Self-Assembly of Patchy Colloidal Dumbbells

Abstract

We employ Monte Carlo simulations to investigate the self-assembly of patchy colloidal dumbbells interacting via a modified Kern-Frenkel potential by probing the system concentration and dumbbell shape. We consider dumbbells consisting of one attractive sphere with diameter $σ_1$ and one repulsive sphere with diameter $σ_2$ and center-to-center distance $d$ between the spheres. For three different size ratios, we study the self-assembled structures for different separations $l = 2d/(σ_1+σ_2)$ between the two spheres. In particular, we focus on structures that can be assembled from the homogeneous fluid, as these might be of interest in experiments. We use cluster order parameters to classify the shape of the formed structures. When the size of the spheres is almost equal, $q=σ_2/σ_1=1.035$, we find that, upon increasing $l$, spherical micelles are transformed to elongated micelles and finally to vesicles and bilayers. For size ratio $q=1.25$ we observe a continuously tunable transition from spherical to elongated micelles upon increasing the sphere separation. For size ratio $q=0.95$ we find bilayers and vesicles, plus faceted polyhedra and liquid droplets. Our results identify key parameters to create colloidal vesicles with attractive dumbbells in experiments.