Can the Ferroelectric Soft Mode Trigger an Antiferromagnetic Phase Transition?

André Maia; Christelle Kadlec; Maxim Savinov; Rui Vilarinho; Joaquim Agostinho Moreira; Viktor Bovtun; Martin Kempa; Martin Míšek; Jiří Kaštil; Andriy Prokhorov; Jan Maňák; Alexei A. Belik; Stanislav Kamba

arXiv · 2211.00386

Can the Ferroelectric Soft Mode Trigger an Antiferromagnetic Phase Transition?

André Maia·Christelle Kadlec·Maxim Savinov·Rui Vilarinho·Joaquim Agostinho Moreira·Viktor Bovtun·Martin Kempa·Martin Míšek·Jiří Kaštil·Andriy Prokhorov·Jan Maňák·Alexei A. Belik·Stanislav Kamba

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Abstract

Type-II multiferroics, where spin interactions induce a ferroelectric polarization, are interesting for new device functionalities due to large magnetoelectric coupling. We report on a new type of multiferroicity in the quadruple-perovskite $\text{BiMn}_{\text{3}}\text{Cr}_{\text{4}}\text{O}_{\text{12}}$, where an antiferromagnetic phase is induced by the structural change at the ferroelectric phase transition. The displacive nature of the ferroelectric phase transition at 125 K, with a crossover to an order-disorder mechanism, is evidenced by a polar soft phonon in the THz range and a central mode. Dielectric and pyroelectric studies show that the ferroelectric critical temperature corresponds to the previously reported Néel temperature of the $\text{Cr}^{\text{3+}}$ spins. An increase in ferroelectric polarization is observed below 48 K, coinciding with the Néel temperature of the $\text{Mn}^{\text{3+}}$ spins. This increase in polarization is attributed to an enhanced magnetoelectric coupling, as no change in the crystal symmetry below 48 K is detected from infrared and Raman spectra.

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André Maia, Christelle Kadlec, Maxim Savinov, Rui Vilarinho, Joaquim Agostinho Moreira, Viktor Bovtun, Martin Kempa, Martin Míšek, Jiří Kaštil, Andriy Prokhorov, Jan Maňák, Alexei A. Belik, Stanislav Kamba. 2022-11-01. Can the Ferroelectric Soft Mode Trigger an Antiferromagnetic Phase Transition?. https://arxiv.org/abs/2211.00386

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