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arXiv · 2001.10513

Vertically-oriented MoS$_2$ nanosheets for nonlinear optical devices

M. Bolhuis·J. Hernandez-Rueda·S. E. van Heijst·M. Tinoco Rivas·L. Kuipers·S. Conesa-Boj
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Abstract

Transition metal dichalcogenides such as MoS$_2$ represent promising candidates for building blocks of ultra-thin nanophotonic devices. For such applications, vertically-oriented MoS$_2$ (v-MoS$_2$) nanosheets could be advantageous as compared to conventional horizontal MoS$_2$ (h-MoS$_2$) given that their inherent broken symmetry would favor an enhanced nonlinear response. However, the current lack of a controllable and reproducible fabrication strategy for v-MoS$_2$ limits the exploration of this potential. Here we present a systematic study of the growth of v-MoS$_2$ nanosheets based on the sulfurization of a pre-deposited Mo-metal seed layer. We demonstrate that the sulfurization process at high temperatures is driven by the diffusion of Sulfur from the vapor-solid interface to the Mo seed layer. Furthermore, we verify an enhanced nonlinear response in the resulting v-MoS$_2$ nanostructures as compared to their horizontal counterparts. Our results represent a stepping stone towards the fabrication of low-dimensional TMD-based nanostructures for versatile nonlinear nanophotonic devices.

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M. Bolhuis, J. Hernandez-Rueda, S. E. van Heijst, M. Tinoco Rivas, L. Kuipers, S. Conesa-Boj. 2020-01-28. Vertically-oriented MoS$_2$ nanosheets for nonlinear optical devices. https://arxiv.org/abs/2001.10513

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