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arXiv · 2104.08694

Impact of particle size on the magnetic properties of highly crystalline Yb3+ substituted Ni-Zn nanoferrites

N. Jahan·M. M. Uddin·M. N. I. Khan·F. -U. -Z. Chowdhury·M. R. Hasan·H. N. Das·M. M. Hossain
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Abstract

Yb-substituted Ni-Zn ferrites have been synthesized using sol-gel auto combustion method. The structural characterization of the compositions has been performed by X-ray diffraction analysis, field emission scanning electron microscopy (FESEM), quantum design physical properties measurement system (PPMS). That ensured the formation of single phase cubic spinel structure. Crystallite and average grain size are calculated and found to decrease with increasing Yb3+ contents. Saturation magnetization and Bohr magnetic moment decrease while the coercivity increases with the increase in Yb3+ contents successfully explained by the Neels collinear two sub-lattice model and critical size effect, respectively. Critical particle size has been estimated at 6.4 nm, the transition point between single domain regime (below the critical size) and multi-domain regime (beyond the critical size). Curie temperature reduces due to the weakening of A-O-B super exchange interaction and redistribution of cations, confirmed by the M-T graph. The compositions retain ferromagnetic ordered structured below Curie temperature and above Curie temperature, it becomes paramagnetic, making them plausible candidates for high temperature magnetic device applications. The relative quality factor peak is obtained at a very high frequency, indicating the compositions could also be applicable for high frequency magnetic device applications.

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N. Jahan, M. M. Uddin, M. N. I. Khan, F. -U. -Z. Chowdhury, M. R. Hasan, H. N. Das, M. M. Hossain. 2021-04-18. Impact of particle size on the magnetic properties of highly crystalline Yb3+ substituted Ni-Zn nanoferrites. https://arxiv.org/abs/2104.08694

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