Search arXiv⌕ Search
Home/Archive/arXiv

arXiv · 1702.00024

Optimal design of a model energy conversion device

Lincoln Collins·Kaushik Bhattacharya
View original source ↗Read source document ↗Export metadata ↓

Abstract

Fuel cells, batteries, thermochemical and other energy conversion devices involve the transport of a number of (electro-)chemical species through distinct materials so that they can meet and react at specified multi-material interfaces. Therefore, morphology or arrangement of these different materials can be critical in the performance of an energy conversion device. In this paper, we study a model problem motivated by a solar-driven thermochemical conversion device that splits water into hydrogen and oxygen. We formulate the problem as a system of coupled multi-material reaction-diffusion equations where each species diffuses selectively through a given material and where the reaction occurs at multi-material interfaces. We express the problem of optimal design of the material arrangement as a saddle point problem and obtain an effective functional which shows that regions with very fine phase mixtures of the material arise naturally. To explore this further, we introduce a phase-field formulation of the optimal design problem, and numerically study selected examples.

Explore related subjects

math.APcond-mat.mtrl-scimath.OC

Keep this discovery

Explore connections, maps & timelines

BibTeXRIS

Lincoln Collins, Kaushik Bhattacharya. 2017-01-31. Optimal design of a model energy conversion device. https://arxiv.org/abs/1702.00024

Cite the original work for its findings. Save a collection to share your selection of sources.

KEEP EXPLORING

Related papers

arXiv2026

Blow-Up Dynamics for the $L^2$ critical case of the $2$D Zakharov-Kuznetsov equation

We study blow-up dynamics for the $L^2$-critical cubic Zakharov--Kuznetsov equation in two dimensions, \[ \partial_tu+\partial_{x_1}(Δu+u^3)=0 \qquad\text{on }\mathbb R^2. \] For a class of localized $H^1$ perturbations of the ground state $Q$, we establish a trichotomy near the soliton manifold: exit from a small $L^2$-tube, global asymptotic stability, or finite-time blow-up. In the stable blow-up regime, the solution concentrates a single bubble and \[ λ(t)\sim \ell_0(T-t)^{1/(3-c)}, \] where $\ell_0>0$ depends on the initial datum and $c\in(1,2)$ is an explicit constant determined by the transverse tail of the first-order approximate profile. Consequently, \[ \|\nabla u(t)\|_{L^2} \sim \frac{\|\nabla Q\|_{L^2}} {\ell_0(T-t)^{1/(3-c)}}. \] After subtraction of the concentrating soliton, the radiation converges strongly in $L^p(\mathbb R^2)$ for every $2\leq p<\infty$ to a common nonzero profile $u^*$, while \[ u^*\notin H^s(\mathbb R^2) \qquad\text{for every }s\geq\frac c2. \] The stable blow-up branch is open in the relative $H^1$ topology of the localized class. Finally, every non-soliton datum in this class with non-positive energy blows up in finite time. Interval-arithmetic computer-assisted proofs certify the numerical inputs to the virial coercivity argument. They also yield a rigorous enclosure of $c$, justifying the polynomial moment of order $21$ imposed on the initial data.

math.AP↗
arXiv2026

Propagation of wave packets close to conical intersections

In this paper, we study the propagation of wave packets close to conical intersections with respect to a system of two Schr{ö}dinger equations presenting a codimension 2 crossing. We focus on the dynamics that occur when the wave packets pass through an area close to the crossing, and our main results provide an explicit formula for the outgoing wave packet in terms of the incoming one, with a complete description of its phase and of the classical trajectories it follows, including a drift.

math.AP↗
arXiv2026

A Volterra Calculus for Lie Groupoids

A pseudodifferential Volterra calculus for inverting parabolic differential equations on Lie groupoids is introduced. This enables the study of fundamental solutions of various cases of heat flows on singular manifolds with corners with non-resonant boundary indicial symbols, such as the $b$-manifolds, as well as other geometric bisection covariant heat flows. We also establish the short time asymptotic expansion for the heat kernel of a positive, elliptic differential operator on a Lie groupoid that acts on suitable Sobolev Hilbert modules and is positive definite with respect to the appropriate $L^2$ inner product.

math.AP↗