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arXiv · 1903.08411

Manifestation of dipole-induced disorder in self-assembly of ferroelectric and ferromagnetic nanocubes

Dmitry Zablotsky·Leonid L. Rusevich·Guntars Zvejnieks·Vladimir Kuzovkov·Eugene Kotomin
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Abstract

The colloidal processing of nearly monodisperse and highly crystalline single-domain ferroelectric or ferromagnetic nanocubes is a promising route to produce superlattice structures for integration into next-generation devices, whereas controlling the local behaviour of nanocrystals is imperative for fabricating highly-ordered assemblies. The current picture of nanoscale polarization in individual nanocrystals suggests a potential presence of a significant dipolar interaction, but its role in the condensation of nanocubes is unknown. We simulate the self-assembly of colloidal dipolar nanocubes under osmotic compression and perform the microstructural characterization of their densified ensembles. Our results indicate that the long-range positional and orientational correlations of perovskite nanocubes are highly sensitive to the presence of dipoles.

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Dmitry Zablotsky, Leonid L. Rusevich, Guntars Zvejnieks, Vladimir Kuzovkov, Eugene Kotomin. 2019-03-20. Manifestation of dipole-induced disorder in self-assembly of ferroelectric and ferromagnetic nanocubes. https://doi.org/10.1039/c9nr00708c

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