Search arXivSearch

arXiv · 2204.09255

Superconducting bimodal ionic photo-memristor

Abstract

Memristive circuit elements constitute a cornerstone for novel electronic applications, such as neuromorphic computing, called to revolutionize information technologies. By definition, memristors are sensitive to the history of electrical stimuli, to which they respond by varying their electrical resistance across a continuum of nonvolatile states. Recently, much effort has been devoted to developing devices that present an analogous response to optical excitation. Here we realize a new class of device, a tunnelling photo-memristor, whose behaviour is bimodal: both electrical and optical stimuli can trigger the switching across resistance states in a way determined by the dual optical-electrical history. This unique behaviour is obtained in a device of ultimate simplicity: an interface between a high-temperature superconductor and a transparent semiconductor. The microscopic mechanism at play is a reversible nanoscale redox reaction between both materials, whose oxygen content determines the electron tunnelling rate across their interface. Oxygen exchange is controlled here via illumination by exploiting a competition between electrochemistry, photovoltaic effects and photo-assisted ion migration. In addition to their fundamental interest, the unveiled electro-optic memory effects have considerable technological potential. Especially in combination with high-temperature superconductivity which, beyond facilitating the high connectivity required in neuromorphic circuits, brings photo-memristive effects to the realm of superconducting electronics.

Explore related subjects

Keep this discovery

Explore connections, maps & timelines

BibTeXRIS

Ralph El Hage, Vincent Humbert, Victor Rouco, Anke Sander, Jérôme Charliac, Salvatore Mesoraca, Juan Trastoy, Javier Briatico, Jacobo Santamaría, Javier E. Villegas. 2022-04-20. Superconducting bimodal ionic photo-memristor. https://arxiv.org/abs/2204.09255

Cite the original work for its findings. Save a collection to share your selection of sources.

KEEP EXPLORING

Related papers

Growth of superconducting boron doped diamond on 4inch silicon wafers

Superconducting boron-doped diamond (BDD) films were grown on 4-inch silicon wafers by microwave plasma chemical vapour deposition using gas-phase B/C ratios ranging from 6536 to 36421 ppm. Surface morphology, boron incorporation and superconducting properties were investigated as a function of gas-phase boron concentration. No systematic variation in apparent lateral grain size was observed across the series. Superconductivity was observed in all films except that grown at a B/C ratio of 6536 ppm within the measured temperature range down to 2 K. The superconducting transition temperature initially increased with increasing B/C ratio, reaching a maximum T$_c$ of 4.03 K at 24691 ppm, before decreasing at higher gas-phase B/C ratios. The corresponding resistive upper critical field at 2 K reached 3.091 T. Raman spectroscopy showed an increase in boron incorporation with increasing gas-phase B/C ratio up to 30303 ppm, followed by a slight decrease at 36421 ppm. Spatial measurements across the film grown at 24691 ppm showed T$_c$ values of 4.02, 4.19 and 3.33 K at the centre, intermediate and edge positions, respectively, with Raman spectroscopy showing a corresponding spatial variation in boron concentration. Comparison with previous growth on 2-inch wafers showed that substantially higher gas-phase B/C ratios were required to obtain comparable boron concentrations and superconducting properties on 4-inch wafers, indicating reduced boron incorporation efficiency during large-area growth. These results demonstrate the feasibility of producing superconducting BDD over a substantial area of a 4-inch silicon wafer while identifying boron incorporation and radial uniformity as key parameters for further wafer-scale optimisation.

cond-mat.supr-con

Multigap superconductivity in Ising superconductors: The case of (LaSe)1.14(NbSe2)m misfit layer compounds

Strong spin-orbit coupling and broken inversion symmetry in transition metal dichalcogenides give rise to Ising superconductivity, a spin-protected pairing state first identified in monolayer NbSe$_2$ through in-plane critical fields far exceeding the Pauli limit. More recently, Ising superconductivity has been proposed as a potential route to unconventional and even topological superconductivity in bulk misfit compounds. Here, we investigate the superconducting order parameter of layered misfit compounds composed of alternating transition metal dichalcogenide and rocksalt layers, which host extremely doped, electronically decoupled NbSe$_2$ sheets within a three-dimensional crystal. Using directional scanning tunneling spectroscopy on the misfit superconductors (LaSe)$_{1.14}$(NbSe$_2$) and (LaSe)$_{1.14}$(NbSe$_2$)$_2$, we uncover a strongly anisotropic multigap superconducting state: a fragile gap on the $Γ$-centered Fermi-surface pocket coexists with a robust, intrinsic gap on the K and K$'$ pockets. These features are in quantitative agreement with momentum-resolved gaps $Δ(\mathbf{k})$ obtained from anisotropic Migdal-Eliashberg calculations. The marked fragility of the $Γ$-centered gap, combined with the strong sensitivity of the critical temperature to non-magnetic disorder, points to pairing beyond conventional $s$-wave symmetry, potentially involving a topological order parameter. These results establish NbSe$_2$-based misfit compounds as a tunable bulk platform for multigap, unconventional superconductivity, with Ising protection offering a promising route toward topological pairing.

cond-mat.supr-con

Thermal Hall effect in elemental niobium, a two-gap superconductor

Niobium holds a pivotal place in superconductivity history: it is not only the elemental superconductor with the highest critical temperature, but also a long-standing candidate for multiband pairing whose evidence has remained controversial. A two-gap scenario was proposed as early as 1959, yet experimental proof stayed elusive. Here, through thermal Hall effect measurements, we unambiguously demonstrate a crossover in transverse thermal transport below $T_{\rm c}$, where the dominant carrier switches from hole-like to electron-like upon cooling. This crossover is a clear hallmark of two distinct superconducting condensates. Fitting our data to a two-gap Bardeen-Rickayzen-Tewordt (BRT) model yields a second energy gap of approximately 0.22 $k_{\rm B}T_{\rm c}$, only 11\% of the dominant gap. This small gap size accounts for the difficulty in resolving the two-gap structure in earlier experiments. Crucially, the temperature at which the electron-like contribution to longitudinal thermal conductivity begins to dominate coincides with the onset of the sign reversal in the thermal Hall coefficient, confirming consistency between the two methods, and providing crucial information on the assignment of the superconducting gaps to their respective hole- or electron-like Fermi surface sheets. These findings not only resolve a longstanding controversy, but also establish that multigap superconductivity is far more common than previously assumed, and demonstrate the thermal Hall effect as a powerful probe for resolving gap multiplicities in superconductors.

cond-mat.supr-con