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arXiv · 2108.11599

Mixed-Salt Enhanced Chemical Vapor Deposition of Two-Dimensional Transition Metal Dichalcogenides

Shisheng Li·Yung-Chang Lin·Jinhua Hong·Bo Gao·Hong En Lim·Xu Yang·Song Liu·Yoshitaka Tateyama·Kazuhito Tsukagoshi·Yoshiki Sakuma·Kazu Suenaga·Takaaki Taniguchi
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Abstract

The usage of molten salts, e.g., Na2MoO4 and Na2WO4, has shown great success in the growth of two-dimensional (2D) transition metal dichalcogenides (TMDCs) by chemical vapor deposition (CVD). In comparison with the halide salt (i.e., NaCl, NaBr, KI)-assisted growth (Salt 1.0), the molten salt-assisted vapor-liquid-solid (VLS) growth technique (Salt 2.0) has improved the reproducibility, efficiency and scalability of synthesizing 2D TMDCs. However, the growth of large-area MoSe2 and WTe2 is still quite challenging with the use Salt 2.0 technique. In this study, a renewed Salt 2.0 technique using mixed salts (e.g., Na2MoO4-Na2SeO3 and Na2WO4-Na2TeO3) is developed for the enhanced CVD growth of 2D MoSe2 and WTe2 crystals with large grain size and yield. Continuous monolayer MoSe2 film with grain size of 100-250 μm or isolated flakes up to ~ 450 μm is grown on a halved 2-inch SiO2/Si wafer. Our study further confirms the synergistic effect of Na+ and SeO32- in the enhanced CVD growth of wafer-scale monolayer MoSe2 film. And thus, the addition of Na2SeO3 and Na2TeO3 into the transition metal salts could be a general strategy for the enhanced CVD growth of many other 2D selenides and tellurides.

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Shisheng Li, Yung-Chang Lin, Jinhua Hong, Bo Gao, Hong En Lim, Xu Yang, Song Liu, Yoshitaka Tateyama, Kazuhito Tsukagoshi, Yoshiki Sakuma, Kazu Suenaga, Takaaki Taniguchi. 2021-08-26. Mixed-Salt Enhanced Chemical Vapor Deposition of Two-Dimensional Transition Metal Dichalcogenides. https://doi.org/10.1021/acs.chemmater.1c01652

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