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arXiv · 2012.15098

Photochromic response of encapsulated oxygen-containing yttrium hydride thin films

Marcos V. Moro·Sigurbjörn M. Aðalsteinsson·Tuan. T. Tran·Dmitrii Moldarev·Ayan Samanta·Max Wolff·Daniel Primetzhofer
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Abstract

Photochromic oxygen$-$containing yttrium$-$hydride thin films are synthesized by argon$-$magnetron sputtering on microscope slides. Some of them are encapsulated with a thin, transparent and non$-$photochromic diffusion-barrier layer of either Al2O3 or Si3N4. Ion beam-based methods prove that these protective diffusion barriers are stable and free from pinholes, with thicknesses of only a few tens of nanometers. Optical spectrophotometry reveals that the photochromic response and relaxation time for both $-$ protected and unprotected $-$ samples are almost identical. Ageing effects in the unprotected films lead to degradation of the photochromic performance (self$-$delamination) while the photochromic response for the encapsulated films is stable. Our results show that the environment does not play a decisive role for the photochromic process and encapsulation of oxygen containing rare-earth hydride films with transparent and non-organic thin diffusion barrier layers provides long-time stability of the films, mandatory for applications as photochromic coatings on e.g., smart windows.

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Marcos V. Moro, Sigurbjörn M. Aðalsteinsson, Tuan. T. Tran, Dmitrii Moldarev, Ayan Samanta, Max Wolff, Daniel Primetzhofer. 2020-12-30. Photochromic response of encapsulated oxygen-containing yttrium hydride thin films. https://doi.org/10.1002/pssr.202000608

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