Search arXiv⌕ Search
Home/Archive/arXiv

arXiv · 2112.02141

Tuning the coherent propagation of organic exciton-polaritons through dark state delocalization

Raj Pandya·Arjun Ashoka·Kyriacos Georgiou·Jooyoung Sung·Rahul Jayaprakash·Scott Renken·Lizhi Gai·Zhen Shen·Akshay Rao·Andrew Musser
View original source ↗Read source document ↗Export metadata ↓

Abstract

While there have been numerous reports of long-range polariton transport at room-temperature in organic cavities, the spatio-temporal evolution of the propagation is scarcely reported, particularly in the initial coherent sub-ps regime, where photon and exciton wavefunctions are inextricably mixed. Hence the detailed process of coherent organic exciton-polariton transport and in particular the role of dark states has remained poorly understood. Here, we use femtosecond transient absorption microscopy to directly image coherent polariton motion in microcavities of varying quality factor. We find the transport to be well-described by a model of band-like propagation of an initially Gaussian distribution of exciton-polaritons in real space. The velocity of the polaritons reaches values of ~0.65x10^6 m s-1, substantially lower than expected from the polariton dispersion. Further, we find that the velocity is proportional to the quality factor of the microcavity. We suggest this unexpected link between the quality-factor and polariton velocity and slow coherent transport to be a result of varying admixing between delocalised dark and polariton states.

Explore related subjects

physics.chem-phcond-mat.mtrl-sci

Keep this discovery

Explore connections, maps & timelines

BibTeXRIS

Raj Pandya, Arjun Ashoka, Kyriacos Georgiou, Jooyoung Sung, Rahul Jayaprakash, Scott Renken, Lizhi Gai, Zhen Shen, Akshay Rao, Andrew Musser. 2021-12-03. Tuning the coherent propagation of organic exciton-polaritons through dark state delocalization. https://doi.org/10.1002/advs.202105569

Cite the original work for its findings. Save a collection to share your selection of sources.

KEEP EXPLORING

Related papers

arXiv2026

Global approximations to the error function of real argument for vectorized computation

The error function of real argument can be approximated to a given uniform relative accuracy by a single closed-form expression for the whole variable range either in terms of addition, multiplication, division, and square root operations only, or also using the exponential function. The coefficients have been tabulated for up to 128-bit precision. Tests of a computer code implementation using the standard single- and double-precision floating-point arithmetic show good performance and vectorizability. Approximations to the complementary error function have also been found, including those where only additions, multiplications, and one division are needed to reach a uniform absolute accuracy.

physics.chem-ph↗
arXiv2026

From Heuristics to Machine Learning: The Performance Ceiling for Single-Ion Magnets and Its Electronic Origin

Machine learning (ML) is expected to speed up the discovery of single-ion magnets (SIMs), but does the structural information available before synthesis allow such predictions? For 1215 lanthanide complexes from the SIMDAVIS 1.2.1 database we compared three increasing levels of structural description: tabular features of the coordination site, continuous symmetry measures of the coordination polyhedron, and the complete 3D arrangement of atoms. All three converge to an accuracy near 76%, only slightly above the 71% of the single rule "predict SIM for Dy3+". To explain the failures, we combined multireference ab initio calculations with an inspection of the structures behind the high-confidence errors. The SIMs missed by the geometric models are field-induced relaxers whose ground Kramers doublets are prone to tunnelling, a property invisible to geometric descriptors. Many false positives contain several lanthanide centers or radicals, so their relaxation is collective and outside the single-ion picture. The electronic-structure and connectivity information needed to identify SIMs is therefore not accessible to geometric methods alone. Geometric models remain useful: restricting the screening to compounds with high prediction confidence raises the accuracy to 88% while retaining 48% of the dataset. Building on the analysis of the failures, we propose a strategy that combines simple filters for nuclearity and for radicals with ligand-field descriptors from ab initio calculations.

physics.chem-ph↗
arXiv2026

Composition-Dependent Self-Diffusion Coefficients in Liquid Mixtures from Hybrid Machine Learning

Self-diffusion coefficients are key descriptors of molecular mobility, yet experimental data remain scarce, highlighting the need for reliable prediction methods. In previous work, we introduced the hybrid Enhanced Stokes-Einstein (ESE) model, which advanced the state of the art in the physically consistent prediction of self-diffusion coefficients of solutes at infinite dilution in pure solvents by integrating the Stokes-Einstein equation with machine learning (ML). Here, we extend this approach to concentration-dependent self-diffusion coefficients and multicomponent solvents with HADES. This hybrid architecture leverages a deep-set neural network to connect pure-component and mixture prediction within a single framework. HADES predicts self-diffusion coefficients in liquid mixtures with any number of components at any composition and temperature. The only required inputs are SMILES-encoded molecular structures of the components and the pure-component viscosities, making the method broadly applicable. Trained and evaluated on a comprehensive dataset of 2526 data points for 600 systems, HADES significantly outperforms benchmark prediction methods. The trained model and its source code are fully disclosed, and the application is available via an interactive website https://ml-prop.mv.rptu.de/.

physics.chem-ph↗