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arXiv · 1804.08696

Percolative Mechanism of Aging in Zirconia-Containing Ceramics for Medical Applications

Carlos Pecharromán·José F. Bartolomé·Joaquin Requena·José S. Moya·Sylvain Deville·Jérôme Chevalier·Gilbert Fantozzi·Ramon Torrecillas
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Abstract

Recently, several episodes of fracture of zirconia ceramic femoral heads of total hip prostheses have alarmed the medical and scientific community regarding aging problems in zirconia prostheses. Such fractures cause immediate local tissue reactions, which require urgent medical intervention to prevent further complications. As a result, it has been promoted that yttria-stabilized zirconia (Y-TZP) hip prostheses be substituted by alumina and alumina/Y-TZP ceramics. In the present investigation, we have found an upper limit of Y-TZP concentration in alumina/Y-TZP composites (16 vol.%) to avoid future aging problems. This limit coincides with the percolation threshold measured by infrared (IR) reflectance in a series of alumina/Y-TZP composites.

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Carlos Pecharromán, José F. Bartolomé, Joaquin Requena, José S. Moya, Sylvain Deville, Jérôme Chevalier, Gilbert Fantozzi, Ramon Torrecillas. 2018-03-29. Percolative Mechanism of Aging in Zirconia-Containing Ceramics for Medical Applications. https://doi.org/10.1002/adma.200390117

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