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arXiv · 1910.13711

Superconductivity in a Scandium Borocarbide with a Layered Crystal Structure

Hiroki Ninomiya·Kunihiko Oka·Izumi Hase·Kenji Kawashima·Hiroshi Fujihisa·Yoshito Gotoh·Shigeyuki Ishida·Hiraku Ogino·Akira Iyo·Yoshiyuki Yoshida·Hiroshi Eisaki
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Abstract

The discovery of nearly room-temperature superconductivity in superhydrides has motivated further materials research for conventional superconductors. To realize the moderately high critical temperature $(T_\mathrm{c})$ in materials containing light elements, we explored new superconducting phases in a scandium borocarbide system. Here, we report the observation of superconductivity in a new ternary Sc-B-C compound. The crystal structure, which was determined through a Rietveld analysis, belongs to tetragonal space group $P4/ncc$. By complementarily using the density functional theory calculations, a chemical formula of the compound was found to be expressed as Sc$_{20}$C$_{8-x}$B$_x$C$_{20}$($x=1\:\mathrm{or}\:2$). Interestingly, a small amount of B is essential to stabilize the present structure. Our experiments revealed the typical type-II superconductivity at $T_\mathrm{c}=7.7\:\mathrm{K}$. Additionally, we calculated the density of states within a first-principles approach and found that the contribution of the Sc-3d orbital was mainly responsible for the superconductivity.

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Hiroki Ninomiya, Kunihiko Oka, Izumi Hase, Kenji Kawashima, Hiroshi Fujihisa, Yoshito Gotoh, Shigeyuki Ishida, Hiraku Ogino, Akira Iyo, Yoshiyuki Yoshida, Hiroshi Eisaki. 2019-10-30. Superconductivity in a Scandium Borocarbide with a Layered Crystal Structure. https://doi.org/10.1021/acs.inorgchem.9b02709

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