glass transition appears to be a process of non-equilibrium solidification of multicomponent solution upon its rapid cooling. The essential feature of this process is that the attempts of the liquid and solid phases of the solidifying solution to separate out are largely arrested due to quenching. Thus, the solidification occurs in the absence of solid-liquid interface, so the substance in the liquid-to-glass transition region is observed behaving like fluid with rapidly growing viscosity that reflects the formation of mechanically rigid and stable bound configurations. It is shown that glass transition shall be classified as phase transition in multicomponent solutions and not a standalone phenomenon.

Explore related subjects

cond-mat.dis-nn

Keep this discovery

Explore connections, maps & timelines

BibTeX RIS

Vladimir Belostotsky. 2021-03-17. Multicomponent solution solidification with arrested phase separation model for liquid-to-glass transition. https://arxiv.org/abs/1409.2906

Cite the original work for its findings. Save a collection to share your selection of sources.

KEEP EXPLORING

Related papers

arXiv2026

The critical slowing down in training diffusion models

Computational sampling has been central to the sciences since the mid-20th century. While machine-learning-based approaches have recently enabled major advances, their behavior remains poorly understood, with limited theoretical control over when and why they succeed. Here we provide such insight for diffusion models---a class of generative schemes highly effective in practice---by analyzing their application to the $O(n)$ model of statistical field theory in the Gaussian limit $n \to \infty$. In this analytically tractable setting, we show that training a score model with a one-layer network architecture matching the exact solution exhibits a form of critical slowing down in parameter learning. This slowing down also impacts the generation process, indicating that the well-known difficulties of sampling near criticality persist even for learned generative models. To overcome this bottleneck, we consider the power of architectural depth. We find that using a two-layer architecture drastically reduces the critical slowing down, with the training time scaling logarithmically rather than quadratically with system size. Using a Fourier implementation of the architecture, we further show that this acceleration in training time can be achieved without drastically increasing operational complexity. Taken together, these results demonstrate that diffusion models can overcome the critical slowing down through appropriate architectural design, and establish a controlled framework for understanding and improving learned sampling methods in statistical physics and beyond.

cond-mat.dis-nn↗

arXiv2026

Switching diffusivity selects Pareto tail exponent in random growth with redistribution

Random multiplicative growth with redistribution generates stationary Pareto wealth tails in the Bouchaud-Mézard model, but assumes a fixed multiplicative noise intensity. This is restrictive for physical and financial growth processes, where volatility (diffusivity) is often fluctuating. We replace the constant noise intensity by a switching diffusivity and ask how these fluctuations select the Pareto stationary tail. For a geometric Brownian motion with switching diffusivity, the long-time Gaussian limit holds when the redraw law has finite mean and variance. The asymptotic variance retains a contribution from diffusivity persistence. With redistribution and a general redraw law, the stationary large-wealth problem is characterized by a spectral condition for admissible algebraic modes. For a two-state diffusivity, an exact tail analysis gives a Pareto exponent interpolating between the high-diffusivity slow-refresh limit and the mean-diffusivity fast-refresh Bouchaud-Mézard limit.

cond-mat.dis-nn↗

arXiv2026

Signatures of Nonergodicity in Sparse Random Matrices

The prevalence of sparsity in the Fock space graph of interacting many-body systems motivates an investigation into the spectral statistics of sparse random matrices with on-site disorder. We numerically determine the delocalization-localization transition in the ground state as a function of the sparsity. The short-range energy correlation in the bulk indicates that the Anderson transition at infinite temperature occurs at the critical percolation limit of the sparse graph. By analytically deriving the energy moments and calculating the shifted kurtosis, we show that the critical sparsity threshold matches the Anderson transition. Furthermore, long-range energy correlations in the bulk spectrum reveal a Thouless energy scale, suggesting a broad nonergodic regime within the delocalized phase.

cond-mat.dis-nn↗