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arXiv · 2008.05502

Defect behavior and radiation tolerance of MAB phases (MoAlB and Fe2AlB2) with comparison to MAX phases

Hongliang Zhang·JunYoung Kim·Ranran Su·Peter Richardson·Jianqi Xi·Erich Kisi·John O'Connor·Liqun Shi·Izabela Szlufarska
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Abstract

MAB phases are a new class of layered ternary materials that have already shown a number of outstanding properties. Here, we investigate defect evolution and radiation tolerance of two MAB phases, MoAlB and Fe2AlB2, using a combination of experimental characterization and first-principles calculations. We find that Fe2AlB2 is more tolerant to radiation-induced amorphization than MoAlB, both at 150 °C and at 300 °C. The results can be explained by the fact that the Mo Frenkel pair is unstable in MoAlB and as a result, irradiated MoAlB is expected to have a significant concentration of MoAl antisites, which are difficult to anneal even at 300 °C. We find that the tolerance to radiation-induced amorphization of MAB phases is lower than in MAX phases, but it is comparable to that of SiC. However, MAB phases do not show radiation-induced cracking which is observed in MAX phases under the same irradiation conditions. This study suggests that MAB phases might be a promising class of materials for applications that involve radiation.

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Hongliang Zhang, JunYoung Kim, Ranran Su, Peter Richardson, Jianqi Xi, Erich Kisi, John O'Connor, Liqun Shi, Izabela Szlufarska. 2020-08-12. Defect behavior and radiation tolerance of MAB phases (MoAlB and Fe2AlB2) with comparison to MAX phases. https://doi.org/10.1016/j.actamat.2020.07.002

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