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arXiv · 1902.05700

Enhancing CdTe Solar Cell Performance by Reducing the "Ideal" Bandgap of CdTe through CdTe1-xSex Alloying

Jingxiu Yang·Su-Huai Wei
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Abstract

CdTe is one of the leading materials for low cost, high efficiency thin-film solar cells, because it has a high absorption coefficient and a nearly ideal band gap of 1.48 eV for solar cell according to the Shockley-Queisser limit. However, its solar to electricity power conversion efficiency (PCE) is hindered by the relatively low open circuit voltage (VOC) due to intrinsic defect related issues. Here, we propose the strategy of improving CdTe solar cell performance byr reducing the "ideal" band gap of CdTe to gain more short-circuit current from long-wavelength absorption without sacrificing much VOC. Alloying CdTe with CdSe seems to be the most appropriate approach to reduce the band gap because of the large optical bowing and relatively small lattice mismatch in this system, even though CdSe has larger band gap than CdTe. Using the first principle hybrid functional calculation, we find that the minimum band gap of the CdTe1-xSex alloy can be reduced from 1.48 eV at x=0 to 1.39 eV at x=0.32. We also show that the formation of the alloy can improve the defect property, for example, p-type doping of CdTe by CuCd can be greatly enhanced by the alloying effects.

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Jingxiu Yang, Su-Huai Wei. 2019-02-15. Enhancing CdTe Solar Cell Performance by Reducing the "Ideal" Bandgap of CdTe through CdTe1-xSex Alloying. https://doi.org/10.1088/1674-1056%2F28%2F8%2F086106

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