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arXiv · 2208.08647

Giant thermoelectric power factor anisotropy in PtSb$_{1.4}$Sn$_{0.6}$

Yu Liu·Zhixiang Hu·Michael O. Ogunbunmi·Eli Stavitski·Klaus Attenkofer·Svilen Bobev·Cedomir Petrovic
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Abstract

We report giant anisotropy in thermoelectric power factor ($S^2σ$) of marcasite structure-type PtSb$_{1.4}$Sn$_{0.6}$. PtSb$_{1.4}$Sn$_{0.6}$, synthesized using ambient pressure flux growth method upon mixing Sb and Sn on the same atomic site, is a new phase different from both PtSb$_2$ and PtSn$_2$ that crystallize in the cubic $Pa\bar{3}$ pyrite and $Fm\bar{3}m$ fluorite unit cell symmetry, respectively. Giant difference in $S^2σ$ for heat flow applied along different principal directions of the orthorhombic unit cell mostly stems from anisotropic Seebeck coefficients.

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Yu Liu, Zhixiang Hu, Michael O. Ogunbunmi, Eli Stavitski, Klaus Attenkofer, Svilen Bobev, Cedomir Petrovic. 2022-08-18. Giant thermoelectric power factor anisotropy in PtSb$_{1.4}$Sn$_{0.6}$. https://doi.org/10.1021/acs.inorgchem.2c02218

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