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arXiv · 1505.06124

Synthesis of monoclinic IrTe2 under high pressure and its physical properties

X. Li·J. -Q. Yan·D. J. Singh·J. B. Goodenough·J. -S. Zhou
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Abstract

In a pressure-temperature (P-T) diagram for synthesizing IrTe2 compounds, the well-studied trigonal (H) phase with the CdI2-type structure is stable at low pressures. The superconducting cubic (C) phase can be synthesized under higher temperatures and pressures. A rhombohedral phase with the crystal structure similar to the C phase can be made at ambient pressure; but the phase contains a high concentration of Ir deficiency. In this paper, we report that a rarely studied monoclinic (M) phase can be stabilized in narrow ranges of pressure and temperature in this P-T diagram. The peculiar crystal structure of the M-IrTe2 eliminates the tendency to form Ir-Ir dimers found in the H phase. The M phase has been fully characterized by structural determination and measurements of electrical resistivity, thermoelectric power, DC magnetization, and specific heat. These physical properties have been compared with those in the H and C phases of Ir1-xTe2. Moreover, magnetic and transport properties and specific heat of the M-IrTe2 can be fully justified by calculations with the density-functional theory presented in this paper.

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X. Li, J. -Q. Yan, D. J. Singh, J. B. Goodenough, J. -S. Zhou. 2015-05-22. Synthesis of monoclinic IrTe2 under high pressure and its physical properties. https://doi.org/10.1103/physrevb.92.155118

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