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arXiv · 1607.05914

Broad-band dielectric response of BTZ-BCT piezoceramics: soft and central mode behaviour

S. Kamba·E. Simon·V. Skoromets·V. Bovtun·M. Kempa·J. Pokorny·M. Savinov·J. Koruza·B. Malic
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Abstract

Dielectric properties of BTZ-BCT ceramics were probed in the frequency range from 10 Hz to 100 THz in a broad temperature range (10-900 K). Polar soft phonon observed in infrared spectra softens with cooling, however below 500 K its frequency becomes temperature independent. Simultaneously, a central mode activates in terahertz and microwave spectra; and it actually drives the ferroelectric phase transitions. Consequently, the phase transition strongly resemble a crossover between the dispacive and order-disorder type. The central mode vanishes below 200 K. The dielectric relaxation in the radiofrequency and microwave range anomalously broadens on cooling below T$_{C1}$ resulting in the nearly frequency independent dielectric loss bleow 200 K. This broadening comes from a broad frequency distribution of ferroelectric domain wall vibrations. Raman spectra reveal new phonons below 400 K, i.e. already 15 K above T$_{C1}$. Several weak modes are detected in the paraelectric phase up to 500 K in the Raman spectra. Activation of these modes is ascribed to the presence of polar nanoclusters in the material.

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S. Kamba, E. Simon, V. Skoromets, V. Bovtun, M. Kempa, J. Pokorny, M. Savinov, J. Koruza, B. Malic. 2016-07-20. Broad-band dielectric response of BTZ-BCT piezoceramics: soft and central mode behaviour. https://doi.org/10.1080/01411594.2016.1199800

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