Search arXivSearch

arXiv · 2103.14766

Memory in Non-Monotonic Stress Response of an Athermal Disordered Solid

Abstract

Athermal systems across a large range of length scales, ranging from foams and granular bead packings to crumpled metallic sheets, exhibit slow stress relaxation when compressed. Experimentally they show a non-monotonic stress response when decompressed somewhat after an initial compression, i.e. under a two-step, Kovacs-like protocol. It turns out that from this response one can tell for how long the system was in a compressed state, suggesting an interpretation as a memory effect. In this work we use a model of an athermal jammed solid, specifically a binary mixture of soft harmonic particles, to explore this phenomenon through in-silico experiments. Using extensive simulations under conditions analogous to those in experiment, we observe identical phenomenology in the stress response under a two-step protocol. Our model system also recovers the behaviour under a more recently studied three-step protocol, which consists of a compression followed by a decompression and then a final compression. We show that the observed response in both two-step and three-step protocols can be understood using Linear Response Theory. In particular, a linear scaling with age for the two-step protocol arises generically for slow linear responses with power law or logarithmic decay and does not in itself point to any underlying aging dynamics.

Explore related subjects

Keep this discovery

Explore connections, maps & timelines

BibTeXRIS

Rituparno Mandal, Diego Tapias, Peter Sollich. 2021-12-05. Memory in Non-Monotonic Stress Response of an Athermal Disordered Solid. https://doi.org/10.1103/physrevresearch.3.043153

Cite the original work for its findings. Save a collection to share your selection of sources.

KEEP EXPLORING

Related papers

Scale dependent chirality in twist-bend liquid crystals

The discovery of new classes of lyotropic and thermotropic liquid crystals (e.g., twist-bend, splay, and ferroelectric phases), together with significant advances in experimental techniques for their investigation, has renewed interest in a number of physical phenomena that have been studied in classical liquid crystals (nematics, cholesterics, and smectics) for more than a century. In this paper, we revisit one such ''old--new'' problem, recently highlighted in the preprint by A. Ashkinazi, H. Chhabra, A. El Moumane, M. M. C. Tortora, and J. P. K. Doye, ''Chirality Transfer in Lyotropic Twist-Bend Nematics,'' arXiv:2508.03544v1 (2025), in which various mechanisms of chirality transfer from the molecular scale to the structural scale were discussed. Here we present a simple theoretical analysis of chirality transfer within a Landau theory describing the phase transition between cholesteric and chiral twist-bend liquid crystals. We demonstrate that the handedness of the heliconical structure is opposite to that of the parent cholesteric phase. This relationship originates from the orthogonality between the cholesteric director and the vector order parameter characterizing the phase.

cond-mat.soft

Why life is hot

The process of evolution by natural selection leads to phenotypes of increasing fitness. For cellular chemical reaction networks, this means optimising a variety of fitness functions such as robustness, precision, or sensitivity to external stimuli. We argue that these diverse goals can be achieved by a versatile, generic mechanism: coupling chemical reaction networks to reservoirs that are strongly out of equilibrium. Using theory and numerics we show that this mechanism of optimisation comes at the price of significant heat dissipation. We compute the heat flux caused by kinetic proofreading in {\it Escherichia coli} and show that it constitutes a significant fraction of the total heat flux experimentally measured in this model organism. We then demonstrate that the degree of optimality achievable saturates, and that Nature appears to operate near saturation despite high energetic costs. We argue that `life is hot' largely because of the need for a versatile mechanism to optimise a variety of fitness functions.

cond-mat.soft

Understanding Structural Representation in Foundation Models for Polymers

From the relative scarcity of training data to the lack of standardized benchmarks, the creation of effective foundation models for polymers faces significant and multi-faceted challenges. At the core, many of these issues are tied directly to the structural representation of polymers. Here, we present a chemical language foundation model built on using a SMILES-based polymer graph representation (CPG) that incorporates polymer architectural features and connectivity that are often missing in other line notations. This foundation model exhibited excellent performance on 30 different polymer property benchmark datasets. Critical evaluation of the developed representation against other variations in control experiments reveals this approach to be a robust method of representing polymers in language-based foundation models. These experiments also reveal a strong invariance of structural representations to small perturbations, with many variations of structural representation exceeding or equaling state-of-the-art (SOTA) performance. Surprisingly, SMILES representations which are chemically or semantically invalid also provided near or SOTA performance in several instances--underscoring an unexamined blind spot in the development of chemistry language models. Examination of error sources and attention maps for the evaluated structural representations corroborate the findings of the control experiments, highlighting the ability of the model to interpolate SMILES sequence space in a manner that is loosely congruent to chemical and architectural space for polymers. Overall, this work highlights the surprising robustness of chemistry language models to structural representation perturbations and identifies the conditions under which CPG representation provides meaningful advantages.

cond-mat.soft