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arXiv · 1704.01270

Cubic lead perovskite PbMoO3 with anomalous metallic behavior

Hiroshi Takatsu·Olivier Hernandez·Wataru Yoshimune·Carmelo Prestipino·Takafumi Yamamoto·Cedric Tassel·Yoji Kobayashi·Dmitry Batuk·Yuki Shibata·Artem M. Abakumov·Craig M. Brown·Hiroshi Kageyama
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Abstract

A previously unreported Pb-based perovskite PbMoO$_3$ is obtained by high-pressure and high-temperature synthesis. This material crystallizes in the $Pm\bar{3}m$ cubic structure at room temperature, making it distinct from typical Pb-based perovskite oxides with a structural distortion. PbMoO$_3$ exhibits a metallic behavior down to 0.1 K with an unusual $T$-sub linear dependence of the electrical resistivity. Moreover, a large specific heat is observed at low temperatures accompanied by a peak in $C_P/T^3$ around 10 K, in marked contrast to the isostructural metallic system SrMoO$_3$. These transport and thermal properties for PbMoO$_3$, taking into account anomalously large Pb atomic displacements detected through diffraction experiments, are attributed to a low-energy vibrational mode, associated with incoherent off-centering of lone pair Pb$^{2+}$ cations. We discuss the unusual behavior of the electrical resistivity in terms of a polaron-like conduction, mediated by the strong coupling between conduction electrons and optical phonons of the local low-energy vibrational mode.

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Hiroshi Takatsu, Olivier Hernandez, Wataru Yoshimune, Carmelo Prestipino, Takafumi Yamamoto, Cedric Tassel, Yoji Kobayashi, Dmitry Batuk, Yuki Shibata, Artem M. Abakumov, Craig M. Brown, Hiroshi Kageyama. 2017-04-05. Cubic lead perovskite PbMoO3 with anomalous metallic behavior. https://doi.org/10.1103/physrevb.95.155105

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