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arXiv · 2004.01146

Spinodal decomposition versus classical gamma-prime nucleation in a nickel-base superalloy powder: An in-situ neutron diffraction and atomic-scale analysis

David M Collins·Neil D'Souza·Chinnapat Panwisawas·Chrysanthi Papadaki·Geoff D West·Aleksander Kostka·Paraskevas Kontis
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Abstract

Contemporary powder-based polycrystalline nickel-base superalloys inherit microstructures and properties that are heavily determined by the thermo-mechanical treatments during processing. Here, the influence of a thermal exposure alone to an alloy powder is studied to elucidate the controlling formation mechanisms of the strengthening precipitates using a combination of atom probe tomography and in-situ neutron diffraction. The initial powder comprised a single-phase supersaturated gamma only; from this, the evolution of gamma-prime volume fraction and lattice misfit was assessed. The initial powder notably possessed elemental segregation of Cr and Co and elemental repulsion between Ni, Al and Ti with Cr; here proposed to be a precursor for subsequent gamma to gamma-prime phase transformations. Subsolvus heat treatments yielded a unimodal gamma-prime distribution, formed during heating, with evidence supporting its formation to be via spinodal decomposition. A supersolvus heat treatment led to the formation of this same gamma-prime population during heating, but dissolves as the temperature increases further. The gamma-prime then reprecipitates as a multimodal population during cooling, here forming by classical nucleation and growth. Atom probe characterisation provided intriguing precipitate characteristics, including clear differences in chemistry and microstructure, depending on whether the gamma-prime formed during heating or cooling.

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David M Collins, Neil D'Souza, Chinnapat Panwisawas, Chrysanthi Papadaki, Geoff D West, Aleksander Kostka, Paraskevas Kontis. 2020-10-17. Spinodal decomposition versus classical gamma-prime nucleation in a nickel-base superalloy powder: An in-situ neutron diffraction and atomic-scale analysis. https://doi.org/10.1016/j.actamat.2020.09.055

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